Flow structure and scour around circular compound bridge piers – A review

Large amount of literature is presently available on the topic of scour around uniform piers and its control. However, relatively fewer studies have been carried out so far on the topic of flow field and scour around compound piers. The state of art on the topic of flow structure and scour around circular compound piers is presented herein. The available literature reveals that variations in foundation and pier geometry significantly affect the maximum depth of scour and its temporal variation. In case of compound piers the scour depth is highly sensitive to the change in elevation of the top surface of the foundation well. As compared to uniform piers, a reduction is observed in maximum depth of scour around compound pier when the top surface of the well is kept below the general level of river bed. These observations however are yet to be quantified. Results from an experimental study on flow field around the compound piers are also presented.     

An it Architecture for Nimble Organizations: Managing Access from Cyberspace

In today's world of “co-opetition” among organizations, where one organization competes and cooperates simultaneously with business partners, all organizations must have IT architectures that are nimble and flexible. This article takes a look at one important aspect in achieving a flexible IT architecture: access management of information resources over the Web. It describes an access management architecture that can change as business does and recommends how best to implement this nimble architecture.     

Effect of CuO on the sintering and cryogenic microwave characteristics of (Zr0.8Sn0.2)TiO4 ceramics

The effect of CuO on the sintering temperature, microstructure and microwave dielectric properties of (Zr_0.8Sn_0.2)TiO₄ (ZST) modified with 1 wt% of ZnO has been investigated. Microwave dielectric properties of ZST ceramics are measured from cryogenic to room temperatures (15–290 K). Crystallite sizes of sintered ZST ceramics as derived from XRD are in the 30–50 nm range. The addition of CuO effectively reduced the sintering temperature to 1300 1C, possibly due to liquid-phase effects. Addition of CuO did not cause any secondary phases up to 1.5 wt% of CuO. The dielectric constant (ε_r) and temperature coefficient of resonant frequency (ε_f) of ZST ceramics do not significantly vary with temperature, whereas the unloaded quality factor (Q_u) changes noticeably. It is found that the Q_u factor of the sample without CuO decreased with increase in temperature, whereas the samples with addition of CuO up to 1.0 wt% showed less dependence on temperature. The Q_u factor of CuO-free ZST is 15,000 and that of ZST with 0.5 wt% of CuO is 11,800 at 15 K. The Q_u factor while measured at room temperature ranged between 2900 and 7000. Efforts were made to understand whether the increase in Q_u factor at both cryogenic and room temperatures is the result of intrinsic or extrinsic factors.     

Effect of gamma irradiation on structural,morphological and optical properties of thermal spray pyrolysis deposited CuO thin film

This study reports the influences of gamma irradiation (GI) in the range of 20–100 kGy on CuO thin films via thermal spray pyrolysis technique on the glass substrates. The results demonstrate significant influences of GI on the crystallographic, microstructural and optical characteristics of CuO thin films. The obtained XRD results showed that the crystallinity of the films deteriorates by gradually decreasing crystallite size (from 59.13 to 46 nm) as applied gamma doses increases. However, the basic monoclinic crystal structure remains same. The dislocation density and lattice strain increased with the rise of GI absorbed dose due to the creation of defects. The values of number of crystallites per unit surface area increased as dose increased indicating the abundance of crystallization of nano CuO thin films. A UV–Vis–NIR spectrophotometer was utilized to determine the optical properties and obtained results indicated that the optical energy band gap (OBG) energies reduced from 2.00 to 1.72 eV as the doses increased from 0 to 100 kGy. No distinctions of the monoclinic phase of virgin CuO thin film have been perceived under applied absorbed doses, notwithstanding the slight deterioration of the crystallinity and narrowing the OBG.     

Novel organic–inorganic hybrid coatings prepared by the sol–gel process: corrosion and mechanical properties

(Hyperbranched polyurethane‐urea)/[(3‐aminopropyl)triethoxysilane]‐ZnO (HBPUU‐APTES‐ZnO) hybrid coatings were synthesized using an inexpensive mixing technique by varying the APTES‐modified ZnO concentration. The mechanical and surface properties of the hybrid coating films were studied and compared with unmodified and modified ZnO. The corrosion, solvent and abrasion resistance show significant enhancement in HBPUU‐APTES‐ZnO hybrids and their properties are increased with increasing APTES‐ZnO concentration. This hybrid coating has opened up an opportunity for automotive topcoat application. Copyright © 2012 Society of Chemical Industry     

Two-step sintering technique for enhancing mechanical and oxygen permeation properties of dual-phase oxygen transport membranes

The present work involved the application of a two-step sintering (TSS) technique for typical Ce_0.9Gd_0.1O_2?δ–La_0.6Sr_0.4Co_0.2Fe_0.8O_3–δ (GDC–LSCF) composites and its effect on the microstructure and resultantly mechanical and O₂-permeating properties. The samples obtained by conventional sintering (CS) performed at 1100, 1250, and 1400 °C for 3 h exhibited maximum flexural strength and hardness values of 142 MPa and 8.71 GPa, respectively. However, the application of a TSS procedure produced fine-grained microstructures with improved mechanical properties. In particular, with the use of a typical 1250/1200 TSS protocol, increases of approximately 31 % and 7% in the flexural strength and hardness values, respectively, were observed compared to those obtained using the CS method. Moreover, thick-film (～ 60 μm) GDC–LSCF membrane prepared by tape casting and the TSS technique showed remarkably 1.5–2 times higher oxygen permeation flux than membrane sintered by CS method. The results are discussed and explained in detail.     

Study of physicochemical properties of flutamide-loaded Ocimum basilicum microspheres with ex vivo mucoadhesion and in vitro drug release

Drug which shows extensive first pass effect is difficult task that, needs to be solved by formulators in the pharmaceutical science. The low oral bioavailability (49%) of flutamide may be due to poor wettability, low aqueous solubility and extensive first pass effect. The aim of present investigation was to prepare flutamide loaded microspheres and incorporate it into suppositories for rectal delivery to avoid first pass effect and enhance residence time. Flutamide loaded mucoadhesive microspheres of Ocimum Basilicum mucilage (OBM) were prepared using spray drying and characterized by percent production yield, encapsulation efficiency, particle size, zeta potential, polydispersity index, DSC, SEM, XRPD, in vitro drug release and stability studies. Moreover, ex vivo mucoadhesion was investigated using falling liquid film technique to determine the adhesion of microspheres to sheep rectal mucosa. The microspheres had nearly spherical shape and size about 2.53?μm. The encapsulation efficiency and mucoadhesion of optimized formulation MBF10 were found to be 69.6?±?2.3% and 89.01?±?2.18%, respectively. Percent CDR of optimized flutamide loaded mucoadhesive microspheres was found to be 88.7?±?1.3 at 7?h. In conclusion, OBM microparticles based suppository could be used to deliver drug through rectal delivery.