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Metal nitrides and carbides powders were synthesized by the spark discharge method in liquid ammonia at 100 °C and 11 kV of the spark discharge voltage and in n-heptane at 25 °C and 7.5 kV using the pellets of aluminum, titanium, iron and chromium as the starting material. The main products were AlN, TiN0.51, -Fe, -Cr2N in liquid ammonia, and Al4C3, TiC, -Fe, Fe2C and Cr7C3 in n-heptane. The agglomerated particle size decreased with increasing melting point of the metal used as the starting material.  相似文献   
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Proton exchanged ultrastable Y-type zeolite with silica/alumina = 40 showed a pronounced catalytic activity for the formation of ethyl methyl ketone directly from 1-butene and water. The formation rate of ethyl methyl ketone was much higher than those on MoO3-based catalysts in the oxidation of 1-butene by oxygen. It was suggested that the basic site necessary for the formation of ethyl ketone directly from 1-butene and water would be the pentacoordinated Al.  相似文献   
14.
The thermal decomposition of uranium peroxide hydrates, UO4·4H2O and UO4·2H2O, has been investigated by thermal analyses, X-ray diffraction study and infrared spectroscopy. As a result, it is concluded that the thermal decomposition of uranium peroxide hydrates proceeds in the following sequence: where 3 ≤ x ≤ 3.5.  相似文献   
15.
Glyoxal, which was the strong mutagen formed by ozonation of humic substances, was treated with granular activated carbon (GAC) and the behavior of glyoxal was investigated. Glyoxal itself was adsorbed well on GAC at pH 5–7. But, glyoxal increased by GAC treatment of ozonated humic substances when the ozone dose was insufficient to decolorize the humic substances. The precursors of glyoxal may be among other ozonated products which may be changed to glyoxal on GAC.  相似文献   
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AIM: To introduce the "starlight" test which was devised to check binocular vision in normal conditions of seeing in a rapid, easy, and cost effective manner and to estimate the possibility of its clinical use in screening the binocular visual field of patients. METHOD: The Bagolini striated glass test consists of optically plano lenses with imperceptible parallel scratches that barely blur the environment but produce two perpendicular luminous stripes (right eye stripe of 45 degrees and left eye stripe of 135 degrees) when subjects with normal binocular vision view one light source. Unlike the original Bagolini test, the starlight test uses three light sources in horizontal or vertical lines according to the testing purposes and the subject is asked to fixate upon the centre light. Through Bagolini glasses, the subject observes the resulting grid-like pattern and the state of binocular visual field of the subject can be roughly estimated. RESULTS: Normal subjects and patients with strabismus, visual field loss from intracranial diseases, glaucoma, retinitis pigmentosa, and functional visual loss were examined using the starlight test and findings from each case were discussed. CONCLUSIONS: The starlight test, which was made by hand at a low cost, is a simple test that can be used clinically. It provides information about the state of binocular vision of patients in normal conditions of seeing. It is also useful because it enables the examiner to share similar experiences with the examinee. The results suggest it can be effective in visual field screening.  相似文献   
18.
In an earlier study, an in vitro evolution procedure was applied to a large population of variants of the Tetrahymena group I ribozyme to obtain individuals with a 10(5)-fold improved ability to cleave a target single-stranded DNA substrate under simulated physiological conditions. The evolved ribozymes also showed a twofold improvement, compared to the wild-type, in their ability to cleave a single-stranded RNA substrate. Here, we report continuation of the in vitro evolution process using a new selection strategy to achieve both enhanced DNA and diminished RNA-cleavage activity. Our strategy combines a positive selection for DNA cleavage with a negative selection against RNA binding. After 36 "generations" of in vitro evolution, the evolved population showed an approximately 100-fold increase in the ratio of DNA to RNA-cleavage activity. Site-directed mutagenesis experiments confirmed the selective advantage of two covarying mutations within the catalytic core of the ribozyme that are largely responsible for this modified behavior. The population of ribozymes has now undergone a total of 63 successive generations of evolution, resulting in an average of 28 mutations relative to the wild-type that are responsible for the altered phenotype.  相似文献   
19.
The goal of this paper is to present an appropriate method for the segmentation of lines at intersections (X-junctions) and branches (T-junctions), which can be regarded as local regions where lines occur at multiple orientations. A novel representation called “orientation space” is proposed, which is derived by adding the orientation axis to the abscissa and the ordinate of the image. The orientation space representation is constructed by treating the orientation parameter, to which Gabor filters can be tuned, as a continuous variable. The problem of segmenting lines at multiple orientations is dealt with by thresholding 3D images in the orientation space and then detecting the connected components therein. In this way, X-junctions and T-junctions can be separated effectively. Curve grouping can also be accomplished. The segmentation of mathematically modeled X-, T-, and L-junctions is demonstrated and analyzed. The sensitivity limits of the method are also discussed. Experimental results using both synthesized and real images show the method to be effective for junction segmentation and curve grouping  相似文献   
20.
Image-based and model-based methods are two representative rendering methods for generating virtual images of objects from their real images. However, both methods still have several drawbacks when we attempt to apply them to mixed reality where we integrate virtual images with real background images. To overcome these difficulties, we propose a new method, which we refer to as the Eigen-Texture method. The proposed method samples appearances of a real object under various illumination and viewing conditions, and compresses them in the 2D coordinate system defined on the 3D model surface generated from a sequence of range images. The Eigen-Texture method is an example of a view-dependent texturing approach which combines the advantages of image-based and model-based approaches. No reflectance analysis of the object surface is needed, while an accurate 3D geometric model facilitates integration with other scenes. The paper describes the method and reports on its implementation  相似文献   
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