Experimental and physical approaches on a novel semiconducting-ionic membrane fuel cell

Semiconducting-ionic membranes (SIMs) have exhibited significant superiority to replace the conventional ionic electrolytes in solid oxide fuel cells (SOFCs). One interesting phenomenon is that the SIMs can successfully avoid the underlying short-circuiting issue and power losses while bringing significantly enhanced power output. It is crucial to understand the physics in such devices as they show distinct electrochemical processes with conventional fuel cells. We first presented experimental studies of a SIM fuel cell based on a composite of semiconductor LiCo_0.8Fe_0.2O₂ (LCF) and ionic conductor Sm-doped CeO₂ (SDC), which achieved a remarkable power density of 1150 mW cm^?2 at 550 °C along with a high open circuit voltage (OCV) of 1.04 V. Then, for the first time we used a physical model via combining a semiconductor-ionic contact junction with a rectifying layer which blocks the electron leakage to describe such unique SIM device and excellent performance. Current and power are the most important characteristics for the device, by introducing the rectifying layer we described the SIM physical nature and new device process. This work presented a new view on advanced SIM SOFC science and technology from physics.     

Continuation ratio model for the performance behavior of wastewater collection networks

Canada’s aged wastewater infrastructure is failing. New financial and environmental regulatory requirements demand municipalities to estimate operating and capital expenditures for running the systems into the future, and to develop plans for financial sustainability while protecting public health and the environment. Presently, wastewater pipelines’ deterioration is not well understood and realistic deterioration models need to be developed.This paper presents a new ordinal regression model for the deterioration of wastewater pipelines based on continuation ratio logits. The model is presented using the generalized linear model formulation, and takes into account the ordinal nature of the dependent variable and the interaction effects between explanatory variables. The model provides estimates of conditional probabilities for a pipeline to advance beyond a particular internal condition grade – to worse condition – depending on pipe material and age. The model development and validation procedure is demonstrated using high quality condition assessment data for reinforced concrete (RC) and vitrified clay (VC) pipes from the City of Niagara Falls wastewater collection system.The new model is found to represent the RC and VC pipes’ degradation behavior for in-service pipes up to 110 years of age at the City of Niagara Falls wastewater collection system. RC pipes’ deterioration is found to be age dependent while VC pipes’ deterioration is not age dependent. The VC pipe finding is contrary to other deterioration model studies that indicate that the type of pipe material is not significant and that the deterioration of VC pipes is age dependent. The analysis shows, for example, that the predicted conditional probability for RC pipes to advance beyond internal condition grade 3 is estimated to be 60% at 40 years of age and it increases to 90% at 80 years. Similarly, there is a 60% chance of advancing beyond grade 4 to collapsed/collapse imminent condition at 80 years of age for RC pipes. VC pipes are found to have an indefinite service life if installed without structural damage. However, VC pipes exhibited relatively higher conditional probabilities than RC pipes for advancing to worse internal condition grades for pipes up to 65 years of age. Poor installation practices that resulted in pipe defects, such as open/displaced joints and defective connections are deemed to be the factors that resulted in VC pipe deterioration.The findings from the continuation ratio model can be used for risk-based policy development for maintenance management of wastewater collection systems. The proposed model can help in devising appropriate intervention plans and optimum network maintenance management strategies based on pipelines’ age, material type, and internal condition grades. These predictions are critical if realistic wastewater networks’ future maintenance and operation budgets are to be developed over the life of asset and to meet new regulatory reporting requirements. Further research is required to validate the proposed model in other networks and to determine if the method can be used to model the deterioration of pipe materials other than RC and VC.     

A web-based remote interactive laboratory for Internetworking education

A Web-based remote interactive laboratory (RIL) developed to deliver Internetworking laboratory experience to geographically remote graduate students is presented in this paper. The onsite Internetworking program employs hands-on laboratories in a group setting that correlates with the constructivist and collaborative pedagogical approach. This paper discusses the pedagogical and technical considerations that influence the design and implementation of the remote laboratory environment given the constraints of the special hardware and learning outcomes of the program. For wide-ranging usability, the remote Internetworking (INWK) laboratory uses de facto networking standards and commercial and broad-band Internet connectivity to ensure real-time secure interaction with equipment. A four-tier role architecture consisting of faculty, local facilitators, remote facilitators, and students has been determined appropriate to maintain academic integrity and ensure good quality of interaction with the remote laboratory. A survey employing a five-point scale has been devised to measure the usability of the remote access INWK laboratory.     

Semivolatile organic compounds in window films from lower Manhattan after the September 11th World Trade Center attacks

The September 11th World Trade Center (WTC) terrorist attacks resulted in the large-scale release of contaminants that were deposited on the environment of New York City (NYC). Six weeks after the attacks, samples of an organic film on window surfaces were collected and analyzed for polybrominated diphenyl ethers (PBDE), polychlorinated biphenyls (PCB), polychlorinated naphthalenes (PCN), polycyclic aromatic hydrocarbons (PAH), and organochlorine pesticides (OCPs). Concentrations dropped by an order of magnitude within 1 km of the WTC and reached background concentrations by 3.5 km. Concentrations within 1 km of the WTC averaged 3280 ng/m2 for sigmaPBDE, 900 ng/m2 for sigmaPCB, 33 ng/m2 for sigmaPCN, and 77100 ng/m2 for sigmaPAH. Congener profiles of the sites nearest the WTC suggested a combination of combustion and evaporative sources of all compounds, whereas the background sites exhibited profiles consistent with evaporative sources. PBDE profiles showed enrichment in lower molecular weight congeners near the WTC, suggesting that these congeners were formed as a result of the combustion conditions. Homologue fractions of PCN combustion markers were approximately 2-9 times greater at near WTC sites compared to background NYC. Gas-phase air concentrations were back-calculated from measured film concentrations using the film-air partition coefficient (KFA), and calculated air concentrations followed spatial trends observed in films.     

A Level Set Algorithm for Tracking Discontinuities in Hyperbolic Conservation Laws II: Systems of Equations

A level set algorithm for tracking discontinuities in hyperbolic conservation laws is presented. The algorithm uses a simple finite difference approach, analogous to the method of lines scheme presented in [36]. The zero of a level set function is used to specify the location of the discontinuity. Since a level set function is used to describe the front location, no extra data structures are needed to keep track of the location of the discontinuity. Also, two solution states are used at all computational nodes, one corresponding to the real state, and one corresponding to a ghost node state, analogous to the Ghost Fluid Method of [12]. High order pointwise convergence was demonstrated for scalar linear and nonlinear conservation laws, even at discontinuities and in multiple dimensions in the first paper of this series [3]. The solutions here are compared to standard high order shock capturing schemes, when appropriate. This paper focuses on the issues involved in tracking discontinuities in systems of conservation laws. Examples will be presented of tracking contacts and hydrodynamic shocks in inert and chemically reacting compressible flow.     

Embedded passive components in advanced 3D chips and micro/nano electronic systems

Microsystem Technologies - Electronic devices are shrinking day by day, while the speed and reliability is increasing. At the same time, IC designs and micro/nano electronic systems are becoming...     

The peaking effect in the internal friction of copper single crystals

Journal of Materials Science Letters -     

Review of liquid metal corrosion issues for potential containment materials for liquid lead and lead–bismuth eutectic spallation targets as a neutron source

Lead (Pb) and lead–bismuth eutectic (44Pb–56Bi) have been the two primary candidate liquid metal target materials for the production of spallation neutrons. Selection of a container material for the liquid metal target will greatly affect the lifetime and safety of the target subsystem. For the liquid lead target, niobium–1 wt% zirconium (Nb–1Zr) is a candidate containment material for liquid lead, but its poor oxidation resistance has been a major concern. In this paper, the oxidation rate of Nb–1Zr was studied based on the calculations of thickness loss resulting from oxidation. According to these calculations, it appeared that uncoated Nb–1Zr may be used for a 1-year operation at 900°C at P_O2=1×10^–6 Torr, but the same material may not be used in argon with 5-ppm oxygen. Coating technologies to reduce the oxidation of Nb–1Zr are reviewed, as are other candidate refractory metals such as molybdenum, tantalum, and tungsten. For the liquid lead–bismuth eutectic target, three candidate containment materials are suggested, based on a literature survey of the materials’ compatibility and proton irradiation tests: Croloy 2-1/4, modified 9Cr–1Mo, and 12Cr–1Mo (HT-9) steel. These materials seem to be used only if the lead–bismuth is thoroughly deoxidized and treated with zirconium and magnesium.     

Controlled Synthesis and Stability of Co@SiO2 Aqueous Colloids

Magnetic nanoparticles have emerged as an important class of functional nanostructures with potential applications of magnetic resonance imaging, drug targeting, and bio-conjugation. We have developed a modified sol–gel approach to synthesize stable and well-dispersed magnetic Co@SiO₂ nanoparticles with improved control over shell thickness and larger core diameters. These well-defined Co@SiO₂ core–shell nanoparticles exhibit useful magnetic properties, and the protective silica shell allows them to be surface modified for bioconjugation for various biomedical applications. The core–shell nanoparticles were characterized by transmission electron microscopy, energy-dispersive spectroscopy, elemental mapping, and the line compositional analyses to demonstrate that uniform individually isolated core–shell nanoparticles are obtained through the improved synthetic route.