Fabrication of Multiscale Gradient Polymer Patterns by Direct Molding and Spatially Controlled Reflow

Size variations of pattern spacing as well as gradient control of the as‐formed polymeric pattern via a spatially controlled reflow process are presented. Micro‐ and nanopatterns of polymethyl methacrylate (PMMA) in the form of line‐and‐space strips are first generated by capillary force lithography (CFL), and the residual layers are removed by ashing process. Subsequently, the exposed PMMA strips underwent a controlled reflow process above the glass transition temperature (T_g) while heating single or both sides of the substrate either in parallel to the line pattern (parallel reflow) or perpendicular to the line pattern (perpendicular reflow). As a result of this controlled reflow, a linear or a parabolic profile of pattern spacing is achieved depending on the heating mode. Furthermore, multiscale gradient patterns are formed with the spacing ranging from 98 nm to 4.23 μm (a difference of two orders of magnitude) in a single patterned layer using the original micropattern of 16 μm width and 8 μm spacing. In order to explain reflow behaviors, a simple theoretical model relating the normalized pattern width to the polymer viscosity is derived based on a leveling kinetics of polymer melt. Also, gradient PMMA channels are fabricated and bonded to a glass substrate, which are used to flow a liquid inside the channels by capillarity‐driven flow.     

Correlated Quantum Phenomena of Spin–Orbit Coupled Perovskite Oxide Heterostructures: Cases of SrRuO3 and SrIrO3 Based Artificial Superlattices

Unexpected, yet useful functionalities emerge when two or more materials merge coherently. Artificial oxide superlattices realize atomic and crystal structures that are not available in nature, thus providing controllable correlated quantum phenomena. This review focuses on 4d and 5d perovskite oxide superlattices, in which the spin–orbit coupling plays a significant role compared with conventional 3d oxide superlattices. Modulations in crystal structures with octahedral distortion, phonon engineering, electronic structures, spin orderings, and dimensionality control are discussed for 4d oxide superlattices. Atomic and magnetic structures, J_eff = 1/2 pseudospin and charge fluctuations, and the integration of topology and correlation are discussed for 5d oxide superlattices. This review provides insights into how correlated quantum phenomena arise from the deliberate design of superlattice structures that give birth to novel functionalities.     

Morphology Associated Positive Correlation between Carrier Mobility and Carrier Density in Highly Doped Donor–Acceptor Conjugated Polymers

Molecular doping in conjugated polymers (CPs) has recently received intensive attention for its potential to achieve high electrical conductivity in organic thermoelectric materials. In particular, it affects not only the carrier density n but also the carrier mobility µ because high degree of molecular doping changes the morphological properties. Herein, the effect of molecular doping in CP thin films on the pathways and mechanisms of charge transport is investigated, which govern the µ-n relationship. Two representative donor–acceptor type CPs with similar µ but different molecular assembly in an undoped state, that is poly[2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno[3,2-b]thiophene)] (DPPDTT) and indacenodithiophene-co-benzothiadiazole (IDTBT), are prepared. Heavy doping with iron chloride (FeCl₃) induced DPPDTT with highly crystalline edge-on orientation to increase its µ up to 19.6 cm² V⁻¹ s⁻¹, whereas IDTBT with irregular intermolecular stacking showed little change in µ. It is revealed that this different µ-n relationship is highly attributed to the initial molecular ordering of CP films. The charge transport mechanism also becomes significantly different: both coherent and incoherent transports are observed in the doped DPPDTT, whereas incoherent transport is only found in the doped IDTBT. This study suggests guidelines for enhancing charge transport of CPs under doping in terms of structural disorder.     

Indicator Sensor Development and Fuel Cell Degradation Imaging

Although extensive research has been conducted, understanding the exact phenomena occurring during the operation of polymer electrolyte fuel cells (PEFCs) remains difficult. This research attempted to identify new reasons for the reduced performance of PEFC using an imaging technique. To begin with, H⁺ and OH⁻ indicator sensors, which display red, blue, and green values (RGB) using digital microscopes, are developed and attached to each electrode of a membrane electrode assembly to enable quantitative analysis of ion generation. The proposed reaction in the fuel cell can be confirmed, and various reactions occurring in the electrode can be examined using this approach. In particular, H⁺ is generated at the anode and cathode of the anion exchange membrane fuel cell, which is found to be a major cause of performance deterioration.     

Adaptive Kernel Function of SVM for Improving Speech/Music Classification of 3GPP2 SMV

Because a wide variety of multimedia services are provided through personal wireless communication devices, the demand for efficient bandwidth utilization becomes stronger. This demand naturally results in the introduction of the variable bitrate speech coding concept. One exemplary work is the selectable mode vocoder (SMV) that supports speech/music classification. However, because it has severe limitations in its classification performance, a couple of works to improve speech/music classification by introducing support vector machines (SVMs) have been proposed. While these approaches significantly improved classification accuracy, they did not consider correlations commonly found in speech and music frames. In this paper, we propose a novel and orthogonal approach to improve the speech/music classification of SMV codec by adaptively tuning SVMs based on interframe correlations. According to the experimental results, the proposed algorithm yields improved results in classifying speech and music within the SMV framework.     

A high-yield fabrication process for silicon neural probes

There is a great need for silicon microelectrodes that can simultaneously monitor the activity of many neurons in the brain. However, one of the existing processes for fabricating silicon microelectrodes-reactive-ion etching in combination with anisotropic KOH etching-breaks down at the wet-etching step for device release. Here we describe a modified wet-etching sidewall-protection technique for the high-yield fabrication of well-defined silicon probe structures, using a Teflon shield and low-pressure chemical vapor deposition (LPCVD) silicon nitride. In the proposed method, a micro-tab holds each individual probe to the central scaffold, allowing uniform anisotropic KOH etching. Using this approach, we obtained a well-defined probe structure without device loss during the wet-etching process. This simple method yielded more accurate fabrication and an improved mechanical profile.     

All‐Carbon Nanotube‐Based Flexible Field‐Emission Devices: From Cathode to Anode

The fabrication of a flexible field‐emission device (FED) using single‐walled carbon nanotube (SWNT) network films as the conducting electrodes (anode and cathode) and thin multi‐walled CNT/TEOS hybrid films as the emitters is reported. P‐type doping with gold ions and passivation with tetraethylorthosilicate (TEOS) made the SWNT network film highly conductive and environmentally stable, and hence a good alternative to conventional indium tin oxide electrodes. CNT/TEOS hybrid emitters showed high current density, low turn‐on field, and long‐term emission stability, compared with CNT emitters; these characteristics can be attributed to the TEOS sol, acting both as a protective layer surrounding the nanotube tip, and as an adhesive layer enhancing the nanotube adhesion to the substrate. All‐CNT‐based flexible FEDs fabricated by this approach showed high flexibility in field emission characteristics and extremely bright electron emission patterns.     

Efficient significance map coding using block-based zerotree andquadtree

For wavelet-based image coding, it is important to efficiently code the significance map for each bit plane. The proposed algorithm provides an effective method for coding the significance map by using block-based zerotree and quadtree decomposition, and demonstrates good R-D performance especially at low bit rates and for images with rich texture     

Surface Chemistry of Vitamin: Pyridoxal 5′‐Phosphate (Vitamin B6) as a Multifunctional Compound for Surface Functionalization

Vitamins are non‐toxic compounds that perform a variety of biological functions and also available in a large quantity. Other than the usage as food supplements, few attempts have been made to use them as functional materials. In this study, we report that vitamin B6, pyridoxal 5′‐phosphate (PLP), is a multi‐functional molecule for oxide surface chemistry. PLP‐immobilized surfaces exhibit superhydrophilicity and even hemophilicity, enhancing proliferation, migration, and differentiation of mammalian cells. Unlike existing molecules used so far in surface modification, PLP has an intrinsic chemical reactivity toward biomacromolecules due to the presence of the aldehyde group. In fact, RGD peptide is covalently tethered onto PLP surfaces directly in one step without any chemical activation. Furthermore, PLP‐functionalized implant device showed rapid bone healing. As vitamin B6 is a FDA approved molecule for human usage, the surface chemistry of vitamin B6 potentially allows a fast route for surface functionalized medical devices into clinic.     

Equalization digital on-channel repeater in the single frequency networks

Digital On-Channel Repeater (DOCR) can be used for Single Frequency Networks (SFN's). It is much simple and low cost compared to Distributed Transmitter which needs Studio to Transmitter Link (STL). However, traditional DOCR has one of those defects such as a power limit, a long time system processing delay or a poor output signal quality. In order to overcome all of those defects, we introduce Equalization DOCR (EDOCR) which regenerates the original 8-VSB output signal with relatively short time system processing delay. Lab. and Field test results show that the EDOCR can eliminate the loop-back signal up to 5.5 dB with 5.5 /spl mu/s system processing delay. By using EDOCR, we can save spectrum resources and extend coverage areas.