A hybrid method through faradaic rectification and a.c. impedance measurements for the corrosion rate determination of metal/oxide/electrolyte systems. I. Theory

The interference of the oxide film in corrosion rate measurements of oxide covered metals is confirmed, and is found to limit the accuracy of measurements in all d.c. and a.c. polarization methods including impedance techniques. A new method is proposed to measure the corrosion rate in metal/oxide/electrolyte systems. It involves the use of faradaic rectification measurements in the absence of concentration polarization. The contribution of the oxide film to the measured currents and potentials are appropriately compensated and this represents a unique feature of the proposed method. Alternating current impedance values of the oxide film measured at the same frequency as that of faradaic rectification are used for this purpose.     

Finite element analysis of the in-plane behaviour of annular disks

In-plane analysis of annular disks using the finite element method is presented. A semi-analytical, one-dimensional finite element model is developed using a Fourier series approach to account for the circumferential behaviour. Using displacement functions which are exact solutions of the two dimensional elasticity plane stress problem, the shape functions, stiffness matrices and mass matrices corresponding to the 0th, 1st and nth harmonics are derived. To show the utility of this new element, example probelms have been solved and compared with the exact solution. The present element can be readily coded into any general purpose finite element program.     

Removal of soy protein-bound phospholipids by a combination of sonication, β-cyclodextrin,and phospholipase A2 treatments

One of the contributing factors to generation of off-flavours in soy protein isolate (SPI) during storage is autoxidation of residual amounts of phospholipids present in SPI. Thus, removal of phospholipids from SPI is a likely first step to improve its flavour stability and enhanced utilisation of SPI in food products. We describe a β-cyclodextrin-based (βCD) process to remove protein-bound phospholipids and free fatty acids in SPI. Treating SPI solution (8%) with 10 mM βCD alone at pH 8.0 decreased the phospholipid content of SPI by about 36%. A greater than 99% removal of phospholipids and free fatty acids was achieved by using a combination of treatments involving sonication of the SPI solution for 5 min at 50 °C followed by treatment with phospholipase A₂ and βCD. SPI prepared by this method was white in colour. The results presented here offer a process for removing residual off-flavour causing phospholipids from soy protein.     

Effects of curtailment on an admissions model for a graduate management program.

Developed 2 admissions models to predict future academic performance of graduate management students. The 1st model was based on 40 students who were admitted and enrolled in the program and was uncorrected for curtailment. The 2nd model was developed from the total applicant population of 222 students after curtailment correction. The corrected model demonstrated higher predictive validity than the uncorrected model for 2 future classes of students. Furthermore, different predictors entered each model, affecting the beta weights, validities of predictors, and the total amount of variance explained by the models. A factor analysis and an analysis of admissions decisions offer additional support for the curtailment-corrected model in selecting students with high academic potential. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Optimized and low-complexity power allocation and beamforming with full duplex in massive MIMO and small-cell networks

The Journal of Supercomputing - By combining massive multiple-input and multiple-output (Ma-MIMO) and small-cell approaches, it is possible to improve the capacity of the network, with the features...     

Electrochemical behavior of blood coagulation proteins—factors V and VIII

The electrochemical reactions of two blood coagulation proteins, factors V and VIII (AC globulin and antihemophila factor) at platinum -NaCl interface were investigated using cyclic voltammetric techniques. Voltammograms were recorded for three concentrations of each of the proteins (0·1, 1·0 and 10 times the physiologic concentration) at different scan rates. The results of this preliminary study suggest that these compounds take part in more than one electron transfer reaction at the interface. Some of these may be coupled with chemical reactions. With both the proteins, particularly at lower concentrations, their adsorption has a significant influence on the peak current functions. Prediction as to the detailed type or nature of these reactions is not feasible at the present time due to the complexity of the molecules and to the lack of structural information of the proteins.     

Grafting of methyl methacrylate to nitrocellulose by ceric ions

Studies were carried out on grafting of various vinyl monomers to nitrocellulose by ceric ions. It was observed that graft copolymerization occurred only with methyl methacrylate (MMA) and methyl acrylate monomer. The variables such as initiator concentration, monomer concentration, time of grafting, and nitrocellulose content on grafting of MMA are discussed. By hydrolyzing away the nitrocellulose backbone, the grafted poly(methyl methacrylate) branches were isolated and the >c?o peak at 1740 cm^?1 in the infrared spectra of these isolated branches gave definite evidence of grafting. The molecular weight of isolated branches has been determined by viscometry. The probable mechanism of grafting may be at the α-carbon atom of primary alcohol or at a C₂-C₃ glycol group of the anhydro glucose unit or at the hemiacetal group of the end unit of nitrocellulose, as nitrocellulose is formed by the partial nitration of cotton cellulose.     

Novel genetic algorithm for short-term scheduling of sequence dependent changeovers in multiproduct polymer plants

Polymer plants generally operate to produce different grades of product from the same reactor. Such systems commonly require short-term scheduling to meet market demand. One important requirement in continuous-time scheduling of such systems is to satisfy a variety of constraints, including identifying feasible sequences of the predecessor and successor jobs to effectively handle changeovers. In this study, a new genetic algorithm (GA) is proposed to solve such job sequencing problems. The proposed GA uses real-coded chromosome to represent job orders and their sequences in the schedule. The novelty is that the representation ensures that all constraints are satisfied a priori, except the sequence constraint which is handled by penalizing violations. Three important problems relevant to polymer industry are solved to obtain optimal schedules. The first deals with the sequencing constraint between individual product orders, the second with sequencing constraint between groups of product orders, while the third incorporates batching with scheduling.     

Graph theory augmented math programming approach to identify minimal reaction sets in metabolic networks

Bioprocesses are of growing importance as an avenue to produce chemicals. Microorganisms containing only desired catalytic and replication capabilities in their metabolic pathways are expected to offer efficient processes for chemical production. Realizing such minimal cells is the holy grail of metabolic engineering. In this paper, we propose a new method that combines graph-theoretic approaches with mixed-integer liner programming (MILP) to design metabolic networks with minimal reactions. Existing MILP based computational approaches are computationally complex especially for large networks. The proposed graph-theoretic approach offers an efficient divide-and-conquer strategy using the MILP formulation on sub-networks rather than considering the whole network monolithically. In addition to the resulting improvement in computational complexity, the proposed method also aids in identifying the key reactions to be knocked-out in order to achieve the minimal cell. The efficacy of the proposed approach is demonstrated using three case studies from two organisms, Escherichia coli and Saccharomyces cerevisiae.