Polymeric nanofibers containing solid nanoparticles prepared by electrospinning and their applications

Generally, polymer solution or sol–gel is used to produce electrospun nanofibers via the electrospinning technique. In the utilized sol–gel, the metallic precursor should be soluble in a proper solvent since it has to hydrolyze and polycondensate in the final solution; this strategy straitens the applications of the electrospinning process and limits the category of the electrospinnable materials. In this study, we are discussing electrospinning of a colloidal solution process as an alternative strategy. We have utilized many solid nanopowders and different polymers as well. All the examined colloids have been successfully electrospun. According to the SEM and FE SEM analyses for the obtained nanofiber mats, the polymeric nanofibers could imprison the small nanoparticles; however, the big size ones were observed attaching the nanofiber mats. Successfully, the proposed strategy could be exploited to prepare polymeric nanofibers incorporating metal nanoparticles which might have interesting properties compared with the pristine. For instance, PCL/Ti nanofiber mats exhibited good bioactivity compared with pristine PCL. The proposed strategy can be considered as an innovated methodology to prepare a new class of the electrospun nanofiber mats which cannot be obtained by the conventional electrospinning technique.     

Functionalization of Electrospun Titanium Oxide Nanofibers with Silver Nanoparticles: Strongly Effective Photocatalyst

In the present study, we are introducing silver-doped titanium oxide nanofibers produced by electrospinning technique. Calcination of dry nanofiber mats consisting of silver nitrate–titanium isopropoxide/PVAc in air at 600°C for 1 h leads to produce Ag-doped titania nanofibers. Two dyes have been invoked to check the photocatalytic ability of the produced nanofibers; methylene blue dihydrate and methyl red. The obtained results indicated that the silver-doped titanium oxide nanofibers can eliminate >92% of the methylene blue dye within 10 min only. In a case of methyl red, almost the dye was decayed (93%) within 3 h.     

Technological innovations and 3G mobile phone diffusion: Lessons learned from Japan

Technology and innovation become more important determinants of corporate competitiveness, and the telecommunications sector is no exception. A good example is found in the development of the mobile phones. Technological development, embodied in innovative functions developed from the first (1G) to third generation (3G) systems, has played significantly important roles in the growth and upheavals of the Japanese mobile phone market. In addition, development in contents, value-added services which are supplied by related firms formed in the vertical structure, charging systems, handset development; all these have made this small gadget an increasingly important part of daily life.     

Successful Use of Geoelectrical Surveys in Area 3 of the Gol-e-Gohar Iron Ore Mine,Iran

Geoelectrical surveys were conducted in Area 3 of the Gol-e-Gohar iron ore mine to provide geological and hydrogeological information. Open pit mining is currently underway in the northern part of the Area, and underground mining operations are planned for the southern section. Groundwater has already been encountered in the open pit mine. Twenty five resistivity soundings were first performed in the mine area; then, induced polarization (IP) measurements were carried out to remove ambiguities between clay and water-bearing layers. To investigate fault zones as water conduits, combined resistivity profiling surveys were also carried out. These measurements provided a detailed structural map of the pit area. Resistivity and IP results have subsequently been confirmed by observations at three monitoring wells and the mine pit wall. Monitoring and piezometric wells will be drilled at locations suggested by the results of the geoelectrical surveys. Drainage galleries may be developed to dewater the open pit mine. However, another option being considered is to start the underground mining with the idea that it will initially simply serve as a dewatering mechanism.     

Crosstalk Stability Analysis in Multilayer Graphene Nanoribbon Interconnects

In this paper a time-domain response and Nyquist stability criterion to acquire dependence of degree of crosstalk relative stability based on transmission lines modeling (TLM) is investigated for coupled multilayer graphene nanoribbon (MLGNR) interconnects. This is the first instance that such an analysis has been presented for coupled MLGNR consisting of both capacitive and mutual-inductive couplings. The near-end and far-end outputs of coupled MLGNR individually are compared in two cases, with considering both couplings and without them (single MLGNR). It is observed that the near-end output of the system together with both couplings is more stable and at its far-end output, an induced voltage is created. By increasing capacitive coupling or decreasing inductive coupling, the near-end output becomes more stable. Also, the results of changes of length and width of each ribbon show that by increasing the length and decreasing the width, the coupled MLGNR interconnects become more stable.     

Spinel-Coated Graphite for Carbon Containing Refractory Castables

Oxidation resistance and water wettability of graphite flakes have been improved by a thin sol–gel film of magnesium aluminate spinel (MgAl₂O₄) over its surface. The hydrosol has been synthesized by less expensive precursors and the spinel formation has been studied by scanning electron microscopy (SEM), supplemented with energy dispersive spectral analysis. After an easy-to-use mixing procedure, drying (110°C), and subsequent calcination (550°C), coated graphites were sieved to below 75 μm. The coating over the powder contained 1.5 wt% MgAl₂O₄, which enormously increased the oxidation resistance (performed at 600°, 900°, and 1200°C) and water wettability, as revealed by hydrophilic functional groups from infrared spectra. Defective, intermediate spinel structure of fine, lamellar Mg-doped γ-Al₂O₃ has been considered to be significant for this improvement. An approximate (1:2) stoichiometry of (Mg:Al) in the coating composition was confirmed by an X-ray photoelectron spectroscopy test. Castables prepared by this graphite remarkably improved their bulk density and apparent porosity compared with those prepared by the as-received graphite. Casting water was reduced along with the amount of antioxidants. This also enhanced the resistance toward the basic slag by retaining the graphite in the refractory.     

Dendrigraft with citric acid on acrylonitrile/acrylic acid copolymer electrospun fibres

Acrylonitrile/acrylic acid copolymers were synthesized with different mole fractions (1, 2, 5 and 10 mol%) of acrylic acid (AA) in the feed by aqueous suspension polymerization, and bead‐free fibres (295–375 nm in diameter) were made from the copolymers in dimethylformamide solutions by electrospinning. In a heterogeneous system containing electrospun fibre mats, dendritic molecules were grown by reaction between carboxylic acid of AA and –OH groups of citric acid activated by dicyclohexylcarbodiimide. The products were analysed using ¹H NMR, ¹³C NMR and Fourier transform infrared spectroscopies, density determination, scanning electron microscopy, optical microscopy, differential scanning calorimetry and pH response properties. With decreasing AA content, the isotacticity of the copolymers decreases with a more random distribution of the co‐monomers which leads to higher percentage conversions of dendrigraft due to reduced steric hindrance. On the formation of dendrigraft, the percentage conversion of the reactions decreases with an increase of generation number and AA content. A reduction of density for the first generation and then an increase with increasing generation are observed. During oxidation stabilization of fibres with a decrease of AA content and an increase in generation number, the amount of liberated heat increases. Fibres containing more carboxylic groups show significantly greater amounts of swelling/de‐swelling in basic and acidic media, respectively. To be used as nanocarbon fibre precursors, or as active particles for loading with guest molecules, or as pH actuators, the first generation of dendrigrafted fibres are expected to have the greatest potential among the various samples examined. © 2013 Society of Chemical Industry