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991.
Monoclinic lithium vanadium phosphate, Li3V2(PO4)3, has been successfully synthesized using LiF as lithium source. The one-step reaction with stoichiometric composition and relative lower sintering temperature (700 °C) has been used in our experimental processes. The solid-state reaction mechanism using LiF as lithium precursor has been studied by X-ray diffraction and Fourier transform infrared spectra. The Rietveld refinement results show that in our product sintered at 700 °C no impurity phases of VPO4, Li5V(PO4)2F2, or LiVPO4F can be detected. The solid-state reaction using Li2CO3 as Li-precursor has also been carried out for comparison. X-ray diffraction patterns indicate that impurities as Li3PO4 can be found in the product using Li2CO3 as Li-precursor unless the sintering temperatures are higher than 850 °C. An abrupt particle growth (about 2 μm) has also been observed by scanning electron microscope for the samples sintered at higher temperatures, which can result in a poor cycle performance. The product obtained using LiF as Li-precursor with the uniform flake-like particles and smaller particle size (about 300 nm) exhibits the better performance. At the 50th cycle, the reversible specific capacities for Li3V2(PO4)3 measured between 3 and 4.8 V at 1C rate are found to approach 147.1 mAh/g (93.8% of initial capacity). The specific capacity of 123.6 mAh/g can even be hold between 3 and 4.8 V at 5C rate. 相似文献
992.
端氨基聚脲聚氨酯环氧树脂体系的固化反应及粘接性能 总被引:2,自引:0,他引:2
本文采用DTA和FT-IR研究了端氨基聚脲聚氨酯固化环氧树脂的反应特性,考察了被粘表面状态、偶联剂和促进剂、填料等对剪切强度性能的影响。并对该粘合剂耐化学腐蚀性进行了试验,说明具有好的耐腐蚀性。 相似文献
993.
Wei Zhang Zhao-Jun Mo ZhiHong Hao Jun Shen Jia-Wei Luo Rui-Jiang Chang Lan Li 《International Journal of Applied Ceramic Technology》2019,16(4):1606-1611
The magnetic properties and magnetocaloric effect for EuTi1-xFexO3 (x = 0.05, 0.1) compounds are investigated. When a part of Ti4+ions were substituted by Fe ions, the AFM ordering can be significantly changed to be FM. The EuTi1-xFexO3 (x = 0.05, 0.1) compounds exhibit a PM to FM transition with decreasing temperature and the Curie temperature is 6 K. Under the field changes of 1 T, and RC are valued to be 10.1 J/kg K and 50.2 J/kg for EuTi0.95Fe0.05O3; 9.6 J/kg K and 47.7 J/kg for EuTi0.9Fe0.1O3, without magnetic and thermal hysteresis. RC is almost twice as much as EuTiO3 (27 J/kg) as substitution of Fe3+ ions for Ti4+ions, which may be attributed to the magnetic transition (AFM to FM). Therefore, the giant and large RC suggest the EuTi1-xFexO3 compounds are good materials for magnetic refrigerant. 相似文献
994.
Molecular species of 1-O-alk-1′-enyl-2-acyl-, 1-O-alkyl-2-acyl-, and 1,2-diacyl-sn-glycero-3-phosphoethanolamine (EPL) andsn-glycero-3-phosphocholine (CPL) of Japanese oysterCrassostrea gigas were analyzed by selectedion monitoring gas chromatography/mass spectrometry using electron impact ionization. The characteristic
fragment ions, [RCH=CH+56]+ due to the alkenyl residue in thesn-1 position and [RCO+74]+ due to the acyl residue in thesn-2 position of alkenylacylglycerols, [R+130]+ due to the alkyl residue in thesn-1 position and [RCO+74]+ due to the acyl residue in thesn-2 position of alkylacylglycerols, [RCO+74]+ due to the acyl residues in thesn-1 and/orsn-2 positions of diacylglycerols, and [M−57]+ being indicative of the corresponding molecular weight, were used for structural assignments.
For alkenylacyl EPL and CPL, 19 and 16 molecular species were determined, respectively. Two molecular species, 18∶0alkenyl-22∶6n−3
and 18∶0-alkenyl-22∶2-non-methylene interrupted diene (NMID), amounted to 53.2% and 47.9%, respectively. The alkylacyl EPL
and CPL consisted of 16 and 20 molecular species, respectively, and the prominent components were 18∶0alkyl-22∶2NMID, 20∶1alkyl-20∶1n−11
(27.4%) and 20∶1alkyl-20∶2NMID (16.3%) in the former, and 16∶0alkyl-20∶5n−3 (23.0%) and 16∶0alkyl-22∶6n−3 (21.6%) in the latter.
For the diacyl EPL and CPL, 14 and 51 molecular species were determined, respectively. The major molecular species were 18∶0–20∶5n−3
(37.4%), 16∶0–20∶5n−3 (14.2%) and 18∶1n−7–22∶2NMID (13.2%) in the former, and 16∶0–20∶5n−3 (33.4%) and 16∶0–22∶6n−3 (22.3%)
in the latter. It was found that there were significant differences in the molecular species between the alkylacyl and diacyl
EPL and the alkylacyl and diacyl CPL; the number of molecular species was larger in CPL than in EPL, while the number of total
carbons and double bonds of the major molecular species were larger in the EPL than in the CPL. Alkenylacyl EPL were similar
to alkenylacyl CPL in molecular species composition. 相似文献
995.
0 引言传统的粉磨工艺是将矿渣与熟料混合入球磨机进行粉磨,当综合比表面积达到350m~2/kg时,水泥中的矿渣粉比表面积仅能达到270~280m~2/kg,矿渣粉的 相似文献
996.
Studies on Macro-kinetics of Gas Phase Polymerization of Butadiene with Rare-earth Catalyst 下载免费PDF全文
The study of the kinetics of gas phase polymerization of butadiene with heterogeneous catalyst based on neodymium (Nd) was carried out. The effects of reaction temperature, reaction pressure, dispersing medium, and types of catalyst on kinetics of polymerization were investigated. A kinetic model with two kinds of active sites was proposed. The results show that the effects of the reaction temperature and the types of dispersing medium and catalyst on the kinetic performance of polymerization are significant, and that the combined model of first and second order decay of active site of catalyst can be used to describe the phenomena. 相似文献
997.
分别采用醚型和酯型热塑性聚氨酯(TPU)对聚对苯二甲酸丁二醇酯(PBT)进行增韧改性,并对共混物的性能、形态结构及流变性能进行了研究。结果表明:醚型TPU对PBT有较好的增韧效果,共混物有明显的两相,PBT为连续相,TPU为分散相,当m(PBT)/m(TPU)=100/75时,拉伸屈服强度可达41.7MPa,缺口冲击强度326 J/m,是纯PBT的两倍,断裂伸长率330%;醚型TPU对PBT共混物的表观粘度有较大的影响,当m(PBT)/m(TPU)=100/50时.共混物表观粘度只有纯PBT的20%。 相似文献
998.
使用低温含铅透明釉为基础釉,选用适宜的包裹红色料,研制成功一种艺术瓷用高光泽大红釉,并探讨了不同因素对大红釉呈色的影响。 相似文献
999.
Borage oil sterols were isolated by TLC and characterized using GC and GC-MS. Several diunsaturated Δ5-sterols, some of them not previously recorded in vegetable oils, were found. Of these, 24-methylcholesta-5,23-dienol and
24-ethylcholesta-5,23-dienol could be useful markers for borage oil. Two other diunsaturated Δ5-sterols that are rarely found in vegetable oils, 24-methylcholesta-5,24(25)-dienol and 24-ethylcholesta-5,24(25)-dienol,
were identified. The diunsaturated C-24(28)-sterol, isofucosterol, was also found, as well as the monounsaturated Δ5-sterols campesterol and sitosterol. These are normally present in vegetable oils, which makes them unsuitable as markers
for borage oil. 相似文献
1000.