有机溶剂下盐酸环丙沙星的荧光特性研究

本文在几种有机试剂(乙醇，甲醇，丙酮)条件下，对盐酸环丙沙星产生的荧光特性进行了初步的研究，并初步探讨了有机溶剂下温度对其荧光强度的影响。     

HDPE/LLDPE reactor blends with bimodal microstructures—part I: mechanical properties

Reactor blends of polyethylene/poly(ethylene-co-1-octene) resins with bimodal molecular weight and bimodal short chain branching distributions were synthesized in a two-step polymerization process. The compositions of these blends range from low molecular weight (LMW) homopolymer to high molecular weight (HMW) copolymer and, vice versa, HMW homopolymer to LMW copolymer. The physical properties of the blends were found to be consistent with the nature of the individual components. For the tensile properties, the stiffness decreases with increasing the fraction of the copolymer, regardless of the molecular weight of the homopolymer fraction. For these blends with bimodal microstructures, it was confirmed that the degree of crystallinity governs the stiffness of the polymer. However, the energy dampening properties of the polymers benefit from the presence of the copolymer. A balance of stiffness and toughness can be obtained by altering the composition of the blends. For some blends, the presence of HMW homopolymer can dominate the tensile properties, showing little variation in the stiffness with increased addition of copolymer. It was also demonstrated that the testing conditions and thermal treatment of the polymer greatly influence the resulting elastic and energy dampening properties. Depending on the desired application, annealing these polymers (especially very low density copolymers) not only increases the crystallinity and stiffness, but also changes the frequency response of the dynamic mechanical properties.     

电化学氧化法处理生活污水的研究

采用电化学氧化法处理生活污水,探讨了电解质浓度、电流密度、pH值、反应温度、不同电极等对COD、浊度的影响。实验表明,处理水中COD、浊度的最佳条件是:电解质浓度为45 g/L,pH值为8,电流密度为60 mA/m2,温度为22℃,阳极为RuSn电极,阴极使用不锈钢电极。此时COD去除率达86.22%,浊度去除率达80%,悬浮固体去除率和细菌去除率94%和99%。     

氢化物发生的机理及其在原子光谱中的应用

详细介绍了氢化物发生的反应体系和氢化反应的两种机理,并讨论了氢化物发生法在原子光谱中的应用现状和发展趋势。     

Preparation and Catalytic Performance of Mesostructured Aluminosilicate Nano-particles with Wormhole-Like Framework Structure

A facile two-step sol–gel method has been developed for the preparation of mesostructured aluminosilicate nano-particles (Si/Al = 7.5) with wormhole-like but uniform pore structures and highly catalytic activities towards bulky hydrocarbon cracking. It is desirable that, as this synthesis takes place in the absence of alkali cations, the mesoporous nano-particulate material is directly obtained in the acid form, making a subsequent ion-exchange and calcination treatment superfluous.     

界面改性PA6/TPE共混物的形态结构与性能

通过控制马来酸酐(MAH)的用量制得不同接枝率的马来酸酐接枝热塑性弹性体(TPE-g-MAH),利用其与尼龙6(PA6)在共混过程中的反应增容作用,实现了与PA6的相容共混,并研究了PA6/TPE共混物的结构与性能。结果表明,TPE-g-MAH可有效地提高PA6/TPE共混物的韧性,且随着其接枝率的增加,共混物的韧性提高;TPE-g-MAH有效地改善了PA6/TPE共混物的界面相容性,并且随着其含量的增加,相界面增容效果变好。     

Detecting video frame-rate up-conversion based on periodic properties of inter-frame similarity

Video frame-rate up-conversion is one of the common operations for tampering digital videos in the temporal domain, such as creating fake high-quality videos and splicing two video clips with different frame rates. However, few existing works have been proposed for detecting this form of tampering operation. Based on the analysis of extensive experiments, we found that frame-rate up-conversion algorithms employed in most current video editing softwares will inevitably introduce some periodic artifacts into inter-frame similarity in the resulting video frame sequence. By analyzing such artifacts, we propose a simple yet very effective method to expose video after frame-rate up-conversion, and further estimate its original frame rate. The experimental results evaluated on 100 original videos at different frame rates have shown the effectiveness of the proposed method. The average detection accuracy can achieve as high as 99 % on noise-free videos in uncompressed and H.264/AVC formats. Besides, the proposed method is robust to noise as the detection accuracy could reach over 85 % and 95 % on noised videos with Gaussian white noise when SNR is 33 db and 36 db respectively.     

The relationship between resources and capabilities of new ventures in emerging economies

Despite the fact that the resource-based view has drawn a great deal of attention in studying new ventures, our understanding on resource management in the emerging economies is limited and there are many unsolved issues. In this paper, theoretical reasoning approach is applied to analyze the relationship between the entrepreneurial resources and the organizational capabilities (including operating and dynamic capabilities) for new ventures. An empirical study in the context of emerging economy in China is conducted to verify the theoretical reasoning. As information technology becomes a key element for new ventures, the enterprise resources relevant to the network technology and e-commerce are especially focused, as well as the impact of information acquisition on the resource combination. The results from the theoretical and empirical study have shown that resource combination mediates the relationship of entrepreneurial resources and organizational capability. It is also found that the information acquisition affects the organizational capabilities significantly; however, there is an inverted U-shape relationship between the information acquisition and the resource combination in emerging economies .     

Adsorption of benzoic acid by CTAB exchanged montmorillonite

This paper reports the adsorption of benzoic acid from water on cetyl trimethylammonium exchanged montmorillonite (CTAB-montmorillonite). Important factors are the adsorbent concentration, ionic strength, equilibrium time and pH. The largest adsorption is at pH 9. The adsorption kinetics data fitted the pseudo-second-order equation. The adsorption isotherms at different pH were linear indicating a partition mechanism. Up to about 61% of the dissolved benzoic acid was adsorbed by CTAB-montmorillonite. These results indicate that CTAB-montmorillonite is a potential adsorbent for benzoic acid.     

改性膨润土对甲基橙的吸附

在用Cu^2 A‘^3 Fe^3 对膨润土改性中，Fe^3 改性的膨润土对甲基橙的吸附性能最好，在振荡20分钟后即可达到吸附平衡。pH=3～7、用量为3g／L、25℃时对甲基橙的吸附量达到最大，在pH=7及常温条件下，铁基膨润土的用量为11g／L时，对浓度为250mg／L甲基橙的吸附量和去除率分别为22.2mg／g98．6％；对浓度为40mg／L的甲基橙去除率达97.1％。