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101.
Salima Alem Ta-Ya Chu Shing C. Tse Salem Wakim Jianping Lu Raluca Movileanu Ye Tao Francis Bélanger Denis Désilets Serge Beaupré Mario Leclerc Sheila Rodman David Waller Russell Gaudiana 《Organic Electronics》2011,12(11):1788-1793
We investigated the effect of solvents on the morphology, charge transport and device performance of poly[N-9″-hepta-decanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) and [6,6]-phenyl C71-butyric acid methyl ester (PC70BM) based solar cells. To carry out this investigation, chloroform and 1,2-dichlorobenzene were chosen as good solvents of the two compounds. Films prepared with chloroform exhibit larger domains than those prepared with 1,2-dichlorobenzene and their size increases with the amount of PC70BM. Fine tuning of the domain size was realized by using a solvent of mixed chloroform and 1,2-dichlorobenzene. At a mixing ratio of 50%:50%, a power conversion efficiency of 6.1% was achieved on PCDTBT:PC70BM (1:3) devices with an active area of 1 cm2, under air mass 1.5 global (AM 1.5 G) irradiation at 100 mW/cm2. 相似文献
102.
Gachot G Ribière P Mathiron D Grugeon S Armand M Leriche JB Pilard S Laruelle S 《Analytical chemistry》2011,83(2):478-485
To allow electric vehicles to be powered by Li-ion batteries, scientists must understand further their aging processes in view to extend their cycle life and safety. For this purpose, we focused on the development of analytical techniques aiming at identifying organic species resulting from the degradation of carbonate-based electrolytes (EC-DMC/LiPF(6)) at low potential. As ESI-HRMS provided insightful information to the mechanism and chronological formation of ethylene oxide oligomers, we implemented "gas" GC/MS experiments to explore the lower mass range corresponding to highly volatile compounds. With the help of chemical simulation tests, we were able to discriminate their formation pathways (thermal and/or electrochemical) and found that most of the degradation compounds originate from the electrochemically driven linear alkyl carbonate reduction upon cycling and to a lesser extent from a two-step EC reduction. Deduced from these results, we propose an overall electrolyte degradation scheme spanning the entire mass range and the chemical or electrochemical type of processes. 相似文献
103.
104.
Alain De Savignac Patrice Dupin Hubert Matondo Serge Bories Armand Lattes 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1980,30(1):117-128
Evidence is given for the involvement of hydrophobic interactions in the retention of hydrocarbons in oil fields. A prerequisite is that the surface of the reservoir rock has to be hydrophobic. This was obtained through adsorption of lipophilic polar compounds. The isotherms for the adsorption of dodecylamine hydrochloride and N-hexadecylpyridine hydrochloride were plotted. The treated quartz could take up large amounts of toluene. The relationships between some features of the isotherms and the retention phenomenon have been analysed. The effect of water-structuring additives (e.g. LiF, CaCl2, NaF and guanidine hydrochloride) on the recovery of hydrocarbons was investigated by means of static and dynamic methods. 相似文献
105.
Serge K. Katenev 《Journal of Infrared, Millimeter and Terahertz Waves》1995,16(10):1825-1835
Analytical expressions for EM-waves and evolutionary equations for the waves in geometric regular waveguides with layered nonstationary media are presented. A piecewise-homogeneous and periodic along the guide's axis medium is considered in detail. The analytical solution of the dispersion equation is invariant to both the guide's cross-section contour form and eigenwave type. The periodicity dispersion, particular resonances and an algorythm of the modeling application are discussed. 相似文献
106.
107.
Erik H. Saenger Oliver S. Krüger Serge A. Shapiro 《International Journal of Fracture》2006,139(3-4):569-576
We present a new technique for static computations of effective elastic properties of multiple fractured rocks. This approach
is based on the viscoelastic rotated staggered finite-difference (FD) grid wave propagation technique. Our simulations are
used to explain discrepancies of some recent numerical studies. The focus is on scale effects of a so-called representative
volume element (RVE). From the point of view of classical micromechanics we review different numerical techniques: Static
as well as dynamic numerical experiments. We show that the differential effective medium theory (DEM) is capable of producing
satisfactory predictions of effective elastic moduli. For non-dilute crack densities this is not the case for the non-interacting
approximation (NIA). 相似文献
108.
Nicolas Boutheiller Pierre Jarry Eric Kerherv Jean‐Marie Pham Serge Vigneron 《国际射频与微波计算机辅助工程杂志》2003,13(6):429-437
This article describes a basic building block for microwave waveguide filters. It uses a new coupling scheme where all resonant modes are used at their cutoff frequency. It is composed of a cascade of basic nonloaded rectangular cavities where the modes are alternately single mode and dual mode. These cavities are coupled directly, without any iris. Neither coupling nor tuning screws are needed. The analysis of the discontinuities is performed by the method of moments (MoM). The synthesis makes use of an optimization method based on the genetic algorithm. Prototypes have been realized and measurements are shown to confirm the analysis results. © 2003 Wiley Periodicals, Inc. Int J RF and Microwave CAE 13: 429–437, 2003. 相似文献
109.
110.
Enthalpies of mixing for the binary system carbon dioxide – hydrogen sulphide were measured by means of an isothermal flow calorimeter at temperatures of 293.15. 305.15 and 313.15 K. For the first isotherm, excess enthalpy measurements were made at pressures of 0.507, 1.013 and 1.419 MPa. For the last two isotherms, these measurements were performed at pressures of 0.507, 1.013 and 1.520 MPa. The experimental data were treated by the same techniques described for the systems previously studied (Barry et al., 1982a, 1982b, 1982c). Two types of binary interaction coefficients kij have been utilized for the prediction of experimental data from equations of state: coefficients kij independent of temperature and pressure, and kij's adjusted as function of temperature and pressure. A better prediction of the excess enthalpy experimental data was obtained from the latter series of binary interaction coefficients. 相似文献