Solid-state spun fibers and yarns from 1-mm long carbon nanotube forests synthesized by water-assisted chemical vapor deposition

We report continuous carbon nanotube (CNT) fibers and yarns dry-drawn directly from water-assisted chemical vapor deposition (CVD) grown forests with about 1-mm height. As-drawn CNT fibers exist as aerogel and can be transformed into more compact fibers through twisting or densification with a volatile organic liquid. CNT fibers are characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, Raman microscopy, and wide-angle X-ray diffraction. Mechanical properties and electrical conductivity of the post-treated CNT fibers are investigated. The resulting fibers show the work of rupture of 30 J/g and DC electrical conductivity of 5.0 × 10⁴ S/m.     

The impact of cross-training on team effectiveness.

The authors examined the role of cross-training in developing shared team-interaction mental models, coordination, and performance in a 2-experiment study using computer simulation methodology (for Experiment 1, N=45 teams; for Experiment 2, N=49 teams). Similar findings emerged across the 2 experiments. First, cross-training enhanced the development of shared team-interaction models. Second, coordination mediated the relationship between shared mental models and team performance. However, there was some inconsistency in the findings concerning the depth of cross-training necessary for improving shared mental models. Results are discussed in terms of the impact of different levels of cross-training on team effectiveness. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

能源发展四大趋势

两年前,剑桥能源研究协会曾经预测油价将在120美元到150美元之间徘徊。如今,油价在一路起起伏伏的过程中印征了剑桥的预言。随着油价的走势,能源市场也面临着巨大的冲击。石油行业未来的发展趋势是什么？投资的主导方向又在哪里？剑桥能源研究协会高级主任Shawn Carraher先生一一解答了这些问题,并指出了能源发展的四大趋势。     

Mothers' and children's expectations for adolescence: The impact of perceptions of an older sibling's experience.

The present study examined the role of perceived experience with an older child in mothers' expectations for subsequent children's adolescence as well as the impact of perceived experience with an older sibling on young adolescent children's expectations for their own adolescence. Participants were 305 sixth- and seventh-grade adolescents and 287 of their mothers. Participants were interviewed via telephone. For both mothers and children, the quality of experience with an older child/sibling was a better predictor of target-based expectations for the young adolescent than was the simple presence or absence of an older sibling. In some cases the link between quality of experience with an earlier born adolescent and mothers' expectations for the target child's adolescence was modified by the target child's temperament. In general, the results support a modeling hypothesis. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

北京智化寺藏殿:一种空间营造思想的研究

北京智化寺藏殿建筑梁架、斗栱、彩画、雕饰与造像完整,是一处难得的完整保留了明代空间特色的建筑遗存。本文以智化寺藏殿及其经藏为主要研究对象,首先通过文字史料与遗迹现象互证,廓清智化寺营造史与藏殿形制中的两大“反常”之处：“快速建造”与“不能转的转轮经藏”,并指出后者可能为明正统年间的新创形式。其次,通过对相关图像与实物的比较及对历史环境的分析,探讨新形式可能的来源。最后,尝试重建明正统年间智化寺藏殿的空间意象,并解析这些意象背后的四种突破“常规”的形式操作方法：一,功能的集约化;二,意义的整合与渗透; 三,空间的轴线、比例与分层;四,装饰表皮与结构骨架分离。通过对营造意图与操作方法的双重解读,得以更加深入地认识古代营造者面对特定问题时展现的设计智慧。     

Discovery of Quinoline‐Derived Trifluoromethyl Alcohols,Determination of Their in vivo Toxicity and Anticancer Activity in a Zebrafish Embryo Model

In this study the rational design, synthesis, and anticancer activity of quinoline‐derived trifluoromethyl alcohols were evaluated. Members of this novel class of trifluoromethyl alcohols were identified as potent growth inhibitors in a zebrafish embryo model. Synthesis of these compounds was carried out with an sp³‐C?H functionalization strategy of methyl quinolines with trifluoromethyl ketones. A zebrafish embryo model was also used to explore the toxicity of ethyl 4,4,4‐trifluoro‐3‐hydroxy‐3‐(quinolin‐2‐ylmethyl)butanoate ( 1 ), 2‐benzyl‐1,1,1‐trifluoro‐3‐(quinolin‐2‐yl)propan‐2‐ol ( 2 ), and trifluoro‐3‐(isoquinolin‐1‐yl)‐2‐(thiophen‐2‐yl)propan‐2‐ol ( 3 ). Compounds 2 and 3 were found to be more toxic than compound 1 ; apoptotic staining assays indicated that compound 3 causes increased cell death. In vitro cell proliferation assays showed that compound 2 , with an LC₅₀ value of 14.14 μm , has more potent anticancer activity than cisplatin. This novel class of inhibitors provides a new direction in the discovery of effective anticancer agents.     

Towards a hydrodynamic modelling framework appropriate for applications in urban flood assessment and mitigation using heterogeneous computing

We present a new hydrodynamic modelling framework capable of fully exploiting modern graphics and central processing units (GPUs and CPUs) from any of the mainstream vendors, to be used in the design and assessment of sustainable drainage systems. A finite-volume Godunov-type scheme is combined with the HLLC Riemann solver to create a robust numerical model which correctly addresses wetting and drying and transient flow conditions, and is suitable for application to a wide range of flood simulations. The software is tested with a three day flood event in Carlisle during 2005, at resolutions from 25 m to 2 m. Run-times are significantly reduced without compromising numerical accuracy. Excellent agreement is found between the simulation results and a comprehensive post-event survey. Changes in sensitivity to Manning's n are examined at different resolutions, with changes to the floodplain found to have little influence at 2 m resolution.     

Synthesis and electrospun fiber mats of low Tg poly(propylene fumerate‐co‐propylene maleate)

Many publications have examined the biodegradable polymer poly(propylene fumate) (PPF) for use in tissue engineering applications. We have examined a similar crosslinkable polymer system, poly(propylene fumerate)‐co‐(propylene maleate) (PPFcPM), derived from maleic anhydride (MA) and 1,2‐propylene diol (PD). This copolymer system uses a less expensive monomer as well as leads to varied ratios of fumerate to maleate groups, allowing tuning of the crosslinked polymer properties such as degradation rate. Two different reaction conditions were used to synthesize the copolymer from MA and PD. In the first case (Method A), toluene was used as a solvent to azeotropically (85°C) remove water to drive the acid catalyzed esterification reaction. In the second case (Method B), the initial ring opening reaction was conducted, followed by addition of catalyst and removal of water to produce polymer of higher molecular weight. Both polymer systems had glass transition temperatures (T_g) below room temperature. The low T_g PPFcPM was dissolved in chloroform along with the photoinitiator phenylbis(2,4,6‐trimethylbenzoyl)‐phosphine oxide (BAPO) and electrospun. The polymer fibers were crosslinked soon after they formed to produce noncalendaring 3D porous scaffolds. Control experiments without the BAPO photoinitiator did not produce fiber mats. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010