Formulation and characterization of glass–ceramics based on Na2Ca2Si3O9–Ca5(PO4)3F–Mg2SiO4-system in relation to their biological activity

Glasses having a chemical composition based on combeite [Na₂Ca₂Si₃O₉]–fluoroapatite [Ca₅(PO₄)₃F] and forsterite [Mg₂SiO₄] system were crystallized through controlled heat-treatment. Two forms of sodium calcium silicate e.g. combeite Na₂Ca₂Si₃O₉ and pectolite Na₂CaSi₃O₈, were formed together with diopside (CaMgSi₂O₆) and monticellite (CaMgSiO₄) in addition to fluoroapatite (Ca₅(PO₄)₃F) phases by thermal treatment of the glasses. Selected glass–ceramics were exposed to a simulated body fluid solution (SBF) which is close to human plasma for 3 weeks. Energy dispersive X-ray analysis (EDX) and inductive coupled plasma (ICP) analysis confirmed the formation of an apatite layer which indicate bioactivity in the all crystallized sample. A decreasing of surface bioactivity with increasing Mg₂SiO₄/Na₂Ca₂Si₃O₉ replacement was observed as indicated by the decrease in the amount of apatite layer on the surface of the crystallized specimens. The Vicker’s microhardness of the studied glass–ceramic materials are between 5,047 and 6,781 MPa.     

The Helsinki Rules,the UN Watercourses Convention and the Berlin Rules: Perspectives on International Water Law

Shared water resources remain the most important area without a universal treaty regulating the uses and protection of such resources. This is notwithstanding the extensive work of two scholarly non-governmental organizations, the Institute of International Law and the International Law Association, as well as the work of the International Law Commission of the United Nations. The work of those institutions resulted in some basic international water law rules, such as the Helsinki and Berlin Rules, and the United Nations Watercourses Convention. The paper analyzes those instruments, discusses the basic areas of similarities and differences among them, and examines the basic challenges facing international water law.     

Binder addition methods and binder distribution in high shear and fluidised bed granulation

Fluidised beds and high shear mixers are both important in industrial granulation. The binder addition method (pouring, melt-in, spraying) affects the growth and properties of granules and is therefore of vital importance to the fundamental understanding of this detailed process. Non-uniformity of binder distribution is well known in high shear melt granulation, however, there is limited literature surrounding binder distribution in fluidised bed granulation. It was therefore the aim of the paper to compare the binder distribution using alternative addition methods in both high shear mixer and fluidised bed.In this work two binder addition methods, ‘wet’ and ‘dry’, in a fluidised bed and high hear mixer were used to successfully produce granules with a typical pharmaceutical size, 150-300 μm. The granules were analysed for final binder distribution in different size classes using Patent V blue dye and ultra-violet spectrometry.All binder addition methods supported previous work showing non-uniformity of binder distribution throughout the size classes. High shear mixer results show great similarity in binder content whichever binder addition method was chosen. This is likely to be due to the same mechanisms occurring due to the impeller forces in the process, mean while the fluidised bed results show little similarity. The binder distribution by mass is also investigated and shows that although most studies show a relative higher binder content in the larger size classes that actually the majority of binder can instead be found around the mean size of the batch.     

Catalytic and Photopolymerization of Isoprene

Stereoregularity of photopolymerized isoprene was determined by NMR spectroscopy and compared with the stereoregularity of polyisoprene which was prepared using n-butyllithium catalyst. It was found that photopolymerization of isoprene gave a high percentage of trans-1,4, while the n-Buli catalyst gave a high percentage of cis-1,4 structure.     

Frequency assignment problem in satellite communications using differential evolution

Satellite communications technology has a tremendous impact in refining our world. The frequency assignment problem is of a fundamental importance when it comes to providing high-quality transmissions in satellite communication systems. The NP-complete frequency assignment problem in satellite communications involves the rearrangement of frequencies of one set of carriers while keeping the other set fixed in order to minimize the largest and total interference among carriers. In this paper, we present a number of algorithms, based on differential evolution, to solve the frequency assignment problem. We investigate several schemes ranging from adaptive differential evolution to hybrid algorithms in which heuristic is embedded within differential evolution. The effectiveness and robustness of our proposed algorithms is demonstrated through solving a set of benchmark problems and comparing the results with a number of previously proposed techniques that solve the same problem. Experimental results show that our proposed algorithms, in general, and hybrid ones in particular, outperform the existing algorithms both in terms of the quality of the solutions and computational time.     

The prototype high-resolution Fly''s Eye cosmic ray detector

The High-Resolution Fly's Eye (HiRes) is an observatory for the highest energy cosmic rays. It detects the nitrogen fluorescence light induced by the passage of giant cosmic ray extensive air showers through the atmosphere. A two-site prototype of the observatory was operated from September 1994 to November 1996. In this paper we describe the components of that detector, and the procedures used to calibrate the detector and characterise the atmosphere. Data collected by the HiRes prototype are being used for physics studies, including an analysis of the cosmic ray mass composition in the energy range from 10¹⁷ to 10¹⁸ eV.     

Optimal architecture of heat generating pieces in a fin

This paper documents the optimal architecture of heat generating pieces connected to and cooled in a circular-shaped fin. Relying on the constructal theory, the optimal distribution of multiple heat sources is obtained by minimizing the thermal resistance of the fin. Since the heat sources are contemplated as electronic devices with uniform heat generation, the minimization of the thermal resistance is indicated by minimization of the hot spot (peak) temperature. Temperature fields in the fin and in the heat sources are calculated using a finite elements approach of MATLAB PDE toolbox. Comparison among the considered configurations reveals that the regular configurations of the heat sources commonly used in cooling industry are not optimal and must be avoided. Optimal configurations such as triangular arrangement of heat sources are proposed to replace the unfavorable configurations.     

Evaluation of Heat Treatment Effect on the Tensile Strength of Mild Steel Welded Joints Using Ultrasonic Testing

Russian Journal of Nondestructive Testing - The tensile strength of welded joints subjected to thermal stresses degrades with age. Tensile strength is generally assessed using tensile test, which...     

Production of bacterial cellulose in static conditions by a simple fed-batch cultivation strategy

The current study investigated fed-batch cultivation for the increased productivity of bacterial cellulose (BC) sheets by Gluconacetobacter hansenii PJK in static conditions using chemically defined medium and waste from beer fermentation broth. Fermentations were carried out in a 3 L jar fermenter without any impeller for 30 days. In the proposed fed-batch cultivation, 500 mL of the medium was initially inoculated with pre-culture in a jar fermenter while a fresh medium was fed periodically. BC production was also done by using batch cultivation which was used as a control for comparison. The results obtained revealed an overall of 2–3 times increase in BC production in fed-batch cultivation compared to batch cultivation after 30 days of cultivation. During these experiments, it was found that waste from beer fermentation broth is a superior medium for the BC production using fed-batch cultivation. The production of water soluble oligosaccharides as useful by-products was also monitored during these investigations. Fed-batch cultivation and waste from beer fermentation was also found superior for the production of these by-products. According to literature search and to the best of our knowledge, it is the first report of using fed-batch cultivation for BC production in static conditions.     

In vitro bioactivity of glass–ceramics of the CaMgSi2O6–CaSiO3–Ca5(PO4)3F–Na2SiO3 system with TiO2 or ZnO additives

Glass–ceramic materials based on diopside [CaMgSi₂O₆]–wollastonite [CaSiO₃]–fluoroapatite [Ca₅(PO₄)₃F]–sodium silicate [Na₂SiO₃] system with TiO₂ or ZnO additives were successfully prepared and examined in vitro, by using a simulated body fluid (SBF) solution, to be suitable for restorative dental and bone implant materials. In vitro bioactivity of the glass–ceramics was examined by using scanning electron microscopy equipped with energy dispersive X-ray detectors (EDAX–SEM) and inductive coupled plasma emission spectroscopy (ICP).