ELECTROKINETIC EFFECTS: CARBONIC ANHYDRASE AND CO2 ELECTRODE DYNAMICS

It is well known that the dynamic response rate of the Severinghaus-type CO₂ electrode is improved significantly in some cases by addition of the enzyme carbonic anhydrase to the electrode assembly. Hysteresis in the response rate also is reduced. Experimental data and modelling results indicate that catalysis of the CO₂ hydration reaction in the bulk of the bicarbonate layer (the Nernst film) is not responsible for the improved response behavior, Evidence is presented to show that catalysis in the electrostatic double layer region at the glass electrode surface is a possible explanation. This proposed phenomenon may have widespread implications for the optimal design of analytical devices, commercial processes involving electrochemical phenomena, and may also provide insight into electrobiologi-cal processes.     

CH4/CO2 reforming over La2NiO4 and 10%NiO/CeO2–La2O3 catalysts under the condition of supersonic jet expansion via cavity ring-down spectroscopic analysis

CH₄/CO₂ reforming over La₂NiO₄ and 10%NiO/CeO₂–La₂O₃ catalysts under the condition of supersonic jet expansion was studied via direct monitoring of the reactants and products using the sensitive technique of cavity ring-down spectroscopy. Vibration–rotational absorption lines of CH₄, H₂O, CO₂ and CO molecules were recorded in the near infrared spectral region. Our results indicated that La₂NiO₄ is superior to 10%NiO/CeO₂–La₂O₃ in performance. In addition, we observed enhanced reverse-water-gas-shift reaction at augmented reaction temperature. The formation of reaction intermediates was also investigated by means of time-of-flight mass spectrometry and there was the detection of CH_x⁺, OH⁺ and H⁺ species.     

High-Temperature Deformation and Microstructural Analysis for Silicon Nitride–Scandium (III) Oxide

Limited past studies have indicated that Si₃N₄ doped with Sc₂O₃ may exhibit high-temperature mechanical properties superior to Si₃N₄ systems with various other oxide sintering additives. High-temperature deformation of this system was studied by characterizing the microstructures before and after deformation. It was found that elements of the additive, Sc and O, exist in small amounts at thin grain boundary layers and within secondary phases at triple and multiple grain boundary junctions. The secondary phase is devitrified as crystalline Sc₂Si₂O₇. Deformation of the samples was dominated by cavitation rather than dislocation processes. Thus, the excellent deformation resistance of the samples at high temperature can be attributed to the high refractories and enhanced crystallization of a secondary phase.     

Frequency-domain computation of inflow broadband noise due to interaction of a rectilinear cascade of flat plates with incident turbulence

This paper deals with the broadband noise due to the interaction between convected turbulent gusts and a rectilinear cascade of flat plates bounded by two parallel walls. An analytic formulation for the acoustic power spectrum due to this turbulence-cascade interaction is derived, which can be used to assess the effects of the span-wise wavenumber components of ingesting turbulent gust on the overall acoustic power spectrum. This three-dimensional theory is based on the two-dimensional theory of Cheong et al. (2006, 2009). The three-dimensional model is shown to provide a close fit to the measured spectrum of rotor-stator interaction. The predictions using this three-dimensional model are also compared with those using the previous two-dimensional model by Cheong et al. (2006; 2009). Through this comparison, it is found that the contributions to the acoustic power of the span-wise wavenumber components of incident turbulent gust are increased as the frequency is augmented, which is mainly due to three-dimensional dispersion-relation characteristics of acoustic waves. This implies that the number of incident turbulent gust modes directly involved in generating cut-on acoustic waves increases as the frequency increases. Therefore, in the lower frequency range, three-dimensional acoustic power is less than its corresponding two-dimensional one, whereas, as the frequency increases, the three-dimensional acoustic power spectrum closely follows those of two-dimension. The formulation is also used to make a parametric study about the effects on the power spectrum of the blade number, stagger angle, gap-chord ratio, and Mach number.     

Anisotropic threshold stress intensity factor, KIH and crack growth rate in delayed hydride cracking of Zr-2.5Nb pressure tubes

The objectives of this study are to systematically investigate the delayed hydride cracking (DHC) velocity and the threshold-stress intensity factor, K _IH , of a Zr-2.5Nb pressure tube as a function of orientation and elucidate the cause of this anistropic DHC behavior. The DHC velocity as a function of orientation was determined using flattened cantilever beam specimens with 60 ppm H while the threshold-stress intensity factor K _IH , was evaluated as a function of orientation on the curved compact-tension (CT) and cantilever-beam (CB) specimens charged with hydrogen to 200 ppm H. To infer a difference in a stress gradient ahead of the crack tip as a function of orientation, tensile tests were conducted at temperatures ranging from room temperature (RT) to 560 °C using small tensile specimens of 2-mm-gage length taken from three directions of the tube. A textural change was investigated by comparing the inverse pole figures before and after DHC while the {10 7} pole figures were constructed to find out the growth pattern of the DHC crack as a function of orientation. Faster DHC velocity and lower K _IH were obtained over temperatures of 170 °C to 270 °C, when the DHC crack grew in the longitudinal direction of the Zr-2.5Nb pressure tube. The strain hardening after yielding and the extent of the textural change accompanied by DHC were higher in the longitudinal direction of the tube, suggesting a higher stress gradient ahead of the crack tip. Thus, the anisotropic DHC behavior of a Zr-2.5Nb pressure tube is discussed based on the stress gradient ahead of the crack tip governed by strain-hardening rate after yielding and a change in texture accompanied by DHC, and the distribution of the {10 7} hydride habit planes. This article is based on a presentation made in the symposium entitled “Defect Properties and Mechanical Behavior of HCP Metals and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee.     

Simulation of the effects of space charge and Schottky barriers on ferroelectric thin film capacitor using Landau Khalatnikov theory

The role of space charge induced in a ferroelectric thin film and the presence of Schottky barriers at the two electrode/film interfaces are studied by numerical simulation using Landau-Khalatnikov theory. In this work, the whole film is considered as the stacking of dipolar layers, each of which contains multilayers of perovskite cells. In the presence of a local electric field, the double-well thermodynamic potential of each layer is modified in an asymmetric manner. The local electric field distribution is determined both by the space charge and the boundary conditions imposed by the Schottky barrier heights. Asymmetric and skewed hysteresis loops are generated     

Red-green-blue laser emissions from dye-doped poly(vinyl alcohol) films

A microscope slide acting as a passive waveguide was coated by three separate poly(vinyl alcohol) films that were doped with Coumarin 460, Disodium Fluorescein, and Rhodamine 640 perchlorate. On collinear pumping by a nitrogen laser, these dyes furnished primary red-green-blue laser emissions that were collected and waveguided by the microscope slide but exited from both ends. Frosting the waveguide exit introduced light scattering at the glass-air interface and spatially overlaid the red-green-blue laser emissions that emerged as a uniform white-light beam.     

Fingerprint classification using fast Fourier transform and nonlinear discriminant analysis

In this paper, we present a new approach for fingerprint classification based on discrete Fourier transform (DFT) and nonlinear discriminant analysis. Utilizing the DFT and directional filters, a reliable and efficient directional image is constructed from each fingerprint image, and then nonlinear discriminant analysis is applied to the constructed directional images, reducing the dimension dramatically and extracting the discriminant features. The proposed method explores the capability of DFT and directional filtering in dealing with low-quality images and the effectiveness of nonlinear feature extraction method in fingerprint classification. Experimental results demonstrates competitive performance compared with other published results.     

Text classification without negative examples revisit

Traditionally, building a classifier requires two sets of examples: positive examples and negative examples. This paper studies the problem of building a text classifier using positive examples (P) and unlabeled examples (U). The unlabeled examples are mixed with both positive and negative examples. Since no negative example is given explicitly, the task of building a reliable text classifier becomes far more challenging. Simply treating all of the unlabeled examples as negative examples and building a classifier thereafter is undoubtedly a poor approach to tackling this problem. Generally speaking, most of the studies solved this problem by a two-step heuristic: first, extract negative examples (N) from U. Second, build a classifier based on P and N. Surprisingly, most studies did not try to extract positive examples from U. Intuitively, enlarging P by P' (positive examples extracted from U) and building a classifier thereafter should enhance the effectiveness of the classifier. Throughout our study, we find that extracting P' is very difficult. A document in U that possesses the features exhibited in P does not necessarily mean that it is a positive example, and vice versa. The very large size of and very high diversity in U also contribute to the difficulties of extracting P'. In this paper, we propose a labeling heuristic called PNLH to tackle this problem. PNLH aims at extracting high quality positive examples and negative examples from U and can be used on top of any existing classifiers. Extensive experiments based on several benchmarks are conducted. The results indicated that PNLH is highly feasible, especially in the situation where |P| is extremely small.     

Efficient Internet Multicast Routing Using Anycast Path Selection

A novel efficient and dynamic multicast routing protocol based on anycast routing techniques is presented. The contributions of the protocol differ from well-known shared-tree systems in two aspects: (1) Off-tree anycast routing: The nodes in the shared tree are formed into a virtual anycast group and multicast sources use anycast routing to select a better path from the source to one router in the group to achieve short delay and fault-tolerance. (2) On-tree dynamic routing: The shared-tree approach is extended with capability of alternative path selections. If a node becomes absent from the shared tree, some predefined backup path(s) is (are) used to bypass the node and enable dynamic multicast routing to continue. The protocol requires only the routers near the faulty node to be reconfigured, thus reducing the runtime overhead as compared with global reconfiguration. The simulation data demonstrates the efficiency of our routing protocol.