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A silane moisture-cured polyolefin elastomer/linear low-density polyethylene (LLDPE) blend was prepared through a two-step silane-grafting method (Sioplas Process) in an industrial scale twin-screw extruder. The silane-grafted compound was used to make wire and cable coatings. In this work, the effect of some interactive parameters on quality of the products prepared by the above method has been studied, while so far, there have been less experimental investigations. The volume resistivity of cross-linked compound was changed from 2.96 × 1014 to 7.41 × 1014 Ω cm with increasing LLDPE component by maximum 10 wt%. Surface morphology of the product was corrected with reduction in benzoyl peroxide (BPO) concentration from 0.2 wt% to 0.13 wt%. BPO at this level acted as an initiator in grafting reaction of vinyl trimethoxysilane. The curing condition and specimen preparation method by injection molding and/or extrusion were factors which influenced the hot-set test results at 200 °C. The results of tensile and elongation studies showed a maximum value of 9 MPa and 397% for the tests, after 6 h curing. With increases in curing time at a specified temperature, the gel content of the cross-linked compound was increased and reached its maximum value. The maximum gel content values were found to be approximately 60%, 80%, and 82% at temperatures of 25, 60, and 85 °C, respectively. The hardness, density, and tear strength of the samples did not vary significantly with the curing temperature.
相似文献Precipitation is one of the most important components of the hydrologic cycle as it is required for multi-objective applications including flood estimation, drought monitoring, watersheds management, hydrology, agriculture, etc. Therefore, its estimation and modeling via a suitable method is a challenging task for hydrologists. The present study seeks to model monthly precipitation at two stations located in Iran. Two artificial intelligence (AI)-based models consisting of multivariate adaptive regression splines (MARS) and k-nearest neighbors (KNN) were used as the modeling techniques. In doing so, nine single-input scenarios under limited climatic data are implemented using minimum, maximum, and mean air temperatures, dew point temperature, station pressure, vapor pressure, relative humidity, wind speed, and antecedent precipitation data. The attained results illustrate that the performance of single MARS and KNN is relatively poor when modeling the monthly precipitation. Additionally, this study develops hybrid models to enhance the precipitation modeling through combining the MARS and KNN models with three diverse types of the time series (TS) models, namely autoregressive (AR), moving average (MA), and autoregressive moving average (ARMA). The most important justification for integrating the models applied is that the AI and TS-based models are respectively capable of modeling the non-linear and linear terms of the hydrological variables such as precipitation. It is therefore necessary to be considered both of the aforementioned terms in the modeling procedure. A performance comparison of the single and hybrid models denotes the higher accuracy of hybrid models than the single ones. However, the hybrid models generated by combining the KNN and the TS models used are the best-performing models.
相似文献Floods are common and recurring natural hazards which damages is the destruction for society. Several regions of the world with different climatic conditions face the challenge of floods in different magnitudes. Here we estimate flood susceptibility based on Analytical neural network (ANN), Deep learning neural network (DLNN) and Deep boost (DB) algorithm approach. We also attempt to estimate the future rainfall scenario, using the General circulation model (GCM) with its ensemble. The Representative concentration pathway (RCP) scenario is employed for estimating the future rainfall in more an authentic way. The validation of all models was done with considering different indices and the results show that the DB model is most optimal as compared to the other models. According to the DB model, the spatial coverage of very low, low, moderate, high and very high flood prone region is 68.20%, 9.48%, 5.64%, 7.34% and 9.33% respectively. The approach and results in this research would be beneficial to take the decision in managing this natural hazard in a more efficient way.
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