Electrochemical copolymerization of m-toluidine and o-phenylenediamine

Electroactive copolymers of m-toluidine (MT) and o-phenylenediamine (OPD) were prepared electrochemically in aqueous sulfuric acid by potential cycling and characterized with cyclic voltametry, in situ conductivity measurements and FT-IR spectroscopy. The voltammograms of the copolymers exhibit different behavior for different concentrations of OPD in the comonomer feed. At optimum conditions the resulting poly(OPD-co-MT) shows an extended useful potential range of the redox activity as compared to the corresponding homopolymers. The effect of scan rate and pH on the electrochemical activity was studied. The copolymer was electrochemically active even at pH 8.0. The stability of the copolymer film was also tested. The copolymer has a potential region of maximum conductivity different from that of PMT and POPD. The conductivity of the copolymer is between the conductivity of the homopolymers. The vibrational bands at 3122/3450 and 2922/875 cm⁻¹ in the FT-IR spectra of the copolymer indicate the presence of both OPD and MT units, respectively, in the copolymer backbone.     

Correction to a novel framework for rapid diagnosis of COVID-19 on computed tomography scans

Pattern Analysis and Applications - A correction to this paper has been published: https://doi.org/10.1007/s10044-021-00969-x     

A novel fault ride-through technique for grid-connected Photo Voltaic energy systems

In this article, a novel fault ride-through technique has been implanted with a double control loop method. This method is implemented with voltage-source converters, where the active and reactive power could be easily done with the voltage control loop and inherent current control loop. The proposed system has been implemented to grid-connected photovoltaic systems, and the results have been explored and compared with the existing techniques. An additional control strategy is implemented successfully for satisfactory performance of the system during low irradiance periods, and the system is made capable to provide Q-support to the grid according to the system operators request with the help of Q-set point.     

Liposomal diltiazem HCl as ocular drug delivery system for glaucoma

In this study, unilamellar liposomal vesicles of diltiazem HCl (DH) were prepared using either reversed phase evaporation (REV) or proliposome methods. Soya phosphatidylcholine (SPC) was used for preparing the liposomes, and the vesicles were rigidified using cholesterol (Chol) or cetyl alcohol (CA) in different molarities. The major differences in both the entrapment efficiency percent (EE%) and drug release were evaluated as a function of the method of preparation, Chol or CA contents, and charging lipids. Moreover, the morphology of the vesicles was confirmed by transmission electron microscopy. The effects of Chol or CA incorporation into the liposomes were discussed based on thermal analysis. The in vivo evaluation of liposomal DH was assessed using intra-ocular pressure (IOP), reducing effects in rabbit eyes. Liposomes prepared via REV exhibited higher EE% and lower release rates when compared with those prepared from proliposomes. The incorporation of either Chol or CA in the liposomes enhanced the EE% and decreased the release rates; however, Chol yielded higher results than CA. In addition, both dicetyl phosphate (DCP; negative charge inducer) and stearyl amine (SA, positive charge inducer) decreased the EE% and increased the DH release rate. The in vivo antiglaucoma effects of the liposomes were calculated according to the area above the IOP/Time curve, the maximum response and the time for the maximum response and were compared with effects of the DH solution. The results were in the following order: DH solution?相似文献   

Evaluation of the physical and antimicrobial properties of silver doped hydroxyapatite depending on the preparation method

In the present study, the effect of the preparation method on the physical and antibacterial properties of silver doped hydroxyapatite (HAp/Ag) samples was investigated. HAp/Ag with 0.1–5 % of silver was prepared using two different modified wet chemical precipitation methods. A comparison of thermal stability and thermodynamical properties indicated that the thermal stability and sintering temperature of HAp/Ag were higher than those of pure hydroxyapatite if Ca(NO₃)₂·4H₂O, AgNO₃, NH₄OH and (NH₄)₂HPO₄ were used as raw materials. Phase composition and silver release were determined by XRD and ICP-MS. The study showed that, after 50 h in simulated body fluid 0.8–1.8 % of silver of the total silver amount was released from compact HAp/Ag scaffolds, and release kinetics strongly depended on the HAp/Ag preparation method. In vitro antibacterial activity of samples from each method against the bacterial strains Staphylococcus epidermidis and Pseudomonas aeruginosa was approved. Results showed that, in the case of using Ca(OH)₂, H₃PO₄ and AgNO₃ as raw materials for HAp/Ag synthesis, higher antibacterial activity towards both bacterial strains could be obtained.     

Porous Si/SiC Composite Based on Nonwoven Cellulosic Fabrics: Synthesis and Characterization

The microstructure and properties of porous Si/silicon carbide (SiC) composites manufactured from nonwoven cellulosic fabrics have been investigated. A fibrillar reaction product with a microstructure reproducing the initial preform morphology consisting of β-SiC and unreacted Si was obtained. Improvement of strength is expected to be achieved by increase of SiC content and reduction of porosity.     

Transient Analysis on Forced Convection Phenomena in a Fluid Valve Using Nanofluid

A transient numerical study is conducted to investigate the transport mechanism of forced convection in a fluid valve filled with water-CuO nanofluid. The flow enters from one inlet at the left with uniform temperature and velocity T _i and U _i , respectively, but can leave the valve through two outlets at the right. The upper and lower boundaries of the valve are heated with constant temperature T _h , while the remaining walls are perfectly insulated. The numerical approach is based on the finite element technique with Galerkin's weighted residual simulation. Solutions are obtained for fixed Prandtl number (Pr = 1.47), Reynolds number (Re = 100), and solid volume fraction (φ = 5%). The streamlines, isotherm plots, flow rate and the local Nusselt number (Nu _local ) at both heated phases, the average Nusselt number (Nu) for base fluid, and nanofluid with the variation of nondimensional time (τ) are presented and discussed. It is found that the rate of heat transfer in the fluid valve reduces for longer time periods.