Magnetron sputtered Dy_2O_3 with chromium and copper contents for antireflective thin films with enhanced absorption

Dy_2O_3 is a rare earth oxide having a number of advanced applications in various fields including protective or antireflective coatings, Main objective of this novel research work is to check the effect of Cr and Cu addition on different properties of Dy_2O_3 and achievement of antireflective thin films with enhanced abso rption. Thin films of these materials we re deposited using DC magnetron with reactive cosputtering. XRD studies reveals the crystalline nature of thin films having Dy_2O_3(222) reflection in all samples with Cr_2O_3(116) and CuO(111) reflections in Cr and Cu containing compositions. Field emission scanning electron microscopy demonstrates the homogeneous deposition of thin films with uniform shape, size and distribution of grains. Refractive index, extinction coefficient and absorption coefficient significantly increase while optical reflectance decreases with Cr and Cu mediation corroborating an improved antireflective mechanism. The imaginary part of dielectric constant is found to increase slightly with low tangent loss for Cr containing composition co nsidered favorable for energy storage applications.     

Performance of microwave synthesized dual solvent dope solution and lithium bromide additives on poly(ethersulfone) membranes

BACKGROUND: Generally the fabrication of polymeric membranes is a complicated and expensive process since it involves several steps. The preliminary preparation steps involve polymer drying and dissolution and is very time consuming and expensive. Currently, conventional electrothermal heating (CEH) is used to dissolve polyethersulfone in an aprotic solvent for membrane fabrication. Usually CEH requires 6 to 8 h at temperatures of 80 to 95 °C. This paper reports the fabrication and characterization of polyethersulfone (PES) asymmetric ultrafiltration membrane made from microwave (MW) synthesis casting solution consisting of various compositions of double solvents and lithium bromide (LiBr) additive. RESULTS: Homogeneous dual solvent dope solutions prepared via microware irradiation took only 1 h instead of the 7 h when prepared using CEH. The results also revealed that the membrane permeation and rejection rates, pore size and porosity were dependent on the ratio of LiBr to acetone. Membranes with LiBr kept at 2 and 3 wt% exhibited both high rejection and permeation rates with minimum pore sizes of 1.067 and 1.214 nm respectively. The presence of LiBr and the occurrence of chain scission were elucidated using Fourier transform infrared (FTIR) spectroscopy while its hydrophilic property was confirmed by water absorption and contact angle measurements. CONCLUSIONS: It was concluded that the microwave technique is capable of producing 1 L membrane solutions in less than 1 h. The membranes prepared from the microwave solutions show good rejection and permeation rates. Copyright © 2011 Society of Chemical Industry     

The effect of SiO2 dielectric layer on ultraviolet detecting properties of pentacene thin film transistor

The pentacene thin film transistor was fabricated on a SiO₂/Si substrate by thermal evaporated method at room temperature. Electrical characteristics of the pentacene transistor subjected to a UV light excitation at a wavelength of 365 nm were analyzed. A significant increase in the drain current of the pentacene thin film transistor under a UV excitation of 365 nm is observed with a maximum photosensitivity of 4.51 in the depletion regime. It is concluded that the pentacene thin film transistor can be used in UV photo-detecting devices.     

Hydrodynamic drainage force in a highly confined geometry: role of surface roughness on different length scales

We measured the hydrodynamic drainage force of an aqueous, Newtonian liquid squeezed between two hydrophobic or two hydrophilic surfaces by means of the colloidal probe technique. We controlled the wettability, the roughness, the topology, and also the approaching velocity of the surfaces. We found that asperities on the surfaces caused an artificial decrease of the measured drainage force that must be considered by the interpretation of the force curves. Even considering the effect of asperities, our experimental results could be interpreted only with the aid of a partial slip model. Or else, interpreted assuming that the viscosity close to the surfaces is different from bulk. On patterned hydrophilic surfaces, we demonstrated that the drainage force depends not only on the overall surface roughness or micro structuring but also on the specific length scale of the surface nanostructures.     

Monitoring of acrylamide carcinogen in selected heat-treated foods from Saudi Arabia

Food Science and Biotechnology - The present study reports the outcomes of assessment on acrylamide levels in selected heat-treated foods of diverse brands and origins from Saudi Arabia. In chips,...     

Experimental and physical approaches on a novel semiconducting-ionic membrane fuel cell

Semiconducting-ionic membranes (SIMs) have exhibited significant superiority to replace the conventional ionic electrolytes in solid oxide fuel cells (SOFCs). One interesting phenomenon is that the SIMs can successfully avoid the underlying short-circuiting issue and power losses while bringing significantly enhanced power output. It is crucial to understand the physics in such devices as they show distinct electrochemical processes with conventional fuel cells. We first presented experimental studies of a SIM fuel cell based on a composite of semiconductor LiCo_0.8Fe_0.2O₂ (LCF) and ionic conductor Sm-doped CeO₂ (SDC), which achieved a remarkable power density of 1150 mW cm^?2 at 550 °C along with a high open circuit voltage (OCV) of 1.04 V. Then, for the first time we used a physical model via combining a semiconductor-ionic contact junction with a rectifying layer which blocks the electron leakage to describe such unique SIM device and excellent performance. Current and power are the most important characteristics for the device, by introducing the rectifying layer we described the SIM physical nature and new device process. This work presented a new view on advanced SIM SOFC science and technology from physics.     

Continuation ratio model for the performance behavior of wastewater collection networks

Canada’s aged wastewater infrastructure is failing. New financial and environmental regulatory requirements demand municipalities to estimate operating and capital expenditures for running the systems into the future, and to develop plans for financial sustainability while protecting public health and the environment. Presently, wastewater pipelines’ deterioration is not well understood and realistic deterioration models need to be developed.This paper presents a new ordinal regression model for the deterioration of wastewater pipelines based on continuation ratio logits. The model is presented using the generalized linear model formulation, and takes into account the ordinal nature of the dependent variable and the interaction effects between explanatory variables. The model provides estimates of conditional probabilities for a pipeline to advance beyond a particular internal condition grade – to worse condition – depending on pipe material and age. The model development and validation procedure is demonstrated using high quality condition assessment data for reinforced concrete (RC) and vitrified clay (VC) pipes from the City of Niagara Falls wastewater collection system.The new model is found to represent the RC and VC pipes’ degradation behavior for in-service pipes up to 110 years of age at the City of Niagara Falls wastewater collection system. RC pipes’ deterioration is found to be age dependent while VC pipes’ deterioration is not age dependent. The VC pipe finding is contrary to other deterioration model studies that indicate that the type of pipe material is not significant and that the deterioration of VC pipes is age dependent. The analysis shows, for example, that the predicted conditional probability for RC pipes to advance beyond internal condition grade 3 is estimated to be 60% at 40 years of age and it increases to 90% at 80 years. Similarly, there is a 60% chance of advancing beyond grade 4 to collapsed/collapse imminent condition at 80 years of age for RC pipes. VC pipes are found to have an indefinite service life if installed without structural damage. However, VC pipes exhibited relatively higher conditional probabilities than RC pipes for advancing to worse internal condition grades for pipes up to 65 years of age. Poor installation practices that resulted in pipe defects, such as open/displaced joints and defective connections are deemed to be the factors that resulted in VC pipe deterioration.The findings from the continuation ratio model can be used for risk-based policy development for maintenance management of wastewater collection systems. The proposed model can help in devising appropriate intervention plans and optimum network maintenance management strategies based on pipelines’ age, material type, and internal condition grades. These predictions are critical if realistic wastewater networks’ future maintenance and operation budgets are to be developed over the life of asset and to meet new regulatory reporting requirements. Further research is required to validate the proposed model in other networks and to determine if the method can be used to model the deterioration of pipe materials other than RC and VC.     

A web-based remote interactive laboratory for Internetworking education

A Web-based remote interactive laboratory (RIL) developed to deliver Internetworking laboratory experience to geographically remote graduate students is presented in this paper. The onsite Internetworking program employs hands-on laboratories in a group setting that correlates with the constructivist and collaborative pedagogical approach. This paper discusses the pedagogical and technical considerations that influence the design and implementation of the remote laboratory environment given the constraints of the special hardware and learning outcomes of the program. For wide-ranging usability, the remote Internetworking (INWK) laboratory uses de facto networking standards and commercial and broad-band Internet connectivity to ensure real-time secure interaction with equipment. A four-tier role architecture consisting of faculty, local facilitators, remote facilitators, and students has been determined appropriate to maintain academic integrity and ensure good quality of interaction with the remote laboratory. A survey employing a five-point scale has been devised to measure the usability of the remote access INWK laboratory.