SPEEK/PVP质子交换膜的制备研究

采用氯磺酸(Cl-SO3H)作磺化剂,合成了磺化聚醚醚酮(SPEEK);并通过不同分子量、掺量的聚乙烯吡咯烷酮(PVP),测试了SPEEK膜的基本性能,并进行了SPEEK/PVP共混膜材的制备研究.采用傅立叶红外(FT-IR)、热重(TG)、扫描电镜(SEM)、交流阻抗(EIS)以及干湿称重法、芬顿法等,测试分析了PVP的分子量及掺量对SPEEK膜的热稳定性、形貌结构、尺寸稳定性、抗氧化性,以及质子传导性能的影响.结果表明:SPEEK/PVP(质量比为1∶1)共混膜具有较好的热稳定性,表面光滑,更加致密,溶胀度仅为13.34%,抗氧化稳定性可达2.06%,电导率达0.06S/cm,显著优于SPEEK膜.     

分子筛纯化系统的控制设计

分子筛纯化系统的工况稳定对空分设备的稳定运行至关重要。简单介绍了分子筛纯化系统的组成、工作原理,着重论述了分子筛纯化系统顺序控制,最后通过实例介绍了顺控系统的逻辑组态及操作画面的组态。     

基于近红外透射光谱的牛奶中脂肪和蛋白质含量检测

基于近红外光谱检测牛奶中蛋白质和脂肪含量是当前的一个研究热门,主要可以利用近红外反射光谱,近红外漫反射光谱和近红外透射光谱的光谱信息来分析牛奶的主成分含量。本文是利用近红外透射光谱原始数据,通过数学方法转换,从吸光值、吸光比和吸收度三种形式,采用偏最小二乘法(PLS)回归,分别建立了其与牛奶主成分浓度之间的校正模型。对比三种形式所建立的数学模型的优劣,探讨了如何提高PLS校正模型预测精度的相关问题。     

In Situ Electrochemical Synthesis and Deposition of Discotic Hexa‐peri‐hexabenzocoronene Molecules on Electrodes: Self‐Assembled Structure,Redox Properties,and Application for Supercapacitor

Discotic hexa‐peri‐hexabenzocoronene (HBC) molecules are synthesized by electrochemical cyclodehydrogenation reaction and in situ self‐assembled to π‐electronic, discrete nanofibular objects with an average diameter about 70 nm, which are deposited directly onto the electrode. The nanofibers consist of columnar arrays of the π‐stacked HBC molecules and the intercolumnar distance is determined to be 1.19 nm by X‐ray diffraction, which corresponds well to the distance of 1.1 nm observed by high‐resolution transmitting electron microscopy. The diameter of the molecular columns matches the size of the discotic HBC molecule indicating face‐to‐face π‐stacking of HBC units in the column. The HBC nanofibers on electrode are redox active, and the nanosized columnar structures provide a huge surface area, which is a great benefit for the charging/discharging process, delivering excellent capacitance of 155 F g^?1. The described electrochemical deposition method shows great advantage for self‐assembling the family of insoluble and structurally designable graphene‐like nano materials, which constitutes an important step toward molecular electronics.     

基于CCD工艺的模型参数提取测试图形设计

介绍了一套基于CCD工艺的模型参数提取用测试图形（Testchip）设计方法。该Testchip的设计充分考虑了CCD工艺特征、中测测试条件、CCD放大器特性等各种关键因素,并在对应的工艺线进行流片,得到了完整的测试数据。     

基于K两端聚类的污秽绝缘子放电状态评估

沿面放电是绝缘子污秽程度及运行状态的重要体现,实时掌握绝缘子的污秽放电状态对污闪的预防具有重大意义.根据污秽绝缘子在放电过程中泄漏电流的波形变化以及放电区段的划分特点,提出了一种基于K两端聚类的动态划分方法.分析污秽绝缘子在运行中受潮、形成干燥带及局部电弧、局部电弧发展至极端闪络的全过程,并依据绝缘子运行中工作电压和泄...     

重庆园博园园林工程监理要点

重庆园博园项目建设量大工期短,项目庞杂,场地拥挤,各项工程设计与施工安排十分紧张,针对这种超常规的建设要求,园林工程监理格外重要.重庆园博园园林工程监理采取在工程前期即从设计切入管理,深入整个过程,对方案、植物、条例、资质先行进行有效控制,在施工过程中对投资和质量进行平衡与保证,充分运用监理工程师的监督与协调,并完善验...     

用废聚苯乙烯泡沫塑料改性制备水性防水涂料

以废PS泡沫塑料为主的改性树脂涂料,具有耐水、硬度好、附着力强等优良的综合性能.通过对涂料的组成和性能进行试验分析,提高了PS回收的利用价值.     

Self-assembled PMo12 3-DODA+ composite superlattice thin films with photochromic properties

A layered superlattice PMo₁₂ ^3-DODA⁺ self-assembled composite film has been successfully prepared. Infrared (IR) spectra revealed that the Keggin structure characteristic of the PMo₁₂O₄₀ ^3- anion was preserved in the composite film. A well-ordered superlattice structure, d spacing of 2.945 nm, was identified by X-ray diffraction (XRD). The superlattice film showed good photochromic properties. On irradiation with UV light, the transparent film changed from light yellow to blue. Then, bleaching occurred when the film was in contact with ambient air or O₂ in the dark. The photochromic mechanism was studied by electron spin resonance (ESR), IR spectra, and UV-Vis spectra.