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31.
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中国石油化工股份有限公司茂名分公司化工事业部乙烯装置随着运行周期的延长,高低压脱丙烷塔和脱丁烷塔结垢严重,分离效果变差,造成丙烯和混合碳四产品的收率降低。通过分析丙烯和混合碳四产品损失大、收率低的原因,提出对策并采取相应措施,从而有效地提高了丙烯和混合碳四产品的收率。 相似文献
33.
Synthesis of superabsorbent resin (SAR) was achieved by a new method, that of direct UV photopolymerization, and in particular the synthesis of a SAR of acrylic acid–potassium acrylate copolymer by UV photopolymerization was investigated. Influences of ratio (mol) of acrylate monomer to acrylic acid monomer, photoinitiators, crosslinking agents, and exposure time of UV light on the water‐absorbent properties were investigated. The results showed that the water absorbency (Q) of SAR based on Irgacure 1700 or Irgacure 1800 was 545–530 mL/g, but under the same conditions Q was 450 mL/g for the SAR based on Irgacure 651. N,N′‐Methylene bisacrylamide, hydroethyl acrylate, and glycerol were used as crosslinking agents, of which N,N′‐methylene bisacrylamide was the most effective. It crosslinked the molecular chains through attending the copolymerization with acrylic acid (AA) and potassium acrylate. When the exposure time was 5 min, the value of Q was 1368 mL/g (the content of N,N′‐methylene bisacrylamide was 100 ppm). © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1618–1624, 2004 相似文献
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A micro-envioment for nerve cells and tissue growth were designed and constructed via surface modification of poly(L-lactide-co-glycolide)(PLGA)
with chitosan and hydroxyapatite(HA). The poly(L-lactide-co-glycolide)/chitosan/hydroxyapatite (PLGA/chitosan/HA) conduits
were manufactured by a combined solvent casting and particulate leaching technique. The conduits were highly porous with an
interconnected pore structure and 76.5% porosity. Micropores with 50–100 micrometer diameter were formed in the conduits.
In vivo application of PLGA/chitosan/HA conduits for reconstruction of 10 mm sciatic nerve defect was assessed by the walking
track analysis, the quantifying of the wet weight of tibialis anterior muscle and the histological assessment. The conduits
in host rats in vivo can not only be an effective in promoting regenerating of nerves but can also lead to favorable nerve
functional recovery.
Funded by the National Natural Science Foundation of China(No.50774096) 相似文献
36.
陈文怡 《武汉理工大学学报(材料科学英文版)》2009,24(1):38-41
A stainless steel/10wt%TiC nanocomposite particles were prepared by high-energy ball-milling method using stainless steel,
carbon and titanium as raw materials. The evolution of phase composition, microstructure and specific surface area of the
stainless steel/TiC nanocomposite particles with increasing ball-milling time in the range of 0–100 h were investigated by
XRD, SEM, TEM and BET techniques. The results showed that the stainless steel/TiC nanocomposite particles were fabricated
when the ball-milling time was longer than 20 h. However, the nanocomposite particles were soldered and agglomerated again
when the ball-milling time was longer than 60 h. The microstructure of the composite particles transformed from lamellar structure
to nanostructure during the repeated process of the cold welding and cracking. TEM image reveals clearly that the in-situ
TiC nanoparticles with grain size of 3–8 nm are in the interior of the stainless steel/TiC nanocomposite particles obtained
by ball-milling 100 h.
Funded by the Natural Science Foundation of Hubei Province (No. 2006ABA304) 相似文献
37.
采用离子注入法制备铜纳米颗粒复合材料,在波长为790 nm的入射激光作用下,运用Z-扫描技术测量了铜纳米颗粒复合材料的非线性光学折射率和非线性光学吸收系数,分析了退火温度对铜纳米颗粒复合材料光学性质的影响。结果表明,随着退火温度的升高,铜纳米颗粒复合材料的颗粒尺寸明显增大,且光学非线性折射率上升。通过改变非晶二氧化硅中铜纳米颗粒复合材料的形状,得到不同的三阶非线性光学系数的特定值。 相似文献
38.
彭丽萍 《武汉理工大学学报(材料科学英文版)》2017,32(4):866-870
Indium doped Zn O films were grown on quartz glass substrates by radio frequency magnetron sputtering from powder targets. Indium content in the targets varied from 1at% to 9at%. In doping on the structure, optical and electrical properties of Zn O thin films were studied. X-ray diffraction shows that all the films are hexagonal wurtzite with c-axis perpendicular to the substrates. There is a positive strain in the films and it increases with indium content. All the films show a high transmittance of 86% in the visible light region. Undoped Zn O thin film exhibits a high transmittance in the near infrared region. The transmittance of indium doped Zn O thin films decreases sharply in the near infrared region, and a cut-off wavelength can be found. The lowest resistivity of 4.3×10~(-4) Ω·cm and the highest carrier concentration of 1.86×10~(21) cm~(-3) can be obtained from Zn O thin films with an indium content of 5at% in the target. 相似文献
39.
S期激酶相关蛋白2(S-phase kinase-associated protein 2,Skp2)与Skp1形成的蛋白质聚合物在调控癌细胞生长周期中发挥着重要作用,而苯并吡喃酮类抑制剂(简称BPC)可有效抑制Skp1-Skp2的形成,但其分子识别机制尚不明确.通过生物信息学统计分析已报道的Skp1-Skp2晶体结构,确定模拟体系后,首先用同源模建对其模拟体系缺失的结构进行补全;然后用分子对接方法获得Skp1-Skp2-BPC复合物模型并用于后续分子动力学模拟.计算结果表明:疏水相互作用是促使BPC特异性结合在由Skp2 W109、D110、L117、I120、R138和W139所构成口袋中的主要驱动力,自由能计算值与实验数据吻合较好.Skp2结合BPC后,结合口袋周围的氢键网络有所加强,口袋附近的溶剂化水分子数量明显减少,导致Skp1-Skp2的体系稳定性下降.体系构象成簇与运动性分析显示,Skp1-Skp2在结合BPC抑制剂后,Skp1的运动更加剧烈,这可能是BPC主要的抑制机理. 相似文献
40.