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排序方式: 共有360条查询结果,搜索用时 15 毫秒
81.
1.IntroductionTheinteractionofhightemperaturewaterwithcarbonsteel(CS)structuralsurfacesundertheprimaryheattransport(PHT)chemistryconditionsresultsintheformationofaprotectivemagnetitefilmwhichhasabilayerstructure.TheoxidelayerclosetometalgrowsintoitduetoO2-movementandoxi-dationofiron.Theouterlayerisformedbyprecipita-tionofFe3O4duetosupersaturationofthecirculat-ingcoolallt.Therelativemagnitudeofthethicknessofthetwolayersandtheirvariationwithtimeareaffectedbymanyfactors.Theporosityofthefilmgi… 相似文献
82.
Mukesh Kumar Sk Nurul Islam Gobinda Sen Susanta Kumar Parui Santanu Das 《国际射频与微波计算机辅助工程杂志》2020,30(7)
This letter presents a filtering directional coupler (FDC) with enhanced coupling and high directivity simultaneously. The proposed FDC is composed of a pair of coupled lines instead transmission line of a directional coupler. This coupled lines resonator increases the design parameters by which even/odd mode phase velocity can be compensated to improve the directivity and coupling level. The coupling enhancement can be explained by analyzing the even mode and odd mode circuit of the proposed coupler. A prototype of the proposed coupler is designed which provides a high directivity of 44 dB for 6 dB coupling level at 1 GHz frequency. The proposed coupler is designed, fabricated, and tested. 相似文献
83.
In this article, a novel design of single layer, compact, multiple input multiple output (MIMO) half‐mode substrate integrated waveguide (HMSIW) cavity backed quad element slot antenna with high front‐to‐back ratio (FTBR) is proposed. The proposed antenna consists of four rectangular SIW cavities with semi‐taper radiating slots. The antenna elements are placed in a fashion to achieve high isolation. This antenna is designed for WLAN vehicular communication system to cover the frequency range of 5.84 GHz to 5.96 GHz. It has high front to back ratio (FTBR) of more than 25 dB without using any external metallic reflector. It has more than 37 dB isolation in between orthogonal elements and more than 24 dB in between parallel elements. The envelop correlation coefficient (ECC) and diversity gain are 0.003 and 9.99 dB respectively in between all the elements. Moreover, the antenna has high gain and efficiency of more than 8 dB and 94%, respectively, in 10 dB impedance bandwidth. It can be tuned in a wide range of frequency. 相似文献
84.
Utpal Basuli Tapan K. Chaki Santanu Chattopadhyay Sunil Sabharwal 《Polymer Composites》2010,31(7):1168-1178
The ethylene methyl acrylate copolymer (EMA) and multiwalled carbon nanotube (MWNT) based composites were prepared by solution mixing as well as by melt processing of the films obtained after solution mixing. Field emission scanning electron microscopy, transmission electron microscopy, and XRD were used to characterize morphologies of various composites. MWNTs were found to be more dispersed in the composites prepared by melt process after solution process. There was no obvious agglomeration of MWNTs at lower % loading (up to 2.5%) in the polymer matrices especially the composites are prepared solution plus melt mixing and consequently better interaction between MWNTs and EMA matrix was anticipated. XRD and differential scanning calorimetry studied showed that the nanotubes affect the crystallization process and subsequently their role as a nucleating agent was established. These are reflected in the mechanical properties of the composites. Dynamic mechanical analysis showed that the storage modulus of the composites drop very sharply beyond 2.5 wt% of MWNT content with increasing % strain and it reflects the Payne effect (a substantial decrease in the storage modulus of a particle‐reinforced polymer with an increase in the amplitude of dynamic oscillations). The influence of concentration of filler was also realized by frequency sweep experiment. The incorporation of MWNTs in EMA offered a stabilizing effect since onset of degradation occurs at higher temperatures for composites. POLYM. COMPOS., 31:1168–1178, 2010. © 2009 Society of Plastics Engineers 相似文献
85.
Several applications of single-walled carbon nanotubes (SWCNT) as nanovectors in biological systems have been reported, and several molecular pathways of cellular entry have been proposed. We employed transmission electron microscopy, confocal fluorescent microscopy, and UV-vis spectroscopic analysis to confirm the internalization of DNA-SWCNT in human umbilical vein endothelial cells. Additionally, by using pharmacological inhibitors as well as genetic approaches, we have found that SWCNT is endocytosed through Rac1- GTPase mediated macropinocytosis in normal endothelial cells. 相似文献
86.
Kratz K Narasimhan A Tangirala R Moon S Revanur R Kundu S Kim HS Crosby AJ Russell TP Emrick T Kolmakov G Balazs AC 《Nature nanotechnology》2012,7(2):87-90
Nanoparticles have useful properties, but it is often important that they only start working after they are placed in a desired location. The encapsulation of nanoparticles allows their function to be preserved until they are released at a specific time or location, and this has been exploited in the development of self-healing materials and in applications such as drug delivery. Encapsulation has also been used to stabilize and control the release of substances, including flavours, fragrances and pesticides. We recently proposed a new technique for the repair of surfaces called 'repair-and-go'. In this approach, a flexible microcapsule filled with a solution of nanoparticles rolls across a surface that has been damaged, stopping to repair any defects it encounters by releasing nanoparticles into them, then moving on to the next defect. Here, we experimentally demonstrate the repair-and-go approach using droplets of oil that are stabilized with a polymer surfactant and contain CdSe nanoparticles. We show that these microcapsules can find the cracks on a surface and selectively deliver the nanoparticle contents into the crack, before moving on to find the next crack. Although the microcapsules are too large to enter the cracks, their flexible walls allow them to probe and adhere temporarily to the interior of the cracks. The release of nanoparticles is made possible by the thin microcapsule wall (comparable to the diameter of the nanoparticles) and by the favourable (hydrophobic-hydrophobic) interactions between the nanoparticle and the cracked surface. 相似文献
87.
Ankit Agarwal Sumyra Sidiq Shilpa Setia Emre Bukusoglu Juan J. de Pablo Santanu Kumar Pal Nicholas L. Abbott 《Small (Weinheim an der Bergstrasse, Germany)》2013,9(16):2785-2792
This paper advances the design of stimuli‐responsive materials based on colloidal particles dispersed in liquid crystals (LCs). Specifically, thin films of colloid‐in‐liquid crystal (CLC) gels undergo easily visualized ordering transitions in response to reversible and irreversible (enzymatic) biomolecular interactions occurring at the aqueous interfaces of the gels. In particular, LC ordering transitions can propagate across the entire thickness of the gels. However, confinement of the LC to small domains with lateral sizes of ~10 μm does change the nature of the anchoring transitions, as compared to films of pure LC, due to the effects of confinement on the elastic energy stored in the LC. The effects of confinement are also observed to cause the response of individual domains of the LC within the CLC gel to vary significantly from one to another, indicating that manipulation of LC domain size and shape can provide the basis of a general and facile method to tune the response of these LC‐based physical gels to interfacial phenomena. Overall, the results presented in this paper establish that CLC gels offer a promising approach to the preparation of self‐supporting, LC‐based stimuli‐responsive materials. 相似文献
88.
Effective integration of various subsystems into the overall process, results in an energy efficient and economic plant design. In this paper, issues related to the area-energy targeting for fired heater integrated heat exchanger networks are studied. Performance of a fired heater is affected by the variables such as fuel fired and air-preheat temperature. These variables along with the minimum approach temperature difference for the heat recovery of the background process, affect the performance of the overall system. A methodology is proposed for the area-energy targeting for fired heater integrated processes. In the proposed methodology, the fired heater heat duty split between the radiation and the convection section is determined using the one gas zone furnace model. 相似文献
89.
The viscoelastic properties of polymer thin films can have a significant impact on the performance in many small-scale devices. In this work, we use a phenomenon based on a thermally induced instability, termed thermal wrinkling, to measure viscoelastic properties of polystyrene films as a function of geometric confinement via changes in film thickness. With application of the appropriate buckling mechanics model for incompressible and geometrically confined films, we estimate the stress-relaxation modulus of polystyrene films by measuring the time-evolved wrinkle wavelength at fixed annealing temperatures. Specifically, we use time-temperature superposition to shift the stress relaxation curves and generate a modulus master curve for polystyrene films investigated here. On the basis of this master curve, we are able to identify the rubbery plateau, terminal relaxation time, and viscous flow region as a function of annealing time and temperatures that are well-above its glass transition. Our measurement technique and analysis provide an alternative means to measure viscoelastic properties and relaxation behavior of geometrically confined polymer films. 相似文献
90.
In this work, we have prepared Ag-nanorods using biscationic gemini surfactant micelles as the media by a seed-mediated wet synthesis method. Towards this end, we first synthesized Ag-nanoseeds of diameter ~7 nm stabilized by trisodium citrate (as the capping agent). Then these Ag-nanoseeds were used to synthesize Ag-nanorods of different aspect ratios. With decreasing Ag-nanoseed concentration, the aspect ratios of the Ag-nanorods stabilized by these gemini surfactants increased gradually. Various Ag-nanoseeds and Ag-nanospecies were characterized using UV-Vis spectroscopy (to know the surface plasmon bands), transmission electron microscopy (to find out their particle sizes and distribution), energy-dispersive X-ray spectroscopy and X-ray diffraction. When we used micelles derived from gemini surfactants of shorter spacer -(CH(2))(n)- (n = 2 or 4) to stabilize the Ag-nanorods, the λ(max) of the longitudinal band shifted more towards the blue region compared to that of the gemini surfactant micelles with a longer spacer -(CH(2))(n)- (n = 5, 12) at a given amount of the Ag-nanoseed solution. So, the growth of Ag-nanorods in the gemini micellar solutions depends on the spacer-chain length of gemini surfactants employed. 相似文献