松裂爆破卸压的试验研究

本文依爆破理论与岩体测试技术理论为基础，进行松裂爆破参数设计。根据现场试验，对松裂爆破卸压孔进行声波检测，证明松裂爆破卸压调整了围岩的应力分布状态，提高了巷道的稳定性。     

石煤提钒的工艺评价

钒是一种重要的战略物资，具有广泛的用途。石煤是我国独特的一种矶矿资源，储量极为丰富。从石煤中提取V2O5是获得钒的重要途径。文中旨在对传统提钒工艺流程进行评价的基础上，总结了石煤提钒中的一些新工艺，并对石煤提钒工艺前景进行了展望。     

铜及铜合金表面改性研究的可行性

钢铁渗硫提高了钢铁零部体的自润滑性能，从而提高耐磨件寿命。从这一观点出发，分析铜及铜合金渗硫的可能性，改善铜及铜合金零件的耐磨性，延长部件寿命，把辉光放电渗硫这一新技术引用到铜及铜合金表面改性的研究。     

NDN 安全机制初探

针对当前网络架构安全的问题,以内容中心网络(content-centric networking,CCN)为例对NDN的安全机制进行研究。分析NDN保护并信任内容本身的安全方式,引出通过减少内容到用户间的跳数,可以有效避免中间系统对数据的破坏的理念,并结合现有的基于NDN架构的应用ACT、VoCCN和ANDaNA,分析NDN安全机制在真实网络下的应用情况,指出现有NDN安全机制存在的漏洞。该分析结果可为今后研究海量数据下的信息过滤问题提供参考。     

Slot die coating window for a uniform fuel cell ink dispersion

The continuous roll-to-roll slot die coating technique has shown great potential for fuel cell electrode fabrication. It is essential to determine the particulate coating window to obtain a defect-free film of uniform thickness and uniform particle dispersion. For this dual-purpose, an additional upper operating limit has been proposed via a “flow field analysis scheme” that combines analysis and simulation. In this analysis, the fundamentals of flow pattern transition (Poiseuille–Couette–bubbly flow) behind coating limits are clarified. The Couette flow is advantageous for uniform shear rate and dispersion. Furthermore, phase-field simulations systematically investigate the effect of fluid and geometrical parameters and quantitatively present the flow limit with explicit expression. Results reveal that the slope of the upper limit is inversely correlated with shear-thinning index n while proportional to the coating gap H. Combining the bubble entrainment boundary, lower n and H are favorable for a larger particulate coating window.     

Synthesis and optimization of high-performance amine-based polymer for CO2 separation

Membrane technology features inspiring excellence from numerous separation technologies for CO₂ capture from post-combustion gas. Polyvinylamine (PVAm)-based facilitated transport membranes show significantly high separation performance, which has been proven promising for industrial scale-up. However, commercialized PVAm with low molecular weight and excessive crystallinity is not available to prepare high-performance membranes. Herein, the synthesis process of PVAm was optimized by regulating polymerization and acidic hydrolytic conditions. The membranes based on PVAm with a molecular weight of 154 kDa and crystallinity of 11.37% display high CO₂ permeance of 726 GPU and CO₂/N₂ selectivity of 55 at a feed gas pressure of 0.50 MPa. Furthermore, we established a PVAm synthesis reactor with an annual PVAm solution (1%(mass)) capacity of over 7000 kg and realized the scaled-up manufacture of both PVAm and composite membranes.     

低温脱硝催化剂研究进展

在传统选择性催化还原技术（SCR）催化剂的基础上,分别以钒-钛系催化剂、固溶体催化剂和新型MnO _x 催化剂为重点介绍了近些年低温SCR催化剂的研究进展,综述了不同活性组分的复合型催化剂的制备方法、元素掺杂、反应机理和抗性等,并通过分析不同复合型催化剂的表征总结了催化剂的性能状况以及低温脱硝效率,着重阐述了新型MnO _x 催化剂所具有的优异脱硝特性,认为通过改性提高新型MnO _x 的抗水抗硫性将会成为该领域未来的发展方向和研究热点,最后介绍了不同负载体对新型MnO _x 催化剂的催化效率的影响规律,发现二氧化钛负载体具有良好的抗水性,三氧化二铝负载体能显著增强催化活性,二氧化铈负载体的热稳定性较好。     

基于生物质制备多孔碳的电化学储能研究

近年来,大量化石燃料的使用改变了全球气候,加剧了温室效应并且产生了严重的热污染.能源枯竭和环境污染问题迫在眉睫,为实现生态环境的可持续发展,人们研究和开发了各种新型的储能材料和器件.超级电容器是最近几年发展迅速的一种新型储能装置,典型特点是储能和快速充放电.因为生物质绿色无污染、资源丰富和可再生,另外,生物质氮自掺杂炭材料因为孔隙发达、孔隙可调、耐酸碱、比表面积大,故可作为制备电极材料碳源的最优选择.本文分别以石榴籽和化妆棉两种生物质作为碳源,利用高温热解法来制备生物质氮自掺杂炭材料电极,并测其电化学性能.经过电化学测试得出,在1 A/g的电流密度下,石榴籽与KOH的质量比为3:1时比电容最大,约为295 F·g-1,同样电流密度下,化妆棉与KOH质量比为3:1时比电容最大,约为225 F·g-1.     

Supramolecular Phosphorescent Polymer Based on Cationic Iridium Complexes for Polymer Light-Emitting Diodes

Three novel orange emission supramolecular phosphorescent polymers (SPPs) with cationic iridium complex have been developed for polymer light-emitting diodes (PLEDs) through efficient self-assembly. The supramolecular assembly process was monitored by ¹H nuclear magnetic resonance (¹H NMR) and viscosity measurement. These SPPs give orange phosphorescence with a peak at about 595 nm and display good thermal properties with a glass-transition temperature (T_g) about 90 °C. The single-emissive-layer PLEDs with charged SPPs exhibited the highest device efficiency of 2.81 cd A^?1 with the Commission Internationale de L’Eclairage coordinates of (0.58, 0.40). The present work reported the charged SPPs self-assembled by the cationic iridium complex for the first time and provided a new guide to develop orange emitters for solution-processable optoelectronic devices.

     

Effect of solid loading and carbon additive on microstructure and mechanical properties of 3D-printed SiC ceramic

3D-printed SiC ceramics were prepared by direct ink writing and solid-phase sintering. The effects of sintering temperature, solid loading, and carbon additive on microstructures and mechanical properties of 3D-printed SiC parts were investigated. It was found that the sintering temperature affected the evolution of the microstructure and mechanical properties of the sintered SiC parts. A high solid loading promoted the densification and mechanical properties of the sintered SiC parts. However, the solid loading exceeded 40 vol.%, which decreased the density and mechanical properties of the samples. The carbon additives could improve the densification of the SiC parts and enhance their mechanical properties. When the sucrose content increased from 0 to 8 wt.%, the open porosity of the SiC part decreased from 26.12% to 3.15%, whereas the flexural strength increased 2.19 times. Using the optimized components and process parameters, the high-performance 3D-printed SiC parts were achieved.