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21.
A two-dimensional ground heat loss model is used to investigate the effect of bottom reflectivity on ground heat losses for solar ponds. In the model, convection boundary conditions are used between water and ground. The convection heat transfer coefficient is estimated using the correlations given for heated or cooled flat plates. The local rate of absorption of the solar radiation in the pond is determined for the direct and diffuse components by the exact treatment of the radiation problem. The fractions of heat adsorbed by the pond bottom that is transferred to soil and to water are investigated for different bottom reflectivities. 相似文献
22.
Carbon nanofibers (CNFs) draw great interest due to their noticeable mechanical, electrochemical, and physical properties. In this study, polyacrylonitrile‐based CNFs are obtained via electrospinning technique. Thermal oxidation and low temperature (950 °C) carbonization are applied to the electrospun web in order to achieve CNF. Through the process, Fourier transform infrared‐attenuated total reflectance spectroscopy and Raman spectroscopic results are investigated. The electrochemical properties of the self‐standing CNF webs are examined with electrochemical impedance spectroscopy and cyclic voltammetry. In addition, various electrolyte solutions are studied to investigate the capacitive behavior of CNF webs. Electrolyte type variation has a significant effect on the capacitance results and high capacitance values are achieved in aqueous solution. According to the differing electrolyte types, specific capacitance values (Csp) are recorded between 204 and 149 F g?1 where maximum specific capacitance is obtained in 0.5 M H2SO4 as 204 F g?1. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45723. 相似文献
23.
Kadir Ugurtan Yilmaz Sezai Ercisli Yasar Zengin Memnune Sengul Ebru Yasa Kafkas 《Food chemistry》2009
Fruit weight, antioxidant capacity, total anthocyanins, total phenolics, ascorbic acid, soluble solid content (SSC), reducing sugar and acidity of a number of selected cornelian cherry (Cornusmas L.) genotypes of varied pigmentation were investigated. Two methods, namely β-carotene bleaching and ferric reducing antioxidant power (FRAP) were used to determine total antioxidant capacity, while Folin–Ciocalteu reagent was used to determine total phenols. Fruit weight, SSC and ascorbic acid content of genotypes were 2.09–9.17; 12.53–21.17% and 29–112 mg/100 g, respectively. Antioxidant activity and total phenolic content varied among genotypes and 44-18 genotype had the highest antioxidant capacity using both methods. This genotype also had the highest total phenolic (74.8 mg GAE/g DW) and total anthocyanin (115 mg cyanidin-3-glucoside equivalents /100 g FW) content. There are linear relationships between antioxidant capacities and total phenols. The present study demonstrates the potential of certain cornelian cherry genotypes, notably 44-18, for improvement of nutritional value through germplasm enhancement programmes. 相似文献
24.
Polycarbazole (PCz) and copolymerization of carbazole (Cz) and N-p-tolylsulfonyl pyrrole (pTsp), P(Cz-co-pTsp), thin films have been cyclovoltammetrically coated onto carbon fiber electrodes as an active functionalized microelectrode in sodium perchlorate (NaClO4)/acetonitrile (ACN) medium. The resulting thin films of homopolymer and copolymer were characterised by using Fourier transform infrared reflectance spectroscopy (ATR-FTIR), energy dispersive X-ray (EDX) point analysis, scanning electron microscopy (SEM) and atomic force microscopy (AFM). An electrical impedance study on the prepared electrodes is reported in the present paper under different feed ratios of [pTsp]0/[Cz]0 during electrochemical impedance spectroscopic (EIS) measurements. Specific capacitance (Csp) were calculated, P(Cz-co-pTsp) in feed ratio of [pTsp]0/[Cz]0 = 200 has preserved more capacitive behavior especially at lower frequency (Csp = ∼156 mF g−1) than polycarbazole (Csp = ∼2.1 mF g−1. The electrochemical impedance data fitted to three different equivalent models were used to find out numerical values of the proposed components. 相似文献
25.
Melda Sipahi Elif Alturk Parlak Aysenur Gul Ekrem Ekinci M. Ferhat Yardim A. Sezai Sarac 《Progress in Organic Coatings》2008
Electropolymerization of aniline on mesophase pitch based carbon foam has been studied in order to evaluate the influence of conductive polymer coating on the properties of carbon foam. The surface morphology of the coating was determined by scanning electron microscopy (SEM). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to investigate the electrochemical properties of resulting modified carbon foam samples. Polyaniline (PANI) electrocoated-mesophase pitch based carbon foam showed good capacitor behavior in 0.5 M H2SO4. Better capacitive behavior is obtained for 100 and 150 mV/s compared to other scan rates, under these faster scan rates thinner films of PANI coatings were combined with more porous structure of carbon foam. Conductivity of the carbon foam was increased from 9.23 to 13.73 S/cm by electrocoating of PANI. 相似文献
26.
A new class of dimethyl formamide (DMF)– and acetone‐soluble conducting pyrrole–ketonic resin copolymers has been developed. This was accomplished by oxidatively polymerizing pyrrole monomer by Ce(IV) salt in the presence of methyl ethyl ketone formaldehyde resin (MEKF–R). The resulting copolymers were readily dissolved in DMF and acetone. These products were characterized by FTIR and UV‐visible spectroscopy, conductivity, four‐probe conductivity, viscosity, and DSC measurements. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1098–1106, 2001 相似文献
27.
The flow and heat transfer characteristics of impinging laminar square twin jets have been investigated numerically through the solution of three-dimensional Navier-Stokes and energy equations in a steady state. The simulations have been carried out for jet-to-jet spacings of 4, 6, and 8 and for nozzle-exit-to-plate distances between 0.25D and 5D. The calculated results show that the flow structure of square twin jets impinging on a heated plate is strongly affected by the jet-to-plate distance. In addition, for very small jet-to-plate distances (L z , 0.25D), no upwash fountain flow can form at the collision point where the jets are merely diverted in the transverse direction. For such nozzle-to-plate distances the wall jet fills the whole gap between the plates with no vortex motion around the twin jets. 相似文献
28.
The products of pyrolysis at 525 and 840 °C of two asphaltites from South-Eastern Turkey have been analysed and compared with the bitumen obtained by solvent extraction. The yield of oil product is reasonably similar for all three treatments, with gas (hydrogen, ethene, C1C4 alkanes and hydrogen sulphide) being liberated during pyrolysis. Greater percentages of alkanes with shorter chain lengths (along with some alkenes), and of pentane-soluble aromatic oils with reduced molecular masses, are generated during pyrolysis, at the expense of asphaltenes. The extra alkanes are generated partly by the cracking of aromatic side-chains and also from kerogen. Pyrolysis reduces the number of sulphur linkages in the oil, but nitrogen- and oxygen-containing structures are liberated from kerogen during heating. 相似文献
29.
This review article focuses on several approaches in the characterization and modification of carbon surfaces with electrocoated thin films which has been realized by recent progress in experimental methods. Electropolymerization and electrocopolymerization of π-conjugated polymers (pyrrole, carbazole, N-vinylcarbazole and aniline) onto carbon surfaces are reviewed with 348 references. Particular emphasis is placed on the recent nanoscale surface characterization techniques applied to the resulting electrocoated polymers onto carbon fibers (i.e., scanning electron microscopy (SEM), cyclic voltammetry (CV), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), focused ion beam-secondary ion mass spectroscopy (FIB-SIMS), Fourier transformed infrared spectroscopy (reflectance-FTIR), and Raman spectroscopic measurements). 相似文献
30.
Electrografting of poly [N-vinylcarbazole-co-methylmethacrylate] onto high tenacity carbon fiber (TENAX HTA 5000) was carried
out under preparative constant current electrolysis conditions by using anode and cathode as fiber towings. The surface morphology
of the electrografted carbon fibers was determined by scanning electron microscopy (SEM). FTIR reflectance measurements (FTIR-ATR)
were applied for the characterization of chemical composition on the electrografted thin film surface on carbon fiber. The
efficiency of the electrocopolymerization on carbon fiber surfaces under preparative constant current electrolysis conditions
were evaluated, i.e., current density (charge) vs. thickness, yield and morphology. 相似文献