Antimicrobial properties and thermal stability of polycarbonate modified with 1‐alkyl‐3‐methylimidazolium tetrafluoroborate ionic liquids

Four water immiscible ionic liquids (ILs): 1‐hexyl‐3‐methylimidazolium tetrafluoroborate, 1‐heptyl‐3‐methylimidazolium tetrafluoroborate, 1‐octyl‐3‐methylimidazolium tetrafluoroborate and 1‐dodecyl‐3‐methylimidazolium tetrafluoroborate have been synthesized. Polycarbonate (PC) films containing ILs were prepared by solvent casting from methylene chloride solutions. Scanning electron microscopy measurements showed the high homogeneity of PC/IL films with the IL content up to 4 wt %. The tendency to IL aggregation was observed for polymeric films with higher IL content (5%). PC/IL composites were found to have the reduced thermal decomposition temperature under both an air and a nitrogen atmosphere in comparison with the neat PC. The effect of IL content on the antimicrobial activity of PC films against Escherichia coli bacteria was studied. Pronounced antimicrobial efficacy was revealed for PC/IL films for all studied ILs starting from 3 wt % of IL. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40050.     

Native fluorescence changes induced by bactericidal agents

Steady-state and time-resolved fluorescence spectroscopy were measured for five species of bacteria (Bacillus subtilis, Staphylococcusaureus, Enterococcus faecalis, Escherichia coli, and Pseudomonas aeruginosa) subjected to three bactericidal agents, formaldehyde, sodium hypochlorite (bleach), and hydrogen peroxide. For all species, the fluorescence was dominated by tryptophan emission with a fluorescence lifetime that can be described by a bi-exponential decay profile. Application of bleach resulted in an almost total loss of scattering and fluorescence, which indicated that total destruction of proteins and amino acids may have occurred. Hydrogen peroxide decreased the fluorescence intensity and shifted /spl lambda//sub max/ to shorter wavelengths, except in S. aureus, which is resistant to oxidizing agents. The formaldehyde shifted /spl lambda//sub max/ to shorter wavelengths for B. subtilis, S. aureus, E. faecalis, and E. coli. The formaldehyde shortened the lifetime of the slow component and increased the amplitude of the fast component relative to the slow component. This study demonstrates that fluorescence spectroscopy offers a method to evaluate the potential for killing bacteria and decontaminating areas by disinfecting agents.     

Ultra-stable nanoparticles of CdSe revealed from mass spectrometry

Nanoparticles under a few nanometres in size have structures and material functions that differ from the bulk because of their distinct geometrical shapes and strong quantum confinement. These qualities could lead to unique device applications. Our mass spectral analysis of CdSe nanoparticles reveals that (CdSe)(33) and (CdSe)(34) are extremely stable: with a simple solution method, they grow in preference to any other chemical compositions to produce macroscopic quantities. First-principles calculations predict that these are puckered (CdSe)(28)-cages, with four- and six-membered rings based on the highly symmetric octahedral analogues of fullerenes, accommodating either (CdSe)(5) or (CdSe)(6) inside to form a three-dimensional network with essentially heteropolar sp(3)-bonding. This is in accordance with our X-ray and optical analyses. We have found similar mass spectra and atomic structures in CdS, CdTe, ZnS and ZnSe, demonstrating that mass-specified and macroscopically produced nanoparticles, which have been practically limited so far to elemental carbon, can now be extended to a vast variety of compound systems.     

Optical nanosensor platform operating in near-physiological pH range via polymer-brush-mediated plasmon coupling

The nanosensors' platform made of a stimuli-responsive polymer/noble metal nanoparticle composite thin film exploits the combination of the swelling-shrinking transition in a poly(N,N'-dimethylaminoethyl methacrylate) brush and the localized surface plasmon resonance in metal nanoparticles to enable the transduction of changes in the solution pH in the near-physiological range into a pronounced optical signal.     

Native fluorescence and excitation spectroscopic changes in Bacillus subtilis and Staphylococcus aureus bacteria subjected to conditions of starvation

Fluorescence emission and excitation spectra were measured over a 7-day period for Bacillus subtilis (Bs), a spore-forming, and Staphylococcus aureus (Sa), a nonspore-forming bacteria subjected to conditions of starvation. Initially, the Bs fluorescence was predominantly due to the amino acid tryptophan. Later, a fluorescence band with an emission peak at 410 nm and excitation peak at 345 m, from dipicolinic acid, appeared. Dipicolinic acid is produced during spore formation and serves as a spectral signature for detection of spores. The intensity of the 410-nm band continued to increase over the next 3 days. The Sa fluorescence was predominantly from tryptophan and did not change over time. In 6 of the 17 Bs specimens studied, an additional band appeared with a weak emission peak at 460 cm and excitation peaks at 250, 270, and 400 nm. The addition of beta-hydroxybutyric acid to the Bs or the Sa cultures resulted in a two-order of magnitude increase in the 460-nm emission. The addition of Fe2+ quenched the 460 emission, indicating that a source of the 460-nm emission was a siderophore produced by the bacteria. We demonstrate that optical spectroscopy-based instrumentation can detect bacterial spores in real time.     

Reflection of light by composite volume holograms: Fresnel corrections and Fabry-Perot spectral filtering

Effects in composite volume Bragg gratings (VBGs) are studied theoretically and experimentally. The mathematics of reflection is formulated with a unified account of Fresnel reflections by the boundaries and of VBG reflection. We introduce the strength S of reflection by an arbitrary lossless element such that the intensity of reflection is R=tanh(2) S. We show that the ultimate maximum/minimum of reflection by a composite lossless system corresponds to addition/subtraction of relevant strengths of the sequential elements. We present a new physical interpretation of standard Fresnel reflection: strength for TE or for TM reflection is given by addition or by subtraction of two contributions. One of them is an angle-independent contribution of the impedance step, while the other is an angle-dependent contribution of the step of propagation speed. We study an assembly of two VBG mirrors with a thin immersion layer between them that constitutes a Fabry-Perot spectral filter. The transmission wavelength of the assembly depends on the phase shift between the two VBGs. Spectral resolution Deltalambda(FWHM)=25 pm at lambda=1063.4 nm is achieved with the device of small total physical thickness 2L=5.52 mm.     

Electrolyte stability determines scaling limits for solid-state 3D Li ion batteries

Rechargeable, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly desirable to power an emerging class of miniature, autonomous microsystems that operate without a hardwire for power or communications. A variety of three-dimensional (3D) LIB architectures that maximize areal energy density has been proposed to address this need. The success of all of these designs depends on an ultrathin, conformal electrolyte layer to electrically isolate the anode and cathode while allowing Li ions to pass through. However, we find that a substantial reduction in the electrolyte thickness, into the nanometer regime, can lead to rapid self-discharge of the battery even when the electrolyte layer is conformal and pinhole free. We demonstrate this by fabricating individual, solid-state nanowire core-multishell LIBs (NWLIBs) and cycling these inside a transmission electron microscope. For nanobatteries with the thinnest electrolyte, ≈110 nm, we observe rapid self-discharge, along with void formation at the electrode/electrolyte interface, indicating electrical and chemical breakdown. With electrolyte thickness increased to 180 nm, the self-discharge rate is reduced substantially, and the NWLIBs maintain a potential above 2 V for over 2 h. Analysis of the nanobatteries' electrical characteristics reveals space-charge limited electronic conduction, which effectively shorts the anode and cathode electrodes directly through the electrolyte. Our study illustrates that, at these nanoscale dimensions, the increased electric field can lead to large electronic current in the electrolyte, effectively shorting the battery. The scaling of this phenomenon provides useful guidelines for the future design of 3D LIBs.     

Kollektorbeschichtungen für die EUV‐Lithografie

Collector Coatings for EUV Lithography Extreme ultraviolet lithography (EUVL) is the next generation lithogra phy method operating at the wavelength of 13.5 nm (14 times shorter than current lithography systems), enabling semiconductor scaling to resolutions of 22 nm and below [1]. This paper presents the successful coating of the world's largest ellipsoidal collector mirror for EUV radiation with a diameter of 660 mm ( Fig. 1 ). In order to achieve the required peak reflectivity of more than 65 %, the ellipsoidal collector was coated with a highly reflective, laterally graded multilayer using the dc magnetron sputtering system “NESSY”. A maximum reflectivity of the laterally graded multilayer of more than 65 % was achieved for radii smaller than 220 mm. For radii between 230 mm and 320 mm the reflectivity decreases to a minimum of 58 %. The targeted wavelength remains constant at (13.50 ± 0.05) nm over the entire collector surface which is well within the tight specifications for high volume manufacturing.     

Quantifying structural attributes of system decompositions in 28 feature-oriented software product lines

A key idea of feature orientation is to decompose a software product line along the features it provides. Feature decomposition is orthogonal to object-oriented decomposition—it crosscuts the underlying package and class structure. It has been argued often that feature decomposition improves system structure by reducing coupling and by increasing cohesion. However, recent empirical findings suggest that this is not necessarily the case. In this exploratory, observational study, we investigate the decompositions of 28 feature-oriented software product lines into classes, features, and feature-specific class fragments. The product lines under investigation are implemented using the feature-oriented programming language Fuji. In particular, we quantify and compare the internal attributes import coupling and cohesion of the different product-line decompositions in a systematic, reproducible manner. For this purpose, we adopt three established software measures (e.g., coupling between units, CBU; internal-ratio unit dependency, IUD) as well as standard concentration statistics (e.g., Gini coefficient). In our study, we found that feature decomposition can be associated with higher levels of structural coupling in a product line than a decomposition into classes. Although coupling can be concentrated in very few features in most feature decompositions, there are not necessarily hot-spot features in all product lines. Interestingly, feature cohesion is not necessarily higher than class cohesion, whereas features are more equal in serving dependencies internally than classes of a product line. Our empirical study raises critical questions about alleged advantages of feature decomposition. At the same time, we demonstrate how our measurement approach of coupling and cohesion has potential to support static and dynamic analyses of software product lines (i.e., type checking and feature-interaction detection) by facilitating product sampling.     

Parallel supervised land-cover classification system for hyperspectral and multispectral images

Hyperspectral and multispectral imagery allows remote-sensing applications such as the land-cover mapping, which is a significant baseline to understand and to monitor the Earth. Furthermore, it is a relevant process for socio-economic activities. For that reason, high land-classification accuracies are imperative, and minor image processing time is essential. In addition, the process of gathering classes’ documented samples is complicated. This implies that the classification system is required to perform with a limited number of training observations. Another point worth mentioning is that there are hardly any methods that can be used analogously for hyperspectral or multispectral images. This paper aims to propose a novel classification system that can be used for both types of images. The designed classification system is composed of a novel parallel feature extraction algorithm, which utilises a cluster of two graphics processing units in combination with a multicore central processing unit (CPU), and an artificial neural network (ANN) particularly devised for the classification of the features ensued by the implemented feature extraction method. To prove the performance of the proposed classification system, it is compared with non-parallel and CPU-only-parallel implementations employing multispectral and hyperspectral databases. Moreover, experiments with different number of samples for training the classifier are performed. Finally, the proposed ANN is compared with a state-of-the-art support vector machine in classification and processing time results.