High performance films of cellulose butyral derivative having a necklace-like annular structure in the side chains

We fabricated high performance films using cellulose butyral (CB) synthesized from native cellulose. Two-step reactions were adopted to produce the derivative CB, including etherification of cellulose with glycidol in NaOH/urea aqueous solution to yield O-(2,3-dihydroxypropyl) cellulose (DHPC), and butyralization of DHPC. Both DHPC and CB products were easily processed into a thin film by hot-press molding. The butyral modifier significantly improved the tenacity of highly ductile DHPC, by virtue of the possible chain-entangling action of the ring structures in the stretching process. Thereby the film toughness was markedly enhanced. The CB films exhibited excellent optical transparency and a good adhesive property to glass plates. Thus the films may be comparable to commercial poly(vinyl butyral) (PVB) films in optical and mechanical performances and therefore possess a potential applicability as interlayer for laminated glasses.     

Repeatable change in electrical resistance of Si surface by mechanical and electrical nanoprocessing

The properties of mechanically and electrically processed silicon surfaces were evaluated by atomic force microscopy (AFM). Silicon specimens were processed using an electrically conductive diamond tip with and without vibration. After the electrical processing, protuberances were generated and the electric current through the silicon surface decreased because of local anodic oxidation. Grooves were formed by mechanical processing without vibration, and the electric current increased. In contrast, mechanical processing with vibration caused the surface to protuberate and the electrical resistance increased similar to that observed for electrical processing. With sequential processing, the local oxide layer formed by electrical processing can be removed by mechanical processing using the same tip without vibration. Although the electrical resistance is decreased by the mechanical processing without vibration, additional electrical processing on the mechanically processed area further increases the electrical resistance of the surface.     

Characteristics of polypyrrole chemically synthesized by various oxidizing reagents

Polypyrrole was chemically synthesized using various oxidizing reagents and examined as a positive electrode material. Physical properties, morphologies and electrochemical characteristics of polypyrrole were greatly influenced by the oxidizing reagent used for polymerization. In general, polypyrrole with a smaller particle size and a larger specific surface area showed better discharge performance than that with a larger particle size and a smaller specific surface area. Polypyrrole was also synthesized on various conducting and nonconducting substrates using Fe(C10₄)₃ as an oxidizing reagent. By using PP nonwoven fabric as a substrate material, a high discharge capacity of 72 mA h g^–1 was obtained. Polypyrrole synthesized on only one side of PP nonwoven fabric was able to be used as an electrode.     

Possibilities of the Formation of Enol-Ethers in Lignin by Soda Pulping

In the alkaline decomposition of a β-O-4 type lignin model compound (erythro-guaiacylglycerol-β-guaiacyl ether, compound 1), an isomeric pair of C₆C₂ enol-ether (2-methoxy-4-[2-(2-methoxyphenoxy)-vinyl]-phenol, compound 2) was detected as the main decomposition product with no trace of C₆C₃ enol-ether (4-[3-hydroxy-1-(2-methoxyphenoxy)-propenyl]-2-methoxy-phenol, compound 3) or other dimers. In contrast, compound 2 was not detected in the alkaline decomposition products of compound 3. Under alkaline conditions, the γ-hydroxymethyl group of compound 3 was reduced to form 2-methoxy-4-[1-(2-methoxyphenoxy)-propenyl]-phenol (compound 4). In the HSQC analysis of soda lignin, the formation of substructures of C₆C₂ type enol-ether (related to compound 2) was confirmed. However, no substructures related to compound 4, which could be formed if a substructure of C₆C₃ type enol-ether was formed under alkaline conditions, were detected. Therefore, it could be concluded that C₆C₃ type enol-ethers could not be intermediates of alkaline decomposition products of lignin.     

A lossless handover method for video transmission in mobile ATMnetworks and its subjective quality assessment

Cell loss is one of the major causes of degradation in quality of service in ATM mobile communication systems. It can be suppressed by employing buffer memories in the network; however, cell delay occurs as a consequence. This article proposes a lossless handover method for mobile ATM communication networks that both prevents cell loss and can suppress cell delay variation. The method was simulated on an experimental system to subjectively evaluate MPEG2 images relative to buffer memory size and the results obtained are presented     

On the efficiency of cautious schedulers for database concurrency control—Why insist on two-phase locking?

Thecautious scheduler, recently proposed for the concurrency control of database systems, never resorts to abortions or rollbacks for the purpose of concurrency control. The comprehensive performance evaluation study among different cautious schedulers and conventional non-cautious schedulers, however, has not yet been attempted. In this paper, we consider five scheduling algorithms and investigate their performance by means of simulation studies. Two of these algorithms are non-cautious; that is, thetwo-phase locking algorithm (2PL) (the most popular transaction scheduling algorithm in practical systems) and theconflict serializable algorithm (CSR) (a typical scheduling algorithm among those not using a locking mechanism; also calledD-serializable algorithm, conflict preserving serializable algorithm, orWW-serializable algorithm). The others are cautious scheduling algorithms modified from the above2PL andCSR; that is,cautious two-phase locking algorithm (C2PL), exclusive preclaimed two-phase locking algorithm (EP2PL), andcautious conflict serializable algoritm (CCSR). The results demonstrate the superiority of the cautious conflict serializable algorithm over the conventional two-phase locking algorithm, especially in the on-line system environment.This work was supported in part by the Ministry of Education, Science and Culture of Japan under Scientific Research Grant-in-Aid and in part by the Advancd Systems Foundations of British Columbia, Canada.     

Stress disturbance due to broken fibres in metal matrix composites with non-uniform fibre spacing

Premature fracture of weaker fibres causes stress disturbances in composites. These disturbances are affected by non-uniformity of fibre spacing. In order to evaluate quantitatively how the disturbances in metal matrix composites are affected by the extent of non-uniformity of fibre spacing, a method of calculation is presented on the basis of two-dimensional shear lag analysis. Static tensile stress concentrations in the intact fibres to broken fibres, tensile stress distribution along the fibre axis in the broken and intact fibres and shear stresses between broken and intact fibres were calculated by the method presented, using some examples. It is shown quantitatively that the spacing between broken and intact fibres and that between intact and next fibres has a significant influence on tensile stress concentrations in intact fibres and also on the shear stresses between broken and intact fibres: the narrower the former spacing and the wider the latter spacing, the higher become both tensile and shear stress concentrations. This tendency is enhanced when the number of broken fibres is large and when the strain hardening of the matrix is high.     

High Field ESR System and Its Application to the Study of Quantum Spin Systems

Developments of the high field ESR system in Kobe University is presented. Using Gunn oscillators and backward traveling oscillators (BWO), we can cover the frequency region from 30 to 1183.6 GHz with the use of InSb detector. Pulsed magnetic field up to 30 T is available and we are now trying to extend the field up to 40 T. Temperature range is from 1.8 to 300 K. Using this system, we studied S=1/2 ladder like system Cu₂(C₅H₁₂N₂)₂Cl₄, and found a new magnetic transition at 10.1 T at 1.8 K. The temperature dependence of ESR in Cu₂(C₅H₁₂N₂)₂CI₄ shows g-shift below 8 K which corresponds to the maximum of the magnetic susceptibility. The g-shift below 8 K suggests the increase of the quantum fluctuation in the system, and the role of the quantum fluctuation in Cu₂(C₅H₁₂N₂)₂CI₄ is discussed.     

Condensation enhancement on a vertical plate (1st report,heat transfer characteristic on a dispersed finned surface)

In this study, a condensation heat transfer experiment on vertical continuous and dispersed finned surfaces using FC5312 was carried out. Experimental parameters were the pitch and height of the fin, and the dispersed fin length. In the results, the phenomena of condensate retention were observed in the bottom of each row of the dispersed fin. The condensate flow from the upper row was concentrated into the valley of the fin and then flowed down into the valley of the next fin. Moreover, it was found from the experiment that the heat transfer coefficient on the dispersed finned surface was lower than the one on the continuous finned surface as the fin pitch was smaller, but was larger than that of the continued finned surface for a larger fin pitch. Furthermore, the heat transfer enhancing effect became more significant for the higher fin with the larger fin pitch, and the heat transfer reducing effect became more significant for the lower fin with the smaller fin pitch. These special characteristics of condensation mentioned above were caused by the phenomena of condensate retention in each row of the fin and the flow pattern of the condensate between two adjacent fins on the dispersed finned surface based on experimental observations. © 2008 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20221