Effects of the reinforcement and toughening of acrylate resin/CaCO3 nanoparticles on rigid poly(vinyl chloride)

Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO₃) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO₃) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO₃ nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO₃ particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO₃ to prepare the modified nanoparticles, breaking down nano‐CaCO₃ particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007     

Synthesis and Morphology of TiO2 Nanotube Arrays by Anodic Oxidation Using Modified Glycerol-Based Electrolytes

Titanium dioxide (TiO₂) nanotube arrays were prepared by electrochemical anodization of titanium sheets in the glycerol 176 mL/H₂O 44 mL/NH₄F 0.5 wt% electrolytes modified with H₂SO₄ and NaAc addition. The surface morphologies, average inner diameter, and the length of the nanotube arrays changed with the solution pH in the range from 5.6 to 4.0 by adding H₂SO₄. A uniform surface morphology of the nanotubes with average inner diameter of ∼80 nm and a length of ∼1000 nm was obtained when the solution pH was 5.0. The growth rates of the nanotubes were remarkably enhanced by NaAc addition in the range of 0.04–0.14 M . With NaAc addition of 0.10 M , the length of the nanotube arrays reached 4.16 μm after an 8-h anodization, increasing 3.23 μm compared with no NaAc addition. The relationship between solution pH and growth of TiO₂ nanotubes was analyzed by current–time curves, solution electrical conductivities, and scanning electron microscopy (SEM), and the role of NaAc was also discussed based on SEM and solution electrical conductivities.     

红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.     

Performance evaluation of anti-radiation based on the gamma degradation process

In the environment of space radiation, the high-energy charged particles or high-energy photons acting on a spacecraft can cause either temporary device degradation or permanent failure. The traditional probability model is difficult to obtain reliable estimation of unit radiation resistance performance with small samples. Considering that different products will change differently after high-energy particle radiation, we construct a model based on the gamma degradation process. This model can efficiently describe the law of unit radiation resistance variation with the total radiation dose levels under the effect of the total dose and displacement damage. Finally, the proposed model is used to assess the anti-radiation performance of the N-channel power MOSFET device STRH60N20FSY3 produced by STM to obtain average unit radiation resistance, survival probability, survival function, etc.     

新日铁高炉冷却壁技术的进展及其在宝钢的应用

从结构、材料、冷却方式和壁厚等方面介绍了新日铁高炉用冷却壁的1～4代演变过程，同时简述了宝钢引进的第3代冷却壁制造技术及其应用概况。认为今后大型高炉冷却系统的设计会向冷却壁倾斜。     

含Cl^-溶液中SO4^2-对316不锈钢临界点蚀温度的影响

采用外加恒电位下腐蚀电流-温度扫描方法研究了在0．5％Cl^-溶液中，SO4^2-浓度对316不锈钢点腐蚀行为的影响．结果表明，随着SO4^2-浓度的增加，钝化电流增加，开路电位降低．当SO4^2-浓度低于0．42％时，316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低；当SO4^2-浓度大于0．42％时，临界点蚀温度比不存在SO4^2-时的临界点蚀温度高．从离子竞争吸附的角度进行分析，对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释．     

汽车用磁性材料和磁性器件

汽车前灯装置用的磁性材料为了减少汽车夜间行驶的交通事故,一个重要的办法就是提高驾驶员的眼睛的夜间辨认能力,这就要在汽车上安装高亮度前灯（High Intensity Dischrge Lamp,简写为HID灯）,这种灯较传统用的卤灯省电且更亮,这样驾驶员就能借助它容易发现路面障碍物.HID灯是水银灯、金属卤化物灯、高压钠灯的统称.其中金属卤化物灯用作汽车前灯有2个缺点：①从点灯至达到规定亮度需数分至数十分钟;②一旦灯灭,再点着也必需数分至数十分钟.为克服这两点缺点在其点灯电路中必须设置变换器和触发器.     

Redundancy filtering and fusion verification for video copy detection

Multimedia Systems - Recently, the frame fusion based video copy detection scheme provides a possibility to detect copies in a continuous query video stream. However, its computational complexity...     

可组合的描述符泄露类型检查

应用程序通过操作系统的系统调用对文件描述符进行操作并管理文件资源。如果应用程序对资源描述符的管理出现错误并发生描述符泄漏,会严重影响系统的可用性。据此,提出了一种检查程序是否会导致描述符泄漏的类型系统,给出了描述符操作方法的语义和类型约束,证明了类型系统的可靠性定理。此外,还初步讨论了该类型系统在并发程序下的扩展。