Microwave-assisted urea-modified sorghum biomass for Cr (III) elimination from aqueous solutions

The present study concentrated on the use of an agro-waste biodegradable sorghum biomass in its simple and modified forms for the binding of Cr (III) ions. A relatively new method of modification was adopted using urea under microwave irradiation. FTIR analysis showed the presence of oxygen and nitrogen bearing functional groups in unmodified (UMS) and modified (MS) sorghum biomass. The appearance of new bands and shifts in the peaks confirmed the modification. The influence of different process parameters such as the adsorbent dose, solution pH, contact time, agitation speed and initial metal ion concentration was studied thoroughly to evaluate optimum conditions for adsorption. Maximum adsorption for Cr (III) ions occurred at pH 5.0–6.0 using UMS and MS. Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models in a non-linear fashion were used to explain the phenomenon. Maximum adsorption capacity was 7.03 and 16.36 mg of Cr (III) per gram of UMS and MS, respectively. Adsorption mechanism was explored by pseudo-first- and pseudo-second-order kinetic models, and it was found that the process followed pseudo-second-order kinetics. Thermodynamic study indicated the process favorability. The study concluded that urea modification under microwave irradiation produces a non-toxic and more effective adsorbent for Cr (III) remediation by inducing new nitrogen bearing functional groups to sorghum biomass.     

Forced migration of soluble and suspended materials by freezing front in aqueous systems

Migration of soluble and suspended materials by directional freezing of aqueous systems has been studied qualitatively. Slow freezing was employed vertically as well as horizontally through solutions and suspensions. In all cases, the impurities (soluble salts as well as suspended materials) were appreciably forced out by dynamic freezing front. The phenomenon worked for concentrating/separating inorganic ions, soluble organic compounds and dyes in synthetic solutions as well as in natural streams. Various analytical techniques were employed to monitor the migrating species through the freezing media. It was found that separation efficiency depends on different factors like rate of cooling, pH and concentration. Model experiments were designed and exercised successfully to employ the technique for treatment of dye-polluted water.     

The Millimeter Wave Radiation of a Dielectric Leaky-Wave Antenna Coupled with a Diffraction Grating: Broad-Face Interaction

The millimeter wave radiation of a dielectric leaky-wave antenna (DLWA) coupled with a metallic diffraction grating with a sinusoidal height profile is experimentally investigated. The interaction between dielectric and grating is contactless and it is from the broad-face of the dielectric line. The measured field patterns are compared with the simulated HFSS patterns. Antenna parameters such as polarization, HPBW, cross-polarization and side lobe levels are measured. The effects of the geometrical parameters of the grating to the radiation are also investigated. Some results are compared with a DLWA which has another diffraction grating profile shape (rectangular). The investigated antenna can be used as a frequency scanning antenna in mm-wave radars because it has low cross and side lobe levels and narrow beam width.     

Photochemical Degradation of Recycled High-Impact Polystyrene

Photooxidative aging of high-impact polystyrene sheets at 25°C was followed for different intervals of 25, 40, 50, 75, and 80 h. Five different types of samples were used, viz. virgin, and recycled once, twice, three, and four times. The optical properties of exposed samples exhibited changes as a result of discoloration. The transmittance and reflection deceases whereas absorbance increases with increasing recycling of high-impact polystyrene.     

Suppression of TRPV1/TRPM8/P2Y Nociceptors by Withametelin via Downregulating MAPK Signaling in Mouse Model of Vincristine-Induced Neuropathic Pain

Vincristine (VCR) is a widely used chemotherapy drug that induced peripheral painful neuropathy. Yet, it still lacks an ideal therapeutic strategy. The transient receptor potential (TRP) channels, purinergic receptor (P2Y), and mitogen-activated protein kinase (MAPK) signaling play a crucial role in the pathogenesis of neuropathic pain. Withametelin (WMT), a potential Phytosteroid isolated from datura innoxa, exhibits remarkable neuroprotective properties. The present investigation was designed to explore the effect of withametelin on VCR-induced neuropathic pain and its underlying molecular mechanism. Initially, the neuroprotective potential of WMT was confirmed against hydrogen peroxide (H₂O₂)-induced PC12 cells. To develop potential candidates for neuropathic pain treatment, a VCR-induced neuropathic pain model was established. Vincristine (75 μg/kg) was administered intraperitoneally (i.p.) for 10 consecutive days (day 1–10) for the induction of neuropathic pain. Gabapentin (GBP) (60 mg/kg, i.p.) and withametelin (0.1 and 1 mg/kg i.p.) treatments were given after the completion of VCR injection on the 11th day up to 21 days. The results revealed that WMT significantly reduced VCR-induced pain hypersensitivity, including mechanical allodynia, cold allodynia, and thermal hyperalgesia. It reversed the VCR-induced histopathological changes in the brain, spinal cord, and sciatic nerve. It inhibited VCR-induced changes in the biochemical composition of the myelin sheath of the sciatic nerve. It markedly downregulated the expression levels of TRPV1 (transient receptor potential vanilloid 1); TRPM8 (Transient receptor potential melastatin 8); and P2Y nociceptors and MAPKs signaling, including ERK (Extracellular Signal-Regulated Kinase), JNK (c-Jun N-terminal kinase), and p-38 in the spinal cord. It suppressed apoptosis by regulating Bax (Bcl2-associated X-protein), Bcl-2 (B-cell-lymphoma-2), and Caspase-3 expression. It considerably attenuated inflammatory cytokines, oxidative stress, and genotoxicity. This study suggests that WMT treatment suppressed vincristine-induced neuropathic pain by targeting the TRPV1/TRPM8/P2Y nociceptors and MAPK signaling.     

Discrimination in the 21st century: Are science and the law aligned?

Although scholars agree that traditional forms of discrimination have generally been supplanted by subtler interpersonal manifestations of discrimination, it is yet unknown whether targets of these behaviors or the American judicial branch recognize such negative behaviors as violations of extant law. Extending research and theory, we propose that denigrating messages toward women and ethnic minorities (i.e., microaggressions) emerge in workplace interactions and are sometimes interpreted as discrimination. Specifically, this research explores the presence, severity, and frequency of microaggressions that appear in a random sample of race and gender discrimination cases in federal court dockets since the year 2000. The results suggest that microinsults, microinvalidations, and microassaults are reported in a variety of discrimination claims. However, only overt and intentional forms of microaggressions (microassaults) increased the likelihood that decisions favored plaintiffs. Thus, there may be a disconnect between forms of discrimination perceived by claimants and how those forms are evaluated by the legal system that protects victims of discrimination. This potential misalignment of science and practice is discussed, as are directions for future research. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

International Rivers as Boundaries

Abstract

International rivers serve a number of purposes, the most obvious are the navigational and non-navigational uses. Less noticed is the fact that international rivers are also used to delimit boundaries between nations. The immediate question that would arise is: Where are such boundaries actually drawn across the river? Boundaries, however, are established by treaties and the answer to this question is often included in the interpretation of treaties delimiting such water boundaries, taking into account the special characteristics of the international river. Indeed, this has been the case regarding the boundaries across the Chobe river between Botswana and Namibia. Determining where such boundaries lie would result in deciding to whom a disputed Island, the Kasikili/Sedudu, belongs. In a praiseworthy step, the two countries agreed to take their dispute over the Island, after failure to resolve it through negotiations, to the International Court of Justice. This paper discusses the uses of international rivers as boundaries, and reviews the dispute between Botswana and Namibia, and the decision of the Court thereon.     

Crystallization behaviour and properties of multicomponent strontium—Containing lithia calcia silicate glasses

The crystallization behaviour of lithia calcia silicate system containing MgO, SrO, and Al₂O₃ has been investigated using DTA, XRD and SEM. The coefficient of thermal expansion and Vicker's microhardness of the obtained products were also evaluated. The main crystalline phases formed after different heat-treatments were lithium metasilicate, wollastonite, diopside, β-spodumene ss, pseudo-wollastonite, Sr₂SiO₄, Sr₂Mg(Si₂O₇) and μ-(Ca,Sr)SiO₃. The wollastonite structure can accept considerable amount of strontium to form wollastonite strontium solid solution, while there is no solid solution of strontium in pseudo-wollastonite.