Spinel-Coated Graphite for Carbon Containing Refractory Castables

Oxidation resistance and water wettability of graphite flakes have been improved by a thin sol–gel film of magnesium aluminate spinel (MgAl₂O₄) over its surface. The hydrosol has been synthesized by less expensive precursors and the spinel formation has been studied by scanning electron microscopy (SEM), supplemented with energy dispersive spectral analysis. After an easy-to-use mixing procedure, drying (110°C), and subsequent calcination (550°C), coated graphites were sieved to below 75 μm. The coating over the powder contained 1.5 wt% MgAl₂O₄, which enormously increased the oxidation resistance (performed at 600°, 900°, and 1200°C) and water wettability, as revealed by hydrophilic functional groups from infrared spectra. Defective, intermediate spinel structure of fine, lamellar Mg-doped γ-Al₂O₃ has been considered to be significant for this improvement. An approximate (1:2) stoichiometry of (Mg:Al) in the coating composition was confirmed by an X-ray photoelectron spectroscopy test. Castables prepared by this graphite remarkably improved their bulk density and apparent porosity compared with those prepared by the as-received graphite. Casting water was reduced along with the amount of antioxidants. This also enhanced the resistance toward the basic slag by retaining the graphite in the refractory.     

Dendrigraft with citric acid on acrylonitrile/acrylic acid copolymer electrospun fibres

Acrylonitrile/acrylic acid copolymers were synthesized with different mole fractions (1, 2, 5 and 10 mol%) of acrylic acid (AA) in the feed by aqueous suspension polymerization, and bead‐free fibres (295–375 nm in diameter) were made from the copolymers in dimethylformamide solutions by electrospinning. In a heterogeneous system containing electrospun fibre mats, dendritic molecules were grown by reaction between carboxylic acid of AA and –OH groups of citric acid activated by dicyclohexylcarbodiimide. The products were analysed using ¹H NMR, ¹³C NMR and Fourier transform infrared spectroscopies, density determination, scanning electron microscopy, optical microscopy, differential scanning calorimetry and pH response properties. With decreasing AA content, the isotacticity of the copolymers decreases with a more random distribution of the co‐monomers which leads to higher percentage conversions of dendrigraft due to reduced steric hindrance. On the formation of dendrigraft, the percentage conversion of the reactions decreases with an increase of generation number and AA content. A reduction of density for the first generation and then an increase with increasing generation are observed. During oxidation stabilization of fibres with a decrease of AA content and an increase in generation number, the amount of liberated heat increases. Fibres containing more carboxylic groups show significantly greater amounts of swelling/de‐swelling in basic and acidic media, respectively. To be used as nanocarbon fibre precursors, or as active particles for loading with guest molecules, or as pH actuators, the first generation of dendrigrafted fibres are expected to have the greatest potential among the various samples examined. © 2013 Society of Chemical Industry     

Constructing a block layout by face area

Solving the facility layout problems by graph theory consists of two stages. In the first stage, a planar graph that specifies desired adjacencies is obtained and in the second stage, a block layout is achieved from the planar graph. In this paper, we introduce face area as a new concept for constructing a block layout. Based on this idea, we present a new algorithm for constructing block layout from a maximal planar graph (MPG). This MPG must be generated from deltahedron heuristic. Constructed block layout by this algorithm satisfies all of adjacency and area requirements.     

Gas-phase driven nano-machined TiO2 ceramics

A simple, inexpensive gas phase reaction termed as “nanocarving process” converts TiO₂ grains into arrays of single crystal nanofibers by selective and anisotropic etching. This process is conducted by exposing dense polycrystalline TiO₂ to a H₂/N₂ environment at 700 °C. The dimensions of nanofibers are around 20 nm in diameter and 1 μm in length. The preferred crystallographic orientation for the nanocarving process is the <001> direction. Nanoparticles composed of Fe and Ni were observed on the surface of TiO₂ that formed nanofiber tips. Sintering parameters before the nanocarving treatment play a critical role in the formation of nanofibers. As sintering temperature and time increased, the rate of nanofiber generation decreased. Moreover, it was observed that by varying the heat treatment conditions, it is possible to create other structures like nanowhiskers and nanofilaments. Nanowhiskers were formed by reoxidation of nanofiber-formed TiO₂ over 600 °C. Nano-filaments were generated by heat treating sintered TiO₂ in N₂-carrying water vapor at 700 °C.     

A Novel Evolutionary-Based Cooperative Spectrum Sensing Mechanism for Cognitive Radio Networks

Cognitive radio (CR) is considered as a feasible intelligent technology for 4G wireless networks or self-organization networks and envisioned as a promising paradigm of exploiting intelligence for enhancing efficiency of underutilized spectrum bands. In CR, one of the main concerns is to reliably sense the presence of primary users, to attain protection against harmful interference caused by the potential spectrum access of secondary users (SUs). In this paper, evolutionary algorithms, namely, genetic algorithm (GA) and particle swarm optimization (PSO) are investigated. An imperialistic competitive algorithm (ICA) is proposed to minimize error detection at the common soft data fusion (SDF) center for structurally centralized cognitive radio network (CRN). By using these techniques, evolutionary operations are invoked to optimize the weighting coefficients applied on the sensing measurement components received from multiple cooperative SUs. The proposed method is compared with other evolutionary algorithms, as well as other conventional deterministic, such as maximal ratio combining- (MRC-), modified deflection coefficient- (MDC-), normal deflection coefficient- (NDC-) based SDF schemes and OR-rule HDF based. MATLAB simulations confirm the superiority of the ICA-based scheme over the PSO-, GA-based and other conventional schemes in terms of detection performance. In addition, the ICA-based scheme also shows promising convergence and time running performance as compared to other iterative-based schemes. This makes ICA an adequate solution to meet real-time requirements.