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991.
The solid solution of CaTi1−x
Zr
x
O3 (x = 0–0.15) was successfully synthesized by the polymerized complex (PC) method. This study has exhibited the advantage of
the PC method to prepare a highly active CaTiO3 compared with the conventional solid-state reaction (SSR) method. More importantly, further improvement in phase purity and
large surface area was achieved by the doping of Zr4+, leading to remarkable enhancement of photocatalytic activities compared to pure CaTiO3. The quantum yield for H2 evolution over the most active photocatalyst, Pt (1.0 wt%)/CaTi0.93Zr0.07O3, was 1.91% and 13.3% in photoreactions from pure water and aqueous ethanol solution, respectively for 0.1 g photocatalyst,
which was about 3.3 and 2.5 times compared to that of PC-derived CaTiO3. 相似文献
992.
Utilizing the solvothermal synthesis technique, lithium intercalated tungsten disulfide LixWS2 with x > 1 was obtained, which was allowed to react with water to the formation of single-molecule-layer suspension of tungsten disulfide. The layered nanocomposites PEG, PEO/WS2, intercalating poly(ethylene glycol) (PEG, MW ≈ 1 × 103, 6 × 103, 1 × 104) and poly(ethylene oxide) (PEO, MW ≈ 3 × 105) into the tungsten disulfide host galleries, were prepared using the improved exfoliation-adsorption technique. It was revealed that the intercalated polymers within the host galleries are in a double-layer arrangement with an interlayer expansion of about 9 Å. Despite high conductivity of the host material, those of the PEG, PEO/WS2 nanocomposites were found to be high in the order of 1 × 10−2 to 10−3 S cm−1 at ambient temperature, resulted from the guest-host charge transfers. 相似文献
993.
994.
995.
基于CAD/CAE/CAM/RP的复杂陶瓷产品快速制造技术 总被引:5,自引:2,他引:5
针对目前手工方式的卫生洁具等复杂陶瓷产品的研发过程,借鉴CAD/CAE/CAM/RP技术在其它制造行业中应用的成功经验,将这些先进制造技术应用于卫生洁具等复杂陶瓷产品的研发中;CAD用于设计产品和模具的模型,CAE用于模拟洁具冲水过程和分析冲水性能,RP用于制作洁具产品的原型,CAM用于加工试用石膏工作模具。就这些技术的应用提出了两种主要方案,并分析了各自的特点。经过实际应用表明:先进制造技术的应用能大大缩短产品研发周期、提高产品质量、降低开发成本。 相似文献
996.
Spherical lithium manganese oxide spinel was synthesized by an ultrasonic spray pyrolysis method, and has been characterized using X-ray diffraction, scanning electron microscopy, transimission electron microscopy and electrochemical cycling at 3 V regions. The LiMn2O4 powders were composed of about 10 nm-sized primary particles. The delivered discharge capacity of the synthesized nano-material was 125 mAh g−1 between 2.4 and 3.5 V and its retention was about 96% upon 50 cycling. From the high resolution transmission electron microscopic study, it was found that structural transition of the parent material did not occur even after the 50th electrochemical cycling on the 3 V region. It seems that the reversible structural change is possible for nanocrystalline LiMn2O4 as observed by the X-ray diffraction and transition electron microscopic observations. 相似文献
997.
Seong‐Ho Choi Min‐Seok Kim Jae Jeong Ryoo Kwang‐Pill Lee Hyun‐Dong Shin Sun‐Hwa Kim Yong‐Hyun Lee 《应用聚合物科学杂志》2002,85(11):2451-2457
Carboxylic acid groups were introduced onto polyethylene (PE) film by radiation‐induced graft copolymerization. Subsequently, the clodextrin glucanotransferase (CGTase) was immobilized on the PE film with a carboxylic acid group. The activity of the immobilized CGTase on PE film was in the range of 0.40–1.04 U/cm2 per min. The production of cyclodextrins (CDs) from corn starch was examined using the CGTase‐immobilized PE film. The production ratios of CDs using CGTase‐immobilized PE film was in the following order: α–CD > β–CD > γ–CD. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2451–2457, 2002 相似文献
998.
炭黑填充硬聚氯乙烯的改性 总被引:1,自引:0,他引:1
为使聚氯乙烯具有抗静电性能,采用加入具有导电性填料的方法,但加入大量的填料,会使硬聚氯乙烯的冲击性能降低,加工性能变差。本文是在以炭黑为填料的基础上,研究不同的改性剂和加工助剂改进硬聚氯乙烯的效果,结果表明,加入冲击改性剂和加工助剂后,大大增加了硬聚氯乙烯的冲击强度,且加工性能也得到改善,同时由于炭黑具有补强效果,其拉伸强度和弯曲强度在加入改性剂后也能满足使用要求。 相似文献
999.
Chunnuan Ji Rongjun Qu Cheng Bo Cao Huo Chen Qiang Xu Changmei Sun Chunhua Wang Huafang Yuan Jun Zhou 《应用聚合物科学杂志》2006,102(6):6054-6059
A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg2+, Ag+, Cu2+, Zn2+, and Pb2+ at various pH values were determined. The maximum adsorption capacities for Hg2+ and Ag+ were 1.56 and 0.75 mmol g?1 respectively. The resin had high selectivity for Hg2+ and Ag+ over the pH range 1.0–7.0. The adsorption capacities for Hg2+ and Ag+ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg2+ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006 相似文献
1000.
注塑级PVC/ABS合金的性能及其加工 总被引:3,自引:2,他引:3
阐述了注塑用聚氯乙烯/丙烯腈-丁二烯-苯乙烯共聚物(PVC/ABS)合金的制备工艺以及合金组成与冲击强度和屈服应力的关系,分析了影响注塑工艺条件的因素,并对体系的热稳定性和流变特性及其影响因素也作了简要的论述。 相似文献