全文获取类型
收费全文 | 87488篇 |
免费 | 8700篇 |
国内免费 | 5181篇 |
专业分类
电工技术 | 6646篇 |
技术理论 | 2篇 |
综合类 | 6499篇 |
化学工业 | 13187篇 |
金属工艺 | 4608篇 |
机械仪表 | 5641篇 |
建筑科学 | 7388篇 |
矿业工程 | 2546篇 |
能源动力 | 2698篇 |
轻工业 | 6369篇 |
水利工程 | 1965篇 |
石油天然气 | 4438篇 |
武器工业 | 981篇 |
无线电 | 11058篇 |
一般工业技术 | 9526篇 |
冶金工业 | 3799篇 |
原子能技术 | 1254篇 |
自动化技术 | 12764篇 |
出版年
2024年 | 447篇 |
2023年 | 1406篇 |
2022年 | 2806篇 |
2021年 | 3956篇 |
2020年 | 2876篇 |
2019年 | 2298篇 |
2018年 | 2510篇 |
2017年 | 2932篇 |
2016年 | 2691篇 |
2015年 | 3803篇 |
2014年 | 4769篇 |
2013年 | 5746篇 |
2012年 | 6598篇 |
2011年 | 6811篇 |
2010年 | 6080篇 |
2009年 | 5835篇 |
2008年 | 5570篇 |
2007年 | 5379篇 |
2006年 | 5059篇 |
2005年 | 4154篇 |
2004年 | 2908篇 |
2003年 | 2277篇 |
2002年 | 2230篇 |
2001年 | 1816篇 |
2000年 | 1638篇 |
1999年 | 1489篇 |
1998年 | 1279篇 |
1997年 | 1024篇 |
1996年 | 1006篇 |
1995年 | 846篇 |
1994年 | 639篇 |
1993年 | 531篇 |
1992年 | 394篇 |
1991年 | 284篇 |
1990年 | 281篇 |
1989年 | 197篇 |
1988年 | 158篇 |
1987年 | 106篇 |
1986年 | 95篇 |
1985年 | 66篇 |
1984年 | 61篇 |
1983年 | 40篇 |
1982年 | 41篇 |
1981年 | 29篇 |
1980年 | 35篇 |
1979年 | 22篇 |
1978年 | 14篇 |
1977年 | 19篇 |
1976年 | 30篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
建立了1个快速测定纺织品中有害有机溶剂残留量的超高效液相色谱/静电场轨道阱高分辨质谱(UPLC/Orbitrap HRMS)方法,该方法以乙醇为萃取溶剂,100℃下微波萃取纺织品中残留的有害有机溶剂,萃取液直接进行UPLC/Orbitrap HRMS,提取离子色谱峰面积外标法定量。对样品的提取条件、分析条件进行了优化。该方法的定量限为0.5μg/kg~10.0μg/kg。在3个不同加标浓度水平下,方法的平均加标回收率为81.8~94.5%,相对偏差偏差为3.8%~10.5%(n=9)。该方法简便快速,灵敏度高,定量限低,可有效地解决纺织品中残留的有害有机溶剂的快速测定问题。 相似文献
982.
The formation mechanism of surface texture for feed-direction ultrasonic vibration?assisted milling (UVAM) was investigated in this study by establishing a kinematic model and a pressing model of UVAM. The kinematic model showed that the cutter tip, which was supposed to be totally sharp, produced closed scratches by crossed trajectories. The variation trends of the interval for closed textures were of sine function. A comparative experiment was carried out by UVAM and conventional milling. A dividing line close to the X coordinate divides the surface feature into two parts. The pressing model showed that the tool minor cutting edge left clear traces with certain width because of the tool minor cutting edge angle. Scratches by tool minor cutting edge were intermittent and regularly varied when feed-direction vibration was introduced. All the surface feature changes are in the radial direction and the trajectory intersections shall always be the scratch grooves or ridges. The ratio between ultrasonic vibration frequency and spindle speed, tool radius, and the located cutter rotation angle affected the changing rule of scratches by tool minor cutting edge. The analytical models and the experimental results proved to each other reasonable. 相似文献
983.
984.
Tao Shen Hailong Dai Mingxin Song Hongchen Liu Xinlao Wei 《Journal of Superconductivity and Novel Magnetism》2017,30(4):937-941
Y3?xCe x Fe5 O 12 (CeYIG) ceramics, with x = 0, 0.15, 0.25, 0.35, 0.45, and 0.5, were fabricated by a conventional ceramic sintering technique. We studied the structures and magnetic fields of a series of CeYIG ceramics using X-ray powder diffraction, a scanning electron microscope, and a superconducting quantum interference device magnetometer. Findings showed that the substitution limit of the concentration of Ce3+ ions in the yttrium iron garnet structure was approximately x = 0.25. An extra CeO2 phase was detected in the ceramic when the addition of CeO2 content overtook the limit. The lattice constants and relative densities increased by increasing the Ce3+ contents in the ceramics. First, the saturation magnetization increased gradually with increases in the substitute concentration of Ce3+ ions and then decreased gradually when x = 0.35, 0.45, and 0.5. Overall, this study showed that the Y3?xCe x Fe5 O 12 material with x ≤ 0.15 exhibited excellent magnetic properties. Hence, the material show promise for magneto-optical and microwave communication applications. 相似文献
985.
Poly(N‐phenylglycine)‐Based Nanoparticles as Highly Effective and Targeted Near‐Infrared Photothermal Therapy/Photodynamic Therapeutic Agents for Malignant Melanoma 下载免费PDF全文
Bang‐Ping Jiang Li Zhang Xiao‐Lu Guo Xing‐Can Shen Yan Wang Yang Zhu Hong Liang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(8)
Malignant melanoma is a highly aggressive tumor resistant to chemotherapy. Therefore, the development of new highly effective therapeutic agents for the treatment of malignant melanoma is highly desirable. In this study, a new class of polymeric photothermal agents based on poly(N‐phenylglycine) (PNPG) suitable for use in near‐infrared (NIR) phototherapy of malignant melanoma is designed and developed. PNPG is obtained via polymerization of N‐phenylglycine (NPG). Carboxylate functionality of NPG allows building multifunctional systems using covalent bonding. This approach avoids complicated issues typically associated with preparation of polymeric photothermal agents. Moreover, PNPG skeleton exhibits pH‐responsive NIR absorption and an ability to generate reactive oxygen species, which makes its derivatives attractive photothermal therapy (PTT)/photodynamic therapy (PDT) dual‐modal agents with pH‐responsive features. PNPG is modified using hyaluronic acid (HA) and polyethylene glycol diamine (PEG‐diamine) acting as the coupling agent. The resultant HA‐modified PNPG (PNPG‐PEG‐HA) shows negligible cytotoxicity and effectively targets CD44‐overexpressing cancer cells. Furthermore, the results of in vitro and in vivo experiments reveal that PNPG‐PEG‐HA selectively kills B16 cells and suppresses malignant melanoma tumor growth upon exposure to NIR light (808 nm), indicating that PNPG‐PEG‐HA can serve as a very promising nanoplatform for targeted dual‐modality PTT/PDT of melanoma. 相似文献
986.
Bo‐Quan Li Shu‐Yuan Zhang Cheng Tang Xiaoyang Cui Qiang Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(25)
The construction of active sites with intrinsic oxygen evolution reaction (OER) is of great significance to overcome the limited efficiency of abundant sustainable energy devices such as fuel cells, rechargeable metal–air batteries, and in water splitting. Anionic regulation of electrocatalysts by modulating the electronic structure of active sites significantly promotes OER performance. To prove the concept, NiFeS electrocatalysts are fabricated with gradual variation of atomic ratio of S:O. With the rise of S content, the overpotential for water oxidation exhibits a volcano plot under anionic regulation. The optimized NiFeS‐2 electrocatalyst under anionic regulation possesses the lowest OER overpotential of 286 mV at 10 mA cm?2 and the fastest kinetics being 56.3 mV dec?1 to date. The anionic regulation methodology not only serves as an effective strategy to construct superb OER electrocatalysts, but also enlightens a new point of view for the in‐depth understanding of electrocatalysis at the electronic and atomic level. 相似文献
987.
988.
Multicolor Photo‐Crosslinkable AIEgens toward Compact Nanodots for Subcellular Imaging and STED Nanoscopy 下载免费PDF全文
Xiaofeng Fang Xuanze Chen Rongqin Li Zhihe Liu Haobin Chen Zezhou Sun Bo Ju Yifei Liu Sean Xiao‐An Zhang Dan Ding Yujie Sun Changfeng Wu 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(41)
Aggregation induced emission (AIE) has attracted considerable interest for the development of fluorescence probes. However, controlling the bioconjugation and cellular labeling of AIE dots is a challenging problem. Here, this study reports a general approach for preparing small and bioconjugated AIE dots for specific labeling of cellular targets. The strategy is based on the synthesis of oxetane‐substituted AIEgens to generate compact and ultrastable AIE dots via photo‐crosslinking. A small amount of polymer enriched with oxetane groups is cocondensed with most of the AIEgens to functionalize the nanodot surface for subsequent streptavidin bioconjugation. Due to their small sizes, good stability, and surface functionalization, the cell‐surface markers and subcellular structures are specifically labeled by the AIE dot bioconjugates. Remarkably, stimulated emission depletion imaging with AIE dots is achieved for the first time, and the spatial resolution is significantly enhanced to ≈95 nm. This study provides a general approach for small functional molecules for preparing small sized and ultrastable nanodots. 相似文献
989.
Hollow Pd/MOF Nanosphere with Double Shells as Multifunctional Catalyst for Hydrogenation Reaction 下载免费PDF全文
Mingming Wan Xinlu Zhang Meiyan Li Bo Chen Jie Yin Haichao Jin Lin Lin Chao Chen Ning Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(38)
A new type of hollow nanostructure featured double metal‐organic frameworks shells with metal nanoparticles (MNPs) is designed and fabricated by the methods of ship in a bottle and bottle around the ship. The nanostructure material, hereinafter denoted as Void@HKUST‐1/Pd@ZIF‐8, is confirmed by the analyses of photograph, transmission electron microscopy, scanning electron microscopy, powder X‐ray diffraction, inductively coupled plasma, and N2 sorption. It possesses various multifunctionally structural characteristics such as hollow cavity which can improve mass transfer, the adjacent of the inner HKUST‐1 shell to the void which enables the matrix of the shell to host and well disperse MNPs, and an outer ZIF‐8 shell which acts as protective layer against the leaching of MNPs and a sieve to guarantee molecular‐size selectivity. This makes the material eligible candidates for the heterogeneous catalyst. As a proof of concept, the liquid‐phase hydrogenation of olefins with different molecular sizes as a model reaction is employed. It demonstrates the efficient catalytic activity and size‐selectivity of Void@HKUST‐1/Pd@ZIF‐8. 相似文献
990.