Preparation of structurally-colored aromatic polyamides and their physicochemical properties

Conclusions One-, two-, and three-stage methods of preparing structurally-dyed aromatic polyamides with chromophoric fragments in the chain have been investigated.It has been shown that the molecular weight of the polymers obtained and the proportion of chromophores bound into their chain is determined by the reactivity of the starting diaminoanthraquinones.It has been found that the introduction of anthraquinone units into the poly-m-phenylene isophthalamide chain has little effect on the structure or basic physicochemical properties of the polyamide, but gives the polymer a uniform and regular coloration.Structural dyeing of poly-m-phenylene isophthalamide with fragments of 1,5-DAAQ or 4,8-DADHAQ increases the resistance of the polyamide fibres to UV irradiation.The authors express their thanks to Yu. Ya. Shavarin and N. M. Bol'bit for performance of the fibre irradiation, and also to B. A. Tsaplin for thermomechanical testing of the fibres.L. Ya. Karpov NIFKhI, Moscow. VNIISV, Tver'. Translated from Khimicheskie Volokna, No. 2, pp. 24–27, March–April, 1992.     

Shock-Wave Synthesis of Micron-Size Diamond From Fullerites

Fullerite powders in copper powder matrix were subjected to shock loading in the pressure range of 20-40 GPa. Diamond, nonreacted fee C₆₀ and graphite were detected in all analyzed specimens. The dimensions of synthesized diamond crystallites were up to 6 micron.     

Fourier-transform infrared conformational study of bovine insulin in surfactant solutions

BACKGROUND: bcl-2 protein is an oncoprotein encoded by a protooncogene bcl-2 which is thought to be a key gene for the regulation of cell life and death. bcl-2 protein has been reported to be expressed in a subset of prostate cancers, and its biological role in this disease has not yet been elucidated. This present study focused on the cell cycle analysis of bcl-2 immunoreactivity in prostate tumor samples and correlated findings with the prognosis of the patients. METHODS: Archival tissues from 37 prostate cancers were submitted for immunohistochemistry and DNA analysis via flow cytometry. All tissues were obtained before the patients received any treatment. Immunohistochemistry was performed using streptavidin biotin procedures, and DNA flow cytometry was done by a combination of two methods. RESULTS: Fourteen of 37 prostate cancers (38%) exhibited bcl-2 immunoreactivity. bcl-2 positive prostate cancers significantly correlated with DNA aneuploidy and higher proliferation indices, but not with histological differentiation. Clinically, there was a poorer prognosis for patients with bcl-2 positive prostate cancer. CONCLUSIONS: Our data indicates that bcl-2 protein expression in prostate cancer is associated with cell proliferation and may serve as a predictive factor for the prognosis of prostate cancer.     

High-speed InGaP/GaAs HBTs with a strained InxGa1-xAs base

A self-aligned InGaP/GaAs heterojunction bipolar transistor with a compositionally graded In_xGa_1-xAs base has been demonstrated with f_T=83 GHz and f_max=197 GHz. To our knowledge, these results are the highest reported for both parameters in InGaP/GaAs HBT's. The graded base, which improves electron transport through the base, results in a DC current gain and a cutoff frequency which are 100% and 20% higher, respectively, than that achieved by an identical device with a nongraded base. The high f_max results from a heavily doped base, self-aligned base contacts, and a self-aligned collector etch. These results demonstrate the applicability of InGaP/GaAs HBT's in high-speed microwave applications     

Psychological stress symptoms before and after autologous bone marrow transplantation in patients with solid tumors

This study sought to examine patterns of changes of psychological stress symptoms in autologous bone marrow transplantation (ABMT) recipients. Forty-nine patients affected by solid tumors were assessed using the Symptom Questionnaire on admission to hospital (before high-dose chemotherapy and ABMT) and before discharge. Symptoms of anxiety and anger tended to decrease and relaxation of improve over time. Nevertheless, on admission to hospital 30-50% of the patients reported severe to moderate symptoms of anxiety and depression. Before discharge, the prevalence was still high (20-35%). The implications of these findings are discussed in terms of the need to monitor the evolution of emotional functioning of cancer patients undergoing ABMT.     

Frequent detection of human herpesvirus-6 sequences by polymerase chain reaction in paraffin-embedded lymph nodes from patients with angioimmunoblastic lymphadenopathy and angioimmunoblastic lymphadenopathy-like lymphoma

In search of a possible involvement of viral agents in angioimmunoblastic lymphadenopathy with dysproteinaemia (AILD) and AILD-like lymphoma (AILD-L), we studied the presence of human herpesvirus-6 (HHV-6) in the lymph node biopsies of 12 cases by polymerase chain reaction (PCR). Given the rarity of this lymphoproliferative disorder, we investigated archival specimens, consisting of formalin-fixed and paraffin-embedded tissues, obtained from patients with a clinical and histologic diagnosis of AILD and AILD-L. HHV-6 sequences were detected in the lymph node biopsies of 7 out of the 12 AILD and AILD-L cases examined. HHV-6 sequences were identified also in the involved liver and spleen tissues of one patient and in the PBMCs of two patients, all carrying viral sequences in the affected lymph nodes. We also used PCR to characterize the HHV-6 genomes, showing that two different viral strains are represented in the pathologic tissues. This study provides evidence of the presence of HHV-6 specific sequences in an unexpectedly high proportion of our series of AILD and AILD-L cases, suggesting a possible involvement of this lymphotropic virus in the pathogenesis of at least some cases of the disease.     

Opposite-channel-based charge injection in SOI MOSFET's under hotcarrier stress

By operating one channel of a typical SOI MOSFET in avalanche while keeping the opposite channel accumulated, charge injection into the opposite gate takes place. Three independent experiments are described that demonstrate the occurrence of this opposite-channel based charge injection. The experimental results are in agreement with PISCES numerical simulations     

Microwave Drymg of Grapes in a Single Mode Cavity at 2450 Mhz - i: Drying Kinetics

Grapes were dried into raisins using combined microwave and convective drying in a single mode cavity specially designed for the studies. Effect of processing parameters, viz.microwave power density (P) air temperature (T) and velocity (u) on drying kinetics was studied in an effort to optimize the operating conditions. The individual and interactive effects of these variables were srudied using three levels of P, four levels of T and two levels of u. Higher drying rates observed with the higher P and T were atuibuted to the increased product temperature and higher partial vapour pressure difference between the surface of the fruit and the air stream. Increase of air velocity increased the drying times. Low drying rate at higher air velocity was attributed to decreased fruit temperature due to rapid convective heat mnsfer at the surface.     

Influence of Two Salicylate Components on the Particle Size of an Oil-in-Water Emulsion with Nonionic Surfactants

This paper reports a study undertaken using techniques of static and dynamic light scattering to investigate the influence of sodium salicylate and methyl salicylate on droplet size of oil-in-water emulsions. The rates of changes were measured by determining the size and distribution of the oil droplet in the material. All emulsions showed a bimodal size distribution; the mean diameters and polydispersity were calculated from intensity. These data were analyzed with nonlinear regressions and bootstrap methodology. An amount of methyl salicylate component induced a decrease of mean diameter and standard deviation. On the contrary, sodium salicylate entailed the growth of all droplet populations and coalescence for the highest concentration.