Constitutive Model for Municipal Solid Waste

Municipal solid waste (MSW) is a refuse composed of various materials with different properties. Some of the components are stable while others degrade as a result of biological and chemical processes. These aspects impart to MSW a complex behavior that has been modeled, with many limitations, within the concepts of soil mechanics. In this paper, a framework to model the MSW mechanical behavior is proposed based on results from laboratory tests, such as triaxial compression and confined compression of large samples. It is suggested that two different effects command MSW mechanical behavior: (a) the reinforcement of MSW by synthetic fibers (composed by many types of polymers) and (b) the behavior of the MSW paste, without fibers. Accordingly, two distinct frameworks were used to represent the main MSW characteristics: (a) a critical state framework for MSW paste and (b) an elastic perfectly plastic framework for waste fibers, with a time lag for fiber loading (function fm). The proposed model is capable of reproducing quite well the results obtained from triaxial and confined compression tests performed in the laboratory as well as the settlement recorded in a sanitary landfill.     

Multi layer structure for encapsulation of organic transistors

A novel encapsulation structure to protect organic thin film transistors against oxygen and moisture contaminations is presented. The sealing architecture is comprised of three-layers: aluminum oxide deposited by means of Atomic Layer Deposition is the actual capping layer, while cross-linked poly-vinylphenol and poly-vinylphenol prevent the contamination/damage of the underlying organic semiconductor during the oxide growth. The process has negligible impact on device mobility but it enables poly-3-hexylthiophene based transistors to operate with an on/off ratio in excess of 10³ even after 100 days of continuous ambient air exposure.     

Intraoperative laparoscope augmentation for port placement and resection planning in minimally invasive liver resection

In recent years, an increasing number of liver tumor indications were treated by minimally invasive laparoscopic resection. Besides the restricted view, two major intraoperative issues in laparoscopic liver resection are the optimal planning of ports as well as the enhanced visualization of (hidden) vessels, which supply the tumorous liver segment and thus need to be divided (e.g., clipped) prior to the resection. We propose an intuitive and precise method to plan the placement of ports. Preoperatively, self-adhesive fiducials are affixed to the patient's skin and a computed tomography (CT) data set is acquired while contrasting the liver vessels. Immediately prior to the intervention, the laparoscope is moved around these fiducials, which are automatically reconstructed to register the patient to its preoperative imaging data set. This enables the simulation of a camera flight through the patient's interior along the laparoscope's or instruments' axes to easily validate potential ports. Intraoperatively, surgeons need to update their surgical planning based on actual patient data after organ deformations mainly caused by application of carbon dioxide pneumoperitoneum. Therefore, preoperative imaging data can hardly be used. Instead, we propose to use an optically tracked mobile C-arm providing cone-beam CT imaging capability intraoperatively. After patient positioning, port placement, and carbon dioxide insufflation, the liver vessels are contrasted and a 3-D volume is reconstructed during patient exhalation. Without any further need for patient registration, the reconstructed volume can be directly augmented on the live laparoscope video, since prior calibration enables both the volume and the laparoscope to be positioned and oriented in the tracking coordinate frame. The augmentation provides the surgeon with advanced visual aid for the localization of veins, arteries, and bile ducts to be divided or sealed.     

Heterogeneous Catalysis for Fine Chemicals in Dense Phase Carbon Dioxide

An increasing number of fine chemicals is being produced using heterogeneously catalysed reactions in supercritical carbon dioxide with significant improvements in terms of process selectivity and purity of the products thereby obtained. A selection of examples and of recent findings shows the large potential of this technology for the synthetic chemistry of the future.     

The impact of different hop compounds on the growth of selected beer spoilage bacteria in beer

Beer spoiling lactic acid bacteria are a major reason for quality complaints in breweries around the world. Spoilage by a variety of these bacteria can result in haze, sediment, slime, off-flavours and acidity. As these bacteria occur frequently in the brewing environment, using certain hop products that inhibit the growth of these spoilers could be a solution to prevent problems. To investigate the impact of seven different hop compounds (α-acids, iso-α-acids, tetrahydro-iso-α-acids, rho-iso-α-acids, xanthohumol, iso-xanthohumol and humulinones) on the growth of six major beer spoilage bacteria (Lactobacillus brevis. L. backi, L. coryniformis, L. lindneri, L. buchneri, Pediococcus damnosous), two concentrations (10 and 25 mg/L) of each hop substance were added to unhopped beer. The potential growth of the spoilage bacteria was investigated over 56 consecutive days. A comparison of the results shows a strong inhibition of growth of all spoilage bacteria at 25 mg/L of tetrahydro-iso-α-acids closely followed by α-acids as the second most inhibitory substance. The results showed a high resistance of L. brevis to all hop compounds as well as an inhibition of L. coryniformis and L. buchneri at low concentrations of most hop components. In comparison with the control sample, L. lindneri showed increased growth in the presence of some hop compounds (rho-iso-α-acids, xanthohumol, iso-xanthohumol, humulinones). © 2020 The Authors. Journal of the Institute of Brewing published by John Wiley & Sons Ltd on behalf of The Institute of Brewing & Distilling     

Multi-Residue Determination of Pesticides in Açai Tropical Fruit (Euterpe oleracea) by Matrix Solid-Phase Dispersion Combined with Liquid Chromatography

An extraction method based on matrix solid phase dispersion was developed to determine bromuconazole, fenbuconazole, parathion-methyl, kresoxim-methyl, and teflubenzuron in açai using liquid chromatography with ultraviolet diode array detector. The best results were obtained using 1.0 g of açai, 3.0 g of neutral alumina as the dispersant sorbent, and cyclohexane/ethyl acetate (1:1, v/v, 20 mL) as an eluting solvent. The method was validated using açai samples fortified with pesticides at three concentration levels (0.25, 0.5, and 1.0 mg kg^?1). Average recoveries (seven replicates) ranged from 66 to 119 %, with relative standard deviations between 1.4 and 20 %. The detection and quantification limits for açai ranged from 0.02 to 0.05 mg kg^?1 and from 0.05 to 0.1 mg kg^?1, respectively.     

Color measurement: comparison of colorimeter vs. computer vision system

The aim of this work was to compare two food color measurement techniques, the traditional tristimulus colorimeter and an image analysis system. In this sense a computer vision system was developed, consisting of a digital camera, a controlled illumination environment, and a software package to process the images. The conversion between color spaces was performed employing empirical mathematical models; a standard color chart was used for its calibration. The color of 40 samples of raw and processed foods was measured in the CIELAB color space with the computer vision system and a colorimeter. The equivalence between both techniques, for individual L*, a* and b* values, was determined using appropriate hypothesis tests. For most samples both systems provide equivalent results, although the total color difference ?Ε was high enough to be noticeable. The average ?Ε was 5.88?±?3.32, with an average absolute ?L*?=?2.79?±?2.42, ?a*?=?3.02?±?2.94; ?b*?=?2.84?±?2.53. In addition, the color measured by the image analyses technique seemed to be more similar to the real ones.     

Laminar,transitional and turbulent friction factors for gas flows in smooth and rough microtubes

Theoretical and experimental works on microscale transport phenomena have been carried out in the past decade in the attempt to analyze possible new effects and to assess the influence of downscaling on the classical correlations which are used in macro-scale heat and fluid flow, following the need to supply engineers with reliable tools to be used in the design of micro-scale devices. These results were sometimes in mutual contrast, as is the case for the determination of the friction factor, which has been found to be lower, higher or comparable to that for macroscopic channels, depending on the researchers. In this work the compressible flow of nitrogen inside circular microchannels from 26 μm to 508 μm in diameter and with different surface roughness is investigated for the whole range of flow conditions: laminar, transitional and turbulent. Over 5000 experimental data have been collected and analysed. The data confirmed that in the laminar regime the agreement with the conventional theory is very good in terms of friction factors both for rough and smooth microtubes. For the smaller microchannels (<100 μm) when Re is greater than 1300 the friction factor tends to deviate from the Poiseuille law because the flow acceleration due to compressibility effects gains in importance. The transitional regime was found to start no earlier than at values of the Reynolds number around 1800. Both smooth and sudden changes in the flow regime have been found, as reported for conventional tubes. Fully developed turbulent flow was attained with both smooth and rough tubes, and the results for smooth tubes seem to confirm Blasius' relation, while for rough tubes the Colebrook–White correlation is found to be only partially in agreement with the experimental friction factors. In the turbulent regime the dependence of the friction factor on the Reynolds number is less pronounced for microtubes than the prediction of the Colebrook–White correlation and the friction factor depends only on the microtube “relative roughness”.     

Monitoring the bacterial population dynamics during fermentation of artisanal Argentinean sausages

The dynamics of the microbial community responsible for the artisanal fermentation of dry sausage produced in Argentina was investigated by using classical and molecular approaches. The combined use of RAPD analysis with primers M13, XD9, RAPD1 and RAPD2 and 16S rDNA sequencing were applied to the identification and intraspecific differentiation of 100 strains of lactobacilli and Micrococcaceae. DGGE analysis was used to monitor the dynamic changes in population after total microbial DNA was directly extracted from sausages and subjected to PCR using V3f (GC), Bact-0124f-GC and Univ-0515r primers. The sequence analysis of 16S rDNA of the dominant species was also carried out. Lactobacillus sakei and Lactobacillus plantarum were the dominant lactic acid organisms during the fermentation while Staphylococcus saprophyticus represented the dominant species of Micrococcaceae. It was demonstrated that the ripening process of Argentinean artisanal fermented sausage is driven by a limited number of Lactobacillus and Staphylococcus strains selected from environmental microbiota by the ability to best compete under the prevailing conditions of the ecological niche. The identification of dominant communities present in this artisanal fermented sausage can help in the selection of starter cultures consisting in well adapted strains to the particular production technology.