Techno-economic performance analysis of bio-oil based Fischer-Tropsch and CHP synthesis platform

The techno-economic potential of the UK poplar wood and imported oil palm empty fruit bunch derived bio-oil integrated gasification and Fischer-Tropsch (BOIG-FT) systems for the generation of transportation fuels and combined heat and power (CHP) was investigated. The bio-oil was represented in terms of main chemical constituents, i.e. acetic acid, acetol and guaiacol. The compositional model of bio-oil was validated based on its performance through a gasification process. Given the availability of large scale gasification and FT technologies and logistic constraints in transporting biomass in large quantities, distributed bio-oil generations using biomass pyrolysis and centralised bio-oil processing in BOIG-FT system are technically more feasible. Heat integration heuristics and composite curve analysis were employed for once-through and full conversion configurations, and for a range of economies of scale, 1 MW, 675 MW and 1350 MW LHV of bio-oil. The economic competitiveness increases with increasing scale. A cost of production of FT liquids of 78.7 Euro/MWh was obtained based on 80.12 Euro/MWh of electricity, 75 Euro/t of bio-oil and 116.3 million Euro/y of annualised capital cost.     

The role of functionalized carbon nanotubes in a PA6/LCP blend

Multi-walled carbon nanotubes (MWCNTs) were carboxyl-functionalized in order to improve their dispersion in a polymer matrix. The carboxyl-functionalized MWCNTs (i.e., MWCNT-COOH) were added into a blend matrix consisting of polyamide 6 (PA6) and liquid crystalline polymer (LCP) (PA6:LCP = 80:20 in weight) to make ternary composites. The effects of MWCNT-COOH on the rheological, physical, morphological, thermal, mechanical, and electrical properties of the ternary composites have been examined systematically. The dispersion of MWCNTs in the polymer matrix and their interactions with the polymers (i.e., PA6 and LCP) were found to be the most important factors affecting all properties. The functionalization of MWCNTs resulted in the significant improvement in their dispersion in the polymer matrix and largely enhanced the interactions of MWCNTs with the polymer matrix. The functionalized MWCNTs acted not only as reinforcement fillers but also as a compatibilizer that could enhance the interfacial adhesion between PA6 and LCP. Interestingly, the packing density of the polymer matrix was greatly increased by adding MWCNT-COOH.     

Sizing of Wastewater Particles Using the Electrozone Sensing Technique

Electrozone sensing is a rapid and effective method that has been widely used for particle size analysis. This method is based on the Coulter principle, which provides a measure of the solid volume of particles. However, for wastewater particles, due to the high porosity of these particles, the measured Coulter size is significantly less than the physical dimension of these particles. To quantify this effect, the size distribution curves of the sieved wastewater particles were measured using the Coulter particle sizing method, microscopy technique, and sieving methods. A theoretical model was developed by accounting for the porosity of wastewater particles to correlate the physical size of these particles to Coulter size measurement. However, this theoretical model underestimated the size of wastewater particles smaller than 100 μm. Instead, the wastewater particles size (D) for both primary and activated sludge samples was found to be linearly related to the Coulter particle size measurement (d) according to: D = 2.14d with r² = 0.98.     

Design optimization of cold-formed steel portal frames taking into account the effect of building topology

Cold-formed steel portal frames are a popular form of construction for low-rise commercial, light industrial and agricultural buildings with spans of up to 20 m. In this article, a real-coded genetic algorithm is described that is used to minimize the cost of the main frame of such buildings. The key decision variables considered in this proposed algorithm consist of both the spacing and pitch of the frame as continuous variables, as well as the discrete section sizes. A routine taking the structural analysis and frame design for cold-formed steel sections is embedded into a genetic algorithm. The results show that the real-coded genetic algorithm handles effectively the mixture of design variables, with high robustness and consistency in achieving the optimum solution. All wind load combinations according to Australian code are considered in this research. Results for frames with knee braces are also included, for which the optimization achieved even larger savings in cost.     

Cu wire bond parameter optimization on various bond pad metallization and barrier layer material schemes

The use of copper wire for semiconductor package assembly has been gradually gaining acceptance throughout the industry over the last decade. Although copper has several advantages over gold for wire bonding applications, the manufacturing difficulties using copper wire have made high volume, fine pitch copper bonding slow to materialize. In recent years with the spike in gold prices, copper wire has become even more attractive, and this has driven many studies on the topic.Due to the propensity for copper to work harden upon deformation, which occurs during the ball bonding process as the capillary tip smashes the ball into the bond pad, a high amount of stress is transferred into the bond pad structure. This can result in catastrophic defects such as dielectric cracking or pad cratering. The current study aims to quantify the level of underlying bond pad damage with respect to various bond pad metallization and barrier layer schemes. A first bond parameter optimization was completed on each experimental group. The results indicate that barrier layer structure and composition have a significant impact on the presence of pad cratering. The experimental group containing only TiN as the barrier material showed a high occurrence of cratering, while groups with Ti and TiW barrier metals showed no cratering, even if a TiN layer was on top of the Ti. The bond pad metal thickness, on the other hand, does not appear to play a significant role in the prevention of bond pad cratering. Metal thickness values ranging from 0.825 to 2.025 μm were evaluated, and none had bond pad cratering other than the group with TiN as the barrier metal. In addition to the first bond parameter evaluations with various bond pad and barrier metal combinations, the initial free air ball (FAB) optimization is discussed.     

Parametric studies of diamond-like carbon by pulsed Nd:YAG laser deposition

This paper presents the results, analysis and discussions of parametric studies of diamond-like carbon (DLC) thin films by pulsed Nd:YAG laser deposition. Effects on the DLC properties and growth rate were investigated by varying the deposition parameters, namely the laser wavelength and fluence, substrate and temperature. For characterization, visible Raman spectroscopy, current-voltage measurement, optical interferometry, and optical absorption technique were employed. Comparisons were made with previous work by other workers who had also employed pulsed Nd:YAG lasers. The results also supported the subplantation mechanism for DLC formation.     

Production of CO-rich hydrogen gas from glycerol dry reforming over La-promoted Ni/Al2O3 catalyst

Dry reforming of glycerol has been carried out over alumina-supported Ni catalyst promoted with lanthanum. The catalysts were characterized using EDX, liquid N₂ adsorption, XRD technique as well as temperature-programmed reduction. Significantly, catalytic glycerol dry reforming under atmospheric pressure and at reaction temperature of 1023 K employing 3 wt%La–Ni/Al₂O₃ catalyst yielded H₂, CO and CH₄ as main gaseous products with H₂:CO < 2.0. Post-reaction, XRD analysis of used catalysts showed carbon deposition during glycerol dry reforming. Consequently, BET surface area measurement for used catalysts yielded 10–21% area reduction. Temperature-programmed gasification studies with O₂ as a gasification agent has revealed that La promotion managed to reduce carbon laydown (up to 20% improvement). In comparison, the unpromoted Ni/Al₂O₃ catalyst exhibited the highest carbon deposition (circa 33.0 wt%).