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101.
Journal of Porous Materials - Zeolitic imidazolate frameworks (ZIFs) consist of transition metal ions (Zinc or Cobalt) and imidazolate (Im) linkers in tetrahedral coordination surrounded by...  相似文献   
102.
Journal of Superconductivity and Novel Magnetism - Double perovskite La1.75Ca0.25MnMO6 (with M?=?Ti and Fe) systems were elaborated employing a solid-state reaction method. The...  相似文献   
103.
    
BACKGROUND: Three annual Atriplex species—A. hortensis var. purpurea, A. hortensis var. rubra and A. rosea—growing on soil with various levels of the heavy metals copper, lead, nickel, and zinc, have been investigated. RESULTS: Metal accumulation by Atriplex plants differed among species, levels of polluted soil and tissues. Metals accumulated by Atriplex were mostly distributed in root tissues, suggesting that an exclusion strategy for metal tolerance widely exists in them. The increased concentration of heavy metals in soil led to increases in heavy metal shoot and root concentrations of Ni, Cu, Pb and Zn in plants as compared to those grown on unpolluted soil. Accumulation was higher in roots than shoots for all the heavy metals. None of the plants were suitable for phytoextraction because no hyperaccumulator was identified. However, plants with a high bioconcentration factor and low translocation factor have the potential for phytostabilization. Similarly, the correlation between metal concentrations and translocations in plants (BCFs and TFs) using a linear regression was also statistically significant. CONCLUSION: Among the plants studied, var. purpurea was the most efficient in accumulating Pb and Zn in its shoots, whereas var. rubra was most suitable for phytostabilization of sites contaminated with Cu and Ni. Copyright © 2011 Society of Chemical Industry  相似文献   
104.
    
The Brazilian Amazonian rain forests are under imminent threat of serious degradation and ultimately deforestation. Human activities such as selective logging are an important cause. Selectively logged locations are difficult to detect from medium-resolution Landsat images, due to their relatively small sizes and subtle spatial patterns. Spectral linear unmixing provides an effective tool for the purpose. The orientation of geometrically corrected images, however, artificially introduces zero-reflectance background pixels. These change the variance–covariance structure of the image bands and hinder the identification of pure endmembers. In this study, we compare image cropping and image rotation as two alternative approaches. Selectively logged forests were detected in northern Rondônia state, north-western Mato Grosso state and south-eastern Amazonas state in Brazil by applying spectral unmixing. The study shows that image rotation is a better approach as it preserves the image extent and thus provides information on forest degradation over a wider region. Spatial statistical analysis of the detected locations shows strong clustering within the study area. We conclude that the endmembers used in this study represent basic components of a degraded forest environment. As spectral unmixing of remote-sensing images avoids collection of field data, it may broadly be applied towards other Amazonian regions as well.  相似文献   
105.
    
Porous polyaniline (PANI) was prepared through an efficient and costeffective method by polymerization of aniline in the NaCl solution at room temperature. The resulting PANI provided large surface area due to its highly porous structure and the intercrossed nanorod, resulting in good electrochemical performance. The porous PANI electrodes showed a high specific capacitance of 480 F·g^-1, 3 times greater than that of PANI without using the NaCl solution. We also make chemically crosslinked hydrogel film for hydrogel polymer electrolyte as well as the flexible supercapacitors (SCs) with PANI. The specific capacitance of the device was 234 F·g^-1 at the current density of 1 A·g^-1. The energy density of the device could reach as high as 75 W·h·kg^-1 while the power density was 0.5 kW·kg^-1, indicating that PANI be a promising material in flexible SCs.  相似文献   
106.
为执行长期监视任务的便携式遥测系统供电.向人们提出了有趣的设计挑战。电池不适合于某些关键性应用,且在这些环境中,设计人员一般用无线感应链路来传输功率与数据。感应链路由一个驱动固定初级线圈的射频发射器与一个为便携式装置提供电源的松耦合次级线圈组成。对设计工程师来说.测量发射功率相当重要.因为它会限制设计人员可包含至便携式装置中的电路数量。但不幸的是,传统测试设备不适合执行该任务.  相似文献   
107.
108.
The present work aims at synthesis and study the bioactivity of porous alumina scaffolds coated with calcium pyrophosphate. Characterization of the formed calcium pyrophosphate and the coated scaffolds was assessed by X‐ray diffraction analysis and scanning electron microscope examinations. The in vivo studies revealed the ability of the porous scaffolds to regenerate bone tissue in femur defects of albino rats. Histological analysis showed that the defect is almost entirely filled with new bone. The formed bone is characterized as a mature bone. The produced bone grafts are intended to be used as bone substitute or bone filler.  相似文献   
109.
It is well known that for the AISI 304 austenitic stainless steel some parameters such as temperature, strain rate, material anisotropy and loading path are the main factors which strongly affect the kinetic of transformation induced plasticity (TRIP) in this material. In literature, tensile and compression tests represent the commonly experimental tools studied on this material. Under such type of loading, dissymmetry plastic behavior was obtained due to the martensitic kinetic evolution.The aim of the present work is to highlight the role of the TRIP phenomenon on the initial material anisotropy of the AISI 304 material using appropriate experimental framework. The cross-coupled effect of the phase transformation on initial anisotropy is studied through special loading test (simple shear test (SST)) conducted at various temperatures.  相似文献   
110.
Olive mill sludge (OMS), a by-product resulting from natural evaporation of olive oil processing effluent, poses a major environmental threat. A current cost-effective practice of OMS management is composting. A mixture of OMS (60%) with poultry manure (PM) was successfully composted for 210 days. During the process, effluents of olive oil mill and confectionary were used to keep moisture at optimal level (40-60%). Biological indicators reflecting stability of the compost (microbial biota respiration and enumeration, and germination index) were analysed for the assessment of the product quality. The composted mixture showed a high microbial activity with a succession of microbial populations depending on the temperature reached during the biodegradation. The pathogen content from PM decreased with composting as did phytotoxic compounds. Phenols and lipids were reduced, respectively, by 40% and 84% while germination index increased with composting progress. Fourier transform infrared (FTIR) spectroscopic analysis revealed that the final compost improved the aromatic content compared to the starting materials, with a decrease in aliphatic groups and a reduction in the easily assimilated components by the microflora acting during the biological process. The final compost was characterized by relatively high organic matter content (26.21%), a low C/N ratio (16.21), an alkaline pH (8.32), a relatively high electrical conductivity (9.21mS/cm) and a high level of nutrients. The germination index for Lepidium sativum L. was 87.71% after 210 days of composting, showing that the final compost was not phytotoxic.  相似文献   
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