Kinetics of graft copolymerization of methyl methacrylate in wool fibers

The graft copolymerization of methyl methacrylate in wool fibers was investigated in the aqueous LiBr–K₂S₂O₈ system without homopolymer. The rate of grafting and the degree of polymerization of graft polymer were determined on varying the extent of reduction of wool fibers and the concentration of monomer. From the graft copolymerization behavior observed at a given concentration of redox catalysts (LiBr and K₂S₂O₈), the thiol groups in wool fibers were considered to play a role as a sort of catalyst of polymerization, not as the chain transfer agent, and also to give the grafting sites. So, the initiation process of grafting was assumed to be started by d[S·]/dt = k_i[SH]_eff, and the kinetic consideration was found to lead to the following expression in agreement with the experimental results: 1/DP = (k_t/k_p²[M]_fib²)R_p, where d[S·]/dt is the rate of formation of thiol radicals by radicalotropy to ? SH from SO₄^?., OH·, or Br·; k_i, k_p, and k_t are the rate constants of initiation, propagation, and termination, respectively; [SH]_eff and [M]_fib are the concentration of the effective thiol groups and the MMA monomers within the wool fibers, respectively; DP is the average degree of polymerization of graft polymers, and R_p the overall rate of grafting.     

A design of a miniature ultrasonic pump using a bending disk transducer

If a pipe end is faced at a piston-vibrating surface with a small gap in liquid, the liquid is suctioned into the pipe. The present ultrasonic pump is based on this phenomenon to induce flow. For a low-profile configuration, we introduce a 30-mm-diameter bending disk driven by a ring-shaped PZT element bonded on the back of the disk. The disk vibrator is softly supported by frames via O-rings at its circumference, and is worked at the fundamental resonance frequency of 19 kHz of the bending mode. A pipe is installed perpendicularly to the center of the disk vibrator with a small gap. To improve the pump performance, we seek for the optimum vibration distribution of the disk vibrator. When the thickness around the disk center becomes large, the shape of the vibration distribution near the center approaches to a piston vibrator. If the flatness of the vibration distribution is defined as the vibration amplitude just under the pipe edge divided by the vibration amplitude at the disk center, it is 92.0% for the original bending disk. The flatness of the new design became 98.1% as a result of the optimization of the thickness profile of the disk. The pump pressure became high as the flatness became large when the gap size was small enough. The maximum pump pressure of 20.6 kPa was achieved when the vibration velocity at the disk center was 1.0 m/s and the gap size was 10 μm, while the maximum flow rate of 22.5 ml/min. was obtained with the input electrical power of 3.8 W.     

Analysis of Bed Load Equations and River Bed Level Variations Using Basin-Scale Process-Based Modelling Approach

Bed load transport is a key process in maintaining the dynamically stable channel geometry for restoring the form and function of river ecosystems. Bed load consists of relatively large sediment particles that are moved along the streambed by rolling, sliding or saltation. Currently, various empirical correlations are used to estimate bed load transport rates since no single procedure, whether theoretical or empirical, has yet to be universally accepted as completely satisfactory in this aspect. Bed load particles are primarily sourced from river bed materials or banks. The amount of bed load and its spatial distribution contributes significantly to river bed level changes. Hillslope sediment contribution, mostly available to the river in the form of suspended load, also plays an important role in river bed level changes. This study aims to analyse different bed load equations and the resultant computations of river bed level variations using a process-based sediment dynamic model. Analyses have revealed that different bed load equations were mainly deduced from the concept of relating bed shear stresses to their critical values which are highly factored by the slope gradient, water discharge and particle sizes. In this study, river bed level variations are calculated by estimating total surplus or deficit sediment loads (suspended loads and bed loads) in a channel section. This paper describes the application of different widely used bed load equations, and evaluation of their various parameters and relative performances for a case study area (Abukuma River Basin, Japan) using a basin-scale process-based modelling approach. Relative performances of river bed level simulations obtained by using different bed load equations are also presented. This paper elaborates on the modelling approaches for river bed load and bed level simulations. Although verifications were not done due to unavailability of field data for bed load, qualitative evaluations were conducted vis-à-vis field data on flow and suspended sediment loads as well as the bed loads presented in different past studies.     

A scalable advanced RF IC design‐oriented MOSFET model

This article presents a validation of the EKV3 MOSFET compact model dedicated to the design of analogue/RF ICs using advanced CMOS technology. The EKV3 model is compared with DC, CV and RF measurements up to 20 GHz of a 110 nm CMOS technology. The scaling behaviour over a large range of channel lengths and bias conditions is presented. Long‐channel devices show significant non‐quasi static effects while in short‐channel devices the parasitics modelling is critical. This is illustrated with Y‐parameters and f_t vs. I_D in NMOS and PMOS devices, showing good overall RF modelling abilities of the EKV3 MOSFET model. © 2008 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2008.     

Construction of a geothermal power generation model based on characteristics of geothermal steam wells and its applications

Electricity generation in geothermal power plants depends on the characteristics of geothermal steam wells. In this research, a geothermal power generation model was constructed based on the characteristics of the steam well, and the generation of electricity was estimated precisely by the constructed model. Many applications of the geothermal power generation model are introduced. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 141(3): 39–49, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10039     

A simple bidirectional linear microactuator for nanopositioning--the "Baltan" microactuator

A new linear microactuator, using bulk PZT and electro-discharge-machined components, generates a sliding velocity and force of 100 mm/s and 12 mN, respectively, in either direction, and a peak velocity and force of 212 mm/s and 44 mN, respectively. Using a simple combination of two slightly different beams placed in contact with a slider, and vibrated at two different resonance frequencies, 508 and 522 kHz, by a specially designed, axially vibrating piezoelectric element, bidirectional linear motion was obtained. By simply reducing the length of the applied signal, the sliding distance was reduced to 90 nm +/- 2 nm, which could be improved with a variety of control methods. The design offers not only silent operation, slider clamping upon removal of power, and all of the other advantages of piezoelectric actuators, but also the potential to be further reduced in size to sub-mm3 for microrobotics and other applications.     

Finite element method failure analysis of a pressurized FRP cylinder under transverse impact loading

Safety is vital in transport vehicles, especially in case of accidents. The fuel tank must particularly be free from failure. This study discusses impact analyses of pressurized fibre-reinforced plastic (FRP) cylinders by simulation, using the finite element method. The FRP material is defined as orthotropic, and different failure conditions are defined for every failure mode. After failure, the elastic moduli are reduced, based on the appropriate damage mechanics. To represent a fluid-filled vessel, inner pressure is added to the cylinder, and nodal forces are loaded on the inner surface and side section nodes. A bar impactor hits the centre of the cylinder, vertical to the axis. As a result, the relationship between burst mode and inner pressure can be clarified.     

Stability analysis of an acoustically levitated disk

In this paper, a model is developed for the stability analysis of an acoustically levitated disk on the basis of analyzing eddy acoustic streaming and acoustic viscous stress. In the model, the effect of the acoustic streaming outside the boundary layer that is on the surface of the levitated disk is properly taken into account. Also, the calculation of sound field and acoustic viscous stress is limited to the range that has a dominant effect on the stability. By this method, we obtain a quite accurate solution of the stability coefficient. For the small horizontal shift of a large levitated disk, the model is verified by the good agreement between the experimental and theoretical results. By means of this model and relevant experiments, some factors that affect the stability of the levitated disk are investigated, and useful guidelines for design and application are obtained. It is found that the range from the edge to the outermost nodal circle of the disk-shaped vibrator has a large effect on the stability of the levitated disk. To stabilize the levitated disk by acoustic viscous force, the distance between the edge and the outermost nodal circle of the vibrator must be larger than a critical value, which is determined by the driving frequency and the sound velocity of the fluid between the levitated disk and the vibrator. When this condition is satisfied, increasing the distance between the edge and the outermost nodal circle leads to a decrease in the stability. It is also found that the property of the fluid between the levitated disk and the vibrator has a large effect on the stability. It is easier to stabilize the levitated disk in steam than in air, but more difficult to do so in carbon dioxide and hydrogen. In addition, theoretical results show that increasing the weight per unit area of the levitated object increases the stability for a given vibrator velocity. The distribution of the acoustic viscous stress and the dependence of the stability coefficient and the holding force on the horizontal shift of the levitated disk, which are obtained by this study, also are useful to a better understanding of the stability of the levitated disk.