Sepehr Sadighi  Mansoor Shirvani  Arshad Ahmad 《加拿大化工杂志》2011,89(1):116-125

Coating thickness protection in the burning zone of a rotary cement kiln during operation is important from the viewpoint of the kiln productivity. In this paper, an integrated model is presented to estimate the coating thickness in the burning zone of a rotary cement kiln by using measured process variables and scanned shell temperature. The model can simulate the variations of the system, thus the impact of different process variables and environmental conditions on the coating thickness can be analysed. The presented steady‐state model derived from heat and mass balance equations uses a plug flame model for simulation of gas and/or fuel oil burning. Moreover, the heat transfer value from shell to the outside is improved by a quasi‐dynamic method. Therefore, at first, the model predicts the inside temperature profile along the kiln, then by considering two resistant nodes between temperatures of the inside and outside, the latter measured by shell scanner, it estimates the formed coating thickness in the burning zone. The estimation of the model was studied for three measured data sets taken from a modern commercial cement kiln. The results confirm that the average absolute error for estimating the coating thickness for the cases 1, 2, and 3 are 3.26, 2.82, and 2.21 cm, respectively.  相似文献   

    

M. Z. Ahmad Thirmizir  Z. A. Mohd Ishak  R. M. Taib  S. Rahim  S. Mohamad Jani 《应用聚合物科学杂志》2011,122(5):3055-3063

Poly(butylene succinate) (PBS) filled kenaf bast fiber (KBF) composites were fabricated via compression molding. The effects of KBF loading on the flexural and impact properties of the composites were investigated for fiber loadings of 10–40 wt %. The optimum flexural strength of the composites was achieved at 30 wt % fiber loading. However, the flexural modulus of the composites kept increasing with increasing fiber loading. Increasing the fiber loading led to a drop in the impact strength of about 57.5–73.6%; this was due to the stiff nature of the KBF. The effect of the fiber length (5, 10, 15, and 20 mm) on the flexural and impact properties was investigated for the 30 wt % KBF loaded composites. The composites with 10‐mm KBF showed the highest flexural and impact properties in comparison to the others. The inferior flexural and impact strength of the composites with 15‐ and 20‐mm KBF could be attributed to the relatively longer fibers that underwent fiber attrition during compounding, which consequently led to the deterioration of the fiber. This was proven by analyses of the fiber length, diameter, and aspect ratio. The addition of maleated PBS as a compatibilizer resulted in the enhancement of the composite's flexural and impact properties due to the formation of better fiber–matrix interfacial adhesion. This was proven by scanning electron microscopy observations of the composites' fracture surfaces. The removal of unreacted maleic anhydride and dicumyl peroxide residuals from the compatibilizers led to better fiber–matrix interfacial adhesion and a slightly enhanced composite strength. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011  相似文献   

    

H. H. Abdel‐Razik  S. El‐Sayed  A. Hassen 《应用聚合物科学杂志》2011,121(6):3579-3589

2,7‐Di‐tert‐butylpyrene was oxidized to 2,7‐di‐tert‐butylpyrene‐4,5,9,10‐tetraone. The latter through condensation reaction with vicinal diamine such as diaminomaleodinitrile afforded heterocyclic monomer, 2,7‐di‐tert‐butyl pyrene[4,5][9,10]bis(2,3‐pyrazine‐5,6‐dinitrile), which was cyclotetramerized to the corresponding 2H‐ and metal‐pyrazinoporphyrazine‐based network polymers (2H‐PyzPz and M‐PyzPz, M = Co, Ni, Zn, or Cu). Elemental analytical results, Infrared, and NMR spectral data of the new prepared molecules are consistent with their assigned formulations. Molecular masses and metal contents of the synthesized polymers proved to be of high molecular masses, which confirm the efficiency of tetramerization polymerization and complexation reactions. Dielectric permittivity, ε′, loss tangent, tan δ, and ac conductivity, σac(ω), of 2H‐PyzPz and M‐PyzPz films were studied as a function of temperature and frequency. It was found that dielectric permittivity, ε′, decreases with the increase of frequency and increases with the increase in temperature. Ac conductivity, σac(ω), is found to vary as Bωs and the frequency exponent, s, is less than unity around room temperature indicating a dominant hopping process. On the other hand, σac(T) of all samples is thermally activated with low activation energies. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011.  相似文献   

    

Mubashshir Ahmad Ansari  Kwang-Yong Kim 《American Institute of Chemical Engineers》2009,55(9):2217-2225

The mixing of fluids in a microchannel is numerically investigated using three-dimensional Navier–Stokes equations. The microchannel has circular mixing chambers that are designed to create a self-circulating flow that operates at low Reynolds numbers. The investigations have been performed on a design that comprises of four circular mixing chambers that are joined together with constriction channels. The study has been carried out in two parts. Firstly, the mixing and the flow field are analyzed for a wide range (1–250) of the Reynolds number. Secondly, the effects of two design parameters, namely, the ratio, w/d, of the width of the constriction channel to the diameter of the circular chamber, and the angle, θ, between the outer walls of the chamber and the connection channel, on the mixing and the flow field have been evaluated. The mixing has been evaluated using a parameter, called mixing index, which is based on the variance of the mass fraction. The mixing index at the end of the device increases rapidly with the Reynolds number. The presence of a flow recirculation zone in the circular chamber is found to be effective in enhancing mixing, especially for larger Reynolds numbers. The mixing performance improves with an increase in θ, and with a decrease in w/d. The characteristics of the pressure drop have also been investigated as a function of the Reynolds number and geometric parameters. © 2009 American Institute of Chemical Engineers AIChE J, 2009  相似文献   

    

Pooria Pasbakhsh  Hanafi Ismail  Mohd Noor Ahmad Fauzi  Azhar Abu Bakar 《应用聚合物科学杂志》2009,113(6):3910-3919

The effect of partial replacement of silica or calcium carbonate (CaCO₃) by halloysite nanotubes (HNTs) on the curing behavior, tensile properties, dynamic mechanical properties, and morphological characteristics of ethylene propylene diene monomer (EPDM) composites was studied. Five different compositions of EPDM/Silica/HNT and EPDM/CaCO₃/HNT compounds (i.e. 100/30/0, 100/25/5, 100/15/15, 100/5/25, and 100/0/30 parts per hundred rubber (phr)) were prepared on a two‐roll mill. The results indicated that the replacement of CaCO₃ by HNTs increased the tensile strength, elongation at break (E_b), and tensile modulus of composites from 0 to 30 phr of HNTs whereas for silica, the maximum tensile strength and E_b occurred at 5 phr loading of HNTs with an enhanced stress at 300% elongation (M300). The curing results show that, with replacement of silica or CaCO₃ by HNTs, the cure time (t₉₀) and cure rate (CRI) were decreased and increased, respectively. Scanning electron microscopy investigation confirmed that co‐incorporation of 5 phr of HNTs with silica would improve the dispersion of silica and enhanced the interactions between fillers and EPDM matrix. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009  相似文献   

    

Sayed Amir Hossein Goli  Miskandar Mat Sahri  Mahdi Kadivar 《European Journal of Lipid Science and Technology》2008,110(12):1102-1108

Structured lipids containing conjugated linoleic acid as a functional ingredient were blended with palm stearin in the ratios of 30 : 70, 40 : 60, 50 : 50, 60 : 40 and 70 : 30 (wt/wt). The blends were subjected to enzymatic interesterification by Candida antarctica lipase. After interesterification of the blends, changes in the physical properties of the products, including lower melting points and solid fat contents along with different melting behaviors, were evidenced. Analysis of triacylglycerols (TAG) of the interesterified blends showed a decrease in the concentration of high‐melting TAG. X‐ray diffraction analysis revealed, that all the reacted blends were predominantly in the β' crystal form. The mixture could be used for the formulation of margarines or other, similar products.  相似文献   

    

El‐Sayed Z. El‐Ashtoukhy 《加拿大化工杂志》2010,88(1):126-132

In situ single‐stage electrochemical bleaching of kraft bagasse pulp was carried out in a cylindrical agitated vessel fitted with four graphite rod anodes and a cylindrical stainless steel screen cathode, using NaCl as an electrolyte. The effect of current density, pH, NaCl concentration, impeller rotational speed, temperature, and pulp consistency on the rate of bleaching was studied. It was found that the rate of bleaching increased with increasing current density, NaCl concentration, and temperature and decreased with increasing pH and pulp consistency. The effect of temperature was found to fit Arrhenius equation with an activation energy of 0.515 kcal/mol, which denotes a diffusion‐controlled mechanism. Energy consumption (EC) calculation showed that EC ranged from 0.225 to 3.11 kWh/kg dry pulp depending on the current density. The strength of bleached pulp was little affected by bleaching lying within an acceptable range.  相似文献   

    

Pawe&#x;&#x;J. Figiel  Ahlam Sibaouih  Jahir Uddin Ahmad  Martin Nieger  Minna&#x;T. Risnen  Markku Leskel  Timo Repo 《Advanced Synthesis u0026amp; Catalysis》2009,351(16):2625-2632

Novel copper(II) 2‐N‐arylpyrrolecarbaldimine‐based catalysts for the aerobic oxidation of benzylic alcohols mediated by the 2,2,6,6‐tetramethylpiperidine‐1‐oxyl (TEMPO) radical are reported. The catalytic activity for both synthesized and in situ made complexes in alkaline water solutions was studied revealing high efficiency and selectivity (according to GC selectivity always >99%) for both of these catalytic systems. For example, quantitative conversion of benzyl alcohol to benzaldehyde can be achieved with the in situ prepared bis[2‐N‐(4‐fluorophenyl)‐pyrrolylcarbaldimide]copper(II) catalysts in 2 h with atmospheric pressure of O₂ at 80 °C. Interestingly, these catalysts can utilize dioxygen as well as air or hydrogen peroxide as the end oxidants, producing water as the only by‐product.  相似文献   

    

Ahmad Hajinezhad  Mohammad H. Katooli 《国际自然能源杂志》2013,34(7):783-789

Solar chimney power plant is one of the rather new technologies that can produce power from solar energy. Its high stack is one of the important parts of the system in which the differential density of air among its top and bottom sections causes air-flow. Dry cooling towers are used in industries for cooling condensing water by utilising this concept and generating air-flow. The structural and conceptual similarity between these two systems cause the feasibility of their combination and usage of waste energy in industries. In this article, a simple and useful analytical thermodynamic model is improved in order to estimate the thermodynamic flow properties for combining both systems. Results show that the stack height and diameter are effective parameters in recovery of power. Moreover, the results show that the collector area does not remarkably affect the system performance.  相似文献   

  总被引：1，自引：0，他引：1  

Salman Azhar  Wade A. CarltonDarren Olsen  Irtishad Ahmad 《Automation in Construction》2011,20(2):217-224

Today, there is a high level of demand for sustainable buildings. The most important decisions regarding a building's sustainable features are made during the design and preconstruction stages. Leadership in Energy and Environmental Design (LEED^®) is the most widely adopted sustainable building rating system in the United States. For projects pursuing LEED^® certification, designers have to conduct in-depth sustainability analyses based on a building's form, materials, context, and mechanical-electrical-plumbing (MEP) systems. Since Building Information Modeling (BIM) allows for multi-disciplinary information to be superimposed within one model, it creates an opportunity to conduct these analyses accurately and efficiently as compared to the traditional methods. In this exploratory research, a case study was conducted on Salisbury University's Perdue School of Business building to demonstrate the use of BIM for sustainable design and the LEED^® certification process. First, a conceptual framework was developed to establish the relationship between BIM-based sustainability analyses and the LEED^® certification process. Next, the framework was validated via this case study. The results of this study indicate that documentation supporting LEED^® credits may be directly or indirectly prepared using the results of BIM-based sustainability analyses software. This process could streamline the LEED^® certification process and save substantial time and resources which would otherwise be required using traditional methods.  相似文献