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33.
N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究 总被引:1,自引:1,他引:0
用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0~10.0,反应温度15~20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3~6.5。 相似文献
34.
Ching‐Nan Chuang Liang Chao Ying‐Jie Huang Tar‐Hwa Hsieh Hung‐Yi Chuang Shu‐Chi Lin Ko‐Shan Ho 《应用聚合物科学杂志》2008,107(6):3917-3924
The synthesis of a p‐toluidine/formaldehyde (PTF) resin was performed, and the effects of the molar ratio of the individual monomers and the polymerization conditions on the structure of the PTF resin were studied. Fourier transform infrared and 13C‐NMR spectra were used to characterize the PTF. Wide‐angle X‐ray diffraction patterns revealed the crystalline structures of various PTFs. Polarized optical microscopy revealed that the molar ratio of the monomers had a strong effect on the crystalline morphologies. A longer polymerization time turned out a polymer with a higher intrinsic viscosity and molecular weight, which led to differences in the proton conductivity. All of the PTFs showed a higher proton conductivity than a commercial Nafion membrane at 90–100°C and 0% relative humidity. The proton conductivity of the PTF series could be improved by sulfonation with sulfuric acid and could be maintained after blending with polyurethane. Pure methanol could be used as a fuel source because of the insolubility and nonwetting properties of PTF in methanol to increase the output current density for a PTF membrane electrode assembly. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
35.
A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
36.
可编程控制器在恶劣环境下比继电器,接触器安全,可靠,耐用,以水压试验机编程控制器程序控制为例。阐述了液压,气动。电气联合作用下系统的可编程控制设计方法以及防干扰措施。 相似文献
37.
Conventional cancer therapies, the second leading cause of death worldwide, result in serious side effects and, at best, merely extend the patient''s lifespan by a few years. Searching for effective prevention is of high priority in both basic and clinical sciences. In recent decades natural products have been considered to be an important source of cancer chemopreventive agents. Red wine polyphenols, which consisted of various powerful antioxidants such as flavonoids and stilbenes, have been implicated in cancer prevention and that promote human health without recognizable side effects. Since resveratrol, a major component of red wine polyphenols, has been studied and reviewed extensively for its chemopreventive activity to interfere with the multi-stage carcinogenesis, this review focuses on recent progress in studies on cancer chemopreventive activities of red wine polyphenol extracts and fractions as well as other red wine polyphenols, like procyanidin B5 analogues and myricetin. 相似文献
38.
Flammability ranking of foliage species by factor analysis of physical and chemical pyric properties
In this paper, factor analysis is introduced to evaluate the flammability of 55 foliage species that may be used in China for construction of the fuel break network of forest strips with lower flammability. Six pyric parameters, i.e. air dry moisture content, absolute dry moisture content, ignition point, ash content, caloric value and extractive content, are measured and used as variables for factor analysis. The covariance analysis shows that four principal factors can be extracted to reflect the flammability in different physical and chemical senses. In terms of the contributions of the four factors to the variances and the physical significance of the relevant parameters, the four factors are, respectively, termed as ‘flaming factor,’ ‘air dry factor,’ ‘ash factor’ and ‘absolute dry factor.’ The stability of the factor analysis method is examined by a different number of samples considered, and the variation degrees of the orderings indicate that the method has high reliability to measure the total flammability of foliage species. The results of the flammability evaluation are verified by comparison with the recommended tree species in the Chinese technology standard. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
39.
Following the original model for a single cell/dendrite growth by Hunt,[5] systematic numerical simulations are carried out with focus on cell shape evolution and tip radius selection in a directional
solidification process conducted in a capillary tube. Computations indicate that the anisotropy of solid/liquid interfacial
energy and the diameter of a capillary tube have significant influences on the selection of a tip shape. The anisotropy in
dilute SCN-salol alloys has been determined through the equilibrium droplet shape method and its value is 1.09 pct. The calculated
cell/dendrite shapes with this value of anisotropy agree with experimental observations where a single cell/dendrite of SCN-salol
alloys grows in a capillary tube. 相似文献
40.
The authors demonstrate, for the first time, a three node optically time division multiplexed network with a maximum capacity of 40 Gbit/s. Electro-optical switches were used for both `drop and insert' and demultiplexing, and electronic clock recovery provided synchronisation throughout the network 相似文献