IR and Raman studies and effect of γ radiation on crystallization of some lead borate glasses containing Al2O3

IR and Raman spectra of glass ceramics based on PbO-Cr₂O₃-B₂O₃glass composition system have been studied. The bands characteristic of BO₃. and BO₄ functional groups are present in all the samples. An incorporation of Al₂O₃(up to 5 mol%) in the initial glass composition considerably changes the glass network structure and relative concentrations of BO₃ and BO₄ groups. The composition 50 PbO-20 Cr₂O₃-25 B₂O₃-5 Al₂O₃(in mol%) reveals a maximum fraction of boron in the BO₄ group. A sample of this composition heat treated at 850° C for 25 h shows a maximum crystallization fraction with Pb₂O · CrO₄ as a prominent crystalline phase. The glasses irradiated with rays inhibit the crystallization into the Pb₂O · CrO₄ phase. They also show relatively smaller thermal conductivity.     

Selective flocculation of iron oxide-kaolin mixtures using a modified polyacrylamide flocculant

High molecular weight polyacrylamides were synthesized and successfully modified to contain up to 8·3% hydroxamate functional groups. The selective flocculation tests carried out on 1:1 iron oxide/kaolin mixtures using parent polyacrylamide, polyacrylic acid and the modified polyacrylamide, confirm the possibility of enhancing selectivity through introduction of iron chelating functional groups in commercially available polymers. Starting with a feed grade of 35% iron, 92% recovery with acceptable grade of 60% iron has been achieved using the modified polyacrylamide. NCL communication No. 4415     

The Oseen model for internal separated flows

Summary The flow field studied in this paper is the viscous laminar, separated flow downstream of a sudden expansion in a two-dimensional duct. The flow is modelled by the Oseen equations and a solution is sought for the downstream flow given the conditions at the sudden expansion. First, the exact solution to a high-Reynolds-number limit equation suggested by Kumar and Yajnik [6] is obtained. Next, the solution to the full equations is sought in terms of an eigenfunction-expansion procedure which leads to a non-standard eigenvalue problem. A detailed study is made of the latter and a number of expansion procedures are considered for the boundary-value problem. Specific calculations of the separated flow are presented for Reynolds numbers R=10 ⁿ , n=0–5. It is found that as R the solution of the full equation does indeed agree with the solution of the high-Reynolds-number limit equation. In particular it is found that the length of the recirculating region x _r scales with R as R.     

How In-Home Technologies Mediate Caregiving Relationships in Later Life

In-home technologies can support older adults' activities of daily living, provide physical safety and security, and connect elders to family and friends. They facilitate aging in place while reducing caregiver burden. One of older adults' primary concerns about in-home technologies is their potential to reduce human contact, particularly from cherished caregivers. In this exploratory in situ study, we provided an ecosystem of networked monitoring technologies to six older adults and their caregivers. We analyzed the amount and content of communication between them. The amount of noncomputer-mediated communication did not decrease through the 6-week study. The content of communication coalesced into four themes: communication about the technologies, communication facilitated by technologies, intrusiveness of technologies, and fun and playfulness with the technologies. Results suggest that in-home technologies, designed with sensitivity to older adults' primary motivations, have the potential to shape and tailor important relationships in later life.     

A new parallel algorithm for parsing arithmetic infix expressions

A new parallel algorithm for transforming an arithmetic infix expression into a par se tree is presented. The technique is based on a result due to Fischer (1980) which enables the construction of the parse tree, by appropriately scanning the vector of precedence values associated with the elements of the expression. The algorithm presented here is suitable for execution on a shared memory model of an SIMD machine with no read/write conflicts permitted. It uses O(n) processors and has a time complexity of O(log²n) where n is the expression length. Parallel algorithms for generating code for an SIMD machine are also presented.     

Trajectory generation for the N-trailer problem using Goursatnormal form

Develops the machinery of exterior differential forms, more particularly the Goursat normal form for a Pfaffian system, for solving nonholonomic motion planning problems, i.e., motion planning for systems with nonintegrable velocity constraints. The authors use this technique to solve the problem of steering a mobile robot with n trailers. The authors present an algorithm for finding a family of transformations which will convert the system of rolling constraints on the wheels of the robot with n trailers into the Goursat canonical form. Two of these transformations are studied in detail. The Goursat normal form for exterior differential systems is dual to the so-called chained-form for vector fields that has been studied previously. Consequently, the authors are able to give the state feedback law and change of coordinates to convert the N-trailer system into chained-form. Three methods for planning trajectories for chained-form systems using sinusoids, piecewise constants, and polynomials as inputs are presented. The motion planning strategy is therefore to first convert the N-trailer system into Goursat form, use this to find the chained-form coordinates, plan a path for the corresponding chained-form system, and then transform the resulting trajectory back into the original coordinates. Simulations and frames of movie animations of the N-trailer system for parallel parking and backing into a loading dock using this strategy are included     

A computational method for regularized long wave equation

Quintic spline technique and splitting method have been used to develop a new-finite difference method to solve regularized long wave (RLW) equation. The convergence and the stability of the proposed method are discussed. Then, it is used to model solitary wave motion and undular bore development by solving two test examples.     

CSCC for the mean and standard deviation of non-normally distributed life test data

In this paper Cumulative Sum Control Charts (CSCC) have been constructed for the mean and standard deviation of non-normally distributed life test data. The parameters of the V-mask have been determined and finally the expression for the Average Run Length is derived.     

Nonlinear optical studies on new conjugated poly{2,2l‐(3,4‐ dialkoxythiophene‐2,5‐diyl) bis[5‐(2‐thienyl)‐1,3,4‐oxadiazole]}s

Three new donor–acceptor type poly{2,2^l‐(3,4‐ dialkoxythiophene‐2,5‐diyl)bis[5‐(2‐thienyl)‐1,3,4‐oxadiazole]}s ( P1, P2, and P3 ) were synthesized starting from thiodiglycolic acid and diethyl oxalate through multistep reactions. The polymerization was carried out using chemical polymerization technique. The optical and charge‐transporting properties of the polymers were investigated by UV‐visible, fluorescence emission spectroscopic and cyclic voltammetric studies. The polymers showed bluish‐green fluorescence in solutions. The electrochemical band gaps were determined to be 2.03, 2.09, and 2.17 eV for P1 , P2, and P3, respectively. The nonlinear optical properties of new polymers were investigated at 532 nm using single beam Z‐scan and degenerate four‐wave mixing (DFWM) techniques with nanosecond laser pulses. The polymers exhibited strong optical limiting behavior due to “effective” three‐photon absorption. Values of the effective three‐photon absorption ( 3PA ) coefficients, third‐order nonlinear susceptibilities (χ⁽³⁾), and figures (F) of merit were calculated. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Superior Analog Performance due to Source-Gate Overlap in Vertical Line-Tunneling FETs and Their Circuits

Silicon - This paper presents a Vertical Line-Tunneling FET (VLTFET) optimized for superior performance in analog applications. The saturation mechanism, DC, and small-signal behaviors are...