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51.
Masato Takeuchi Junichi Deguchi Manabu Hidaka Shiro Sakai Kyoungja Woo Pyuck-Pa Choi Jong-Ku Park Masakazu Anpo 《Applied catalysis. B, Environmental》2009,89(3-4):406-410
The photocatalytic oxidation of gaseous acetaldehyde with O2 on commercial TiO2 nano-particles could be successfully enhanced by a simple mechanical blending with a high-silica mordenite (MOR) zeolite, the surface of which showed high hydrophobic properties. When the TiO2 nano-particles of ca. 5–20 wt% were mixed with the MOR zeolite powders in an agate mortar for only 5 min, the blended TiO2/MOR samples showed higher photocatalytic reactivity as compared to the pure TiO2 nano-particles. Since the high-silica zeolite powders are highly transparent in UV light regions, the incident UV light is effectively irradiated onto the whole part of the TiO2 nano-particles without any loss of light intensity. Furthermore, the siliceous MOR zeolite powders effectively adsorb the gaseous acetaldehyde molecules and supply them onto the surfaces of the blended TiO2 nano-particles, resulting in an enhancement of the photocatalytic reactivity. 相似文献
52.
Guo-Dong Li Shiro Masuda Daisuke Yamaguchi Masatake Nagai 《IEEJ Transactions on Electrical and Electronic Engineering》2009,4(4):570-577
The PID control algorithm has been widely applied in many industry control system to solve efficiently the control problems of manufacturing processes. However, PID control algorithm belong to “delay control”, because it functions on basis of the actions occurred in the system. Thus the control accuracy in real-time is limited. In this paper, in order to realize the accurate control in real-time, the grey model based on grey system theory is first proposed to combine with PID control to establish the control system. We define the proposed control system as grey PID control system. Then the cubic spline function is integrated into the grey model. to enhance the control accuracy of system. To further improve the performance, the particle swarm optimization (PSO) algorithm is employed to optimize the parameters of PID algorithm. Finally, we validated the effectiveness of the proposed control system by computer simulation. © 2009 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
53.
Narisawa N Furukawa S Kawarai T Ohishi K Kanda S Kimijima K Negishi S Ogihara H Yamasaki M 《International journal of food microbiology》2008,124(1):103-107
We investigated the effects of skimmed milk and its protein fractions (casein, whey, globulin, and albumin) on the injury and inactivation of Escherichia coli K-12 by high hydrostatic pressure (HHP) treatment. The protective effect of skimmed milk on HHP-mediated inactivation and injury of E. coli increased with increases in the skimmed milk concentration. However, protein fractions derived from skimmed milk did not exhibit this protective effect. Microscopy analysis by DAPI/PI staining indicated that some cells were localized in the solid portion of skimmed milk, and some of these cells were alive. The coagulated fraction derived from the autoclaved whey fraction also showed a significant protective effect. We speculate that the solid portion in skimmed milk could provide the protective effect to bacterial cells. 相似文献
54.
55.
Latifa Seniorita Eiji Minami Yoshiteru Yazawa Hitoshi Hayashi Shiro Saka 《Journal of the American Oil Chemists' Society》2019,96(9):979-987
Monoacylglycerols (MAG) are impurities present in biodiesel as a result of incomplete reactions. MAG often solidify in biodiesel even at room temperature because of their high melting points. This worsens the cold-flow properties such as the cloud point and pour point. We hypothesized that several types of MAG solidify simultaneously; therefore, we performed differential scanning calorimetry of binary mixtures of MAG to elucidate their interactions during solidification. Three thermodynamic formulas were then applied to the experimental results: (1) non-solid-solution, (2) solid-solution, and (3) compound formation models. Binary mixtures of MAG showed complicated liquidus curves with multiple upward convex shapes, with which only the compound formation model fitted well. This model was applied to multicomponent mixtures that consisted of MAG and fatty acid methyl esters (FAME) as surrogate biodiesel fuels. We confirmed that the model still worked well. The results show that the compound formation model has good potential for predicting the cold-flow properties of biodiesel. 相似文献
56.
Oxidation of SiC compositionally graded (SCGed) graphite coated with HfO2 derived from HfCl4 by a sol–gel process was performed at 1500° and 1600°C in a flowing gas mixture of Ar and O2 (80/20 kPa). SCGed graphite was produced by reaction of graphite with either molten Si or SiO gas at 1450°C. The sol–gel-derived HfO2 precursor was deposited on SCGed graphite by a dip-coating method. Isothermal and cyclic oxidation of uncoated- and HfO2 -coated SCGed graphite was studied by monitoring overall weight change using an electro-microbalance. Scanning electron microscopy with energy-dispersive X-ray analysis was used to observe the surfaces and cross-sections of the oxidized HfO2 -coated SCGed graphite. The formation of HfSiO4 was confirmed on the outer layer of the oxidized sample, beneath which a thin silica layer was formed. The improved oxidation resistance of SCGed graphite by coating with HfO2 is discussed on the basis of the formation of these two layers. 相似文献
57.
Dirac Cone Spin Polarization of Graphene by Magnetic Insulator Proximity Effect Probed with Outermost Surface Spin Spectroscopy
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Seiji Sakai Sergei V. Erohin Zakhar I. Popov Satoshi Haku Takahiro Watanabe Yoichi Yamada Shiro Entani Songtian Li Pavel V. Avramov Hiroshi Naramoto Kazuya Ando Pavel B. Sorokin Yasushi Yamauchi 《Advanced functional materials》2018,28(20)
The effects of the proximity contact with magnetic insulator on the spin‐dependent electronic structure of graphene are explored for the heterostructure of single‐layer graphene (SLG) and yttrium iron garnet Y3Fe5O12 (YIG) by means of outermost surface spin spectroscopy using a spin‐polarized metastable He atom beam. In the SLG/YIG heterostructure, the Dirac cone electrons of graphene are found to be negatively spin polarized in parallel to the minority spins of YIG with a large polarization degree, without giving rise to significant changes in the π band structure. Theoretical calculations reveal the electrostatic interfacial interactions providing a strong physical adhesion and the indirect exchange interaction causing the spin polarization of SLG at the interface with YIG. The Hall device of the SLG/YIG heterostructure exhibits a nonlinear Hall resistance attributable to the anomalous Hall effect, implying the extrinsic spin–orbit interactions as another manifestation of the proximity effect. 相似文献
58.
Predicting Solid–Liquid Equilibrium of Fatty Acid Methyl Ester and Monoglyceride Mixtures as Biodiesel Model Fuels
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Shinichiro Yoshidomi Yuitsu Sugami Eiji Minami Noriko Shisa Hitoshi Hayashi Shiro Saka 《Journal of the American Oil Chemists' Society》2017,94(8):1087-1094
Fatty acid methyl esters from plant oils are the main component of biodiesel and used as a substitute for petroleum diesel. Biodiesel generally contains a small amount of monoglycerides as intermediate compounds, which have high melting points and often solidify and clog fuel filters. The prediction of the cold-flow property of biodiesel is of great importance for practical application. In this study, a thermodynamic study was conducted for mixtures of monoglycerides and fatty acid methyl esters. Temperatures of the solid–liquid equilibrium for the mixtures were measured by differential scanning calorimetry and visual observation, while the theoretical values were calculated using the modified Universal Quasi-chemical Functional-group Activity Coefficients (UNIFAC) model (Dortmund). The theoretical and experimental results were in good agreement, especially for binary mixtures of monoglycerides and methyl esters. The importance of monoglycerides on the cold-flow properties of biodiesel was determined, and the effects could be well described by the modified UNIFAC model (Dortmund). 相似文献
59.
Ohmae M Sakaguchi K Kaneto T Fujikawa S Kobayashi S 《Chembiochem : a European journal of chemical biology》2007,8(14):1710-1720
Keratan sulfate (KS) oligomers with well-defined structures were synthesized by keratanase II (KSase II)-catalyzed transglycosylation. N-Acetyllactosamine [Galbeta(1-->4)GlcNAc; LacNAc] oxazoline derivatives with sulfate groups at the C-6 (1 a) and both the C-6 and the C-6' (1 b) were prepared as transition-state analogue substrate monomers for KSase II. Monomer 1 a was effectively oligomerized by the enzyme under weak alkaline conditions, to give alternating 6-sulfated KS oligomers (2 a) in good yields, and with total control of regioselectivity and stereochemistry. KSase II also recognized 1 b, which provided fully 6-sulfated KS oligomers (2 b) in good yields under similar conditions. Nonsulfated LacNAc oxazoline was difficult to oligomerize enzymatically. These results imply that the catalysis mechanism of KSase II involves a sugar oxazolinium ion that requires the 6-sulfate group in the GlcNAc residue not only in hydrolysis of KS chains, but also in oligomerization of oxazoline monomers. This is the first report of KSase II-catalyzed transglycosylation to form beta(1-->3)-glycosidic bond through a substrate-assisted mechanism. 相似文献
60.
Summary
Poly(phenylene oxide) (PPO) — aromatic polyester multiblock copolymers were synthesized by polycondensation of bisphenol-A
/ isophthalic acid or m- and p-hydroxybenzoic acids in the presence of PPO having a carboxylic acid at one end and a phenolic hydroxy group at the other
using triphenylphosphine / hexachloroethane as coupling agent. TG analysis showed that the multiblock copolymer showed relatively
high thermal stability.
Received: 5 January 1998/Accepted: 4 February 1998 相似文献