Preparative scale synthesis ofO-glycosides and of a disaccharide by electrochemical oxidation of phenylS-glycosides

Summary O-glycosides were synthesized by electrochemical oxidation of phenylS-glycosides in the presence of primary alcohols in acetonitrile. Similarly, a -linked disaccharide was obtained selectively by oxidation of phenylS-glycoside in the presence of a sugar alcohol. Electrosyntheses were performed under controlled potential or at constant current, in an undivided cell, on a large scale. 1 to 60 g of phenylS-glycosides in 0.5 to 1 dm³ of acetonitrile were converted with chemical yields in the range of 65–75%.     

Efficiency Enhancement in Organic Photovoltaic Cells: Consequences of Optimizing Series Resistance

Here, means to enhance power conversion efficiency (PCE or η) in bulk‐heterojunction (BHJ) organic photovoltaic (OPV) cells by optimizing the series resistance (R_s)—also known as the cell internal resistance—are studied. It is shown that current state‐of‐the‐art BHJ OPVs are approaching the limit for which efficiency can be improved via R_s reduction alone. This evaluation addresses OPVs based on a poly(3‐hexylthiophene):6,6‐phenyl C₆₁‐butyric acid methyl ester (P3HT:PCBM) active layer, as well as future high‐efficiency OPVs (η > 10%). A diode‐based modeling approach is used to assess changes in R_s. Given that typical published P3HT:PCBM test cells have relatively small areas (～0.1 cm²), the analysis is extended to consider efficiency losses for larger area cells and shows that the transparent anode conductivity is then the dominant materials parameter affecting R_s efficiency losses. A model is developed that uses cell sizes and anode conductivities to predict current–voltage response as a function of resistive losses. The results show that the losses due to R_s remain minimal until relatively large cell areas (>0.1 cm²) are employed. Finally, R_s effects on a projected high‐efficiency OPV scenario are assessed, based on the goal of cell efficiencies >10%. Here, R_s optimization effects remain modest; however, there are now more pronounced losses due to cell size, and it is shown how these losses can be mitigated by using higher conductivity anodes.     

Dual-Antenna RF CMOS Front-End for Interferer Removal in Ultra-Wideband Systems

Many ultra-wideband (UWB) systems are challenged by strong jammers and narrowband interferers. Using two antennas, we demonstrate a robust UWB radio frequency (RF) front-end design in a 0.25 μm mixed-signal complementary metal oxide semiconductor (CMOS) technology. The proposed realization is capable of adaptively removing a high-power, narrowband interferer early in the receiver chain avoiding front-end saturation and preserving UWB signal power. The early interferer removal resulting in interferer-free demodulation is based on the least mean squares (LMS) algorithm and achieved through a novel combiner low-noise amplifier and noise optimized filtering. Circuit level RF simulations of the proposed circuitry indicate a maximum improvement in signal-to-interference ratio of 39.6 dB.     

FeO0.7F1.3/C Nanocomposite as a High‐Capacity Cathode Material for Sodium‐Ion Batteries

Searching high capacity cathode materials is one of the most important fields of the research and development of sodium‐ion batteries (SIBs). Here, we report a FeO_0.7F_1.3/C nanocomposite synthesized via a solution process as a new cathode material for SIBs. This material exhibits a high initial discharge capacity of 496 mAh g^?1 in a sodium cell at 50 °C. From the 3^rd to 50^th cycle, the capacity fading is only 0.14% per cycle (from 388 mAh g^?1 at 3^rd the cycle to 360 mAh g^?1 at the 50^th cycle), demonstrating superior cyclability. A high energy density of 650 Wh kg^?1 is obtained at the material level. The reaction mechanism studies of FeO_0.7F_1.3/C with sodium show a hybridized mechanism of both intercalation and conversion reaction.     

Synthetic C-oligosaccharides mimic their natural, analogous immunodeterminants in binding to three monoclonal immunoglobulins

The binding of three monoclonal antigalactan immunoglobulins, IgAs X24, J539 and X44 to their natural haptens methyl beta-D-galactopyranosyl-(1-->6)-beta-D-galactopyranoside, and the corresponding tri- and tetrasaccharides, was compared to the binding of these immunoglobulins with the comparable C-linked oligosaccharide analogues 1-3. The near identity of affinities of the two sets of oligosaccharides indicated the absence of any hydrogen bond involvement by the intersaccharidic oxygen atoms in the natural immunodeterminants.     

Evaluate and control service and transaction dependability of complex IoT systems

Observing and controlling the dependability of service provision of complex IoT systems is challenging. In practice, many organizations struggle to derive consumer needs related to quality and to observe and quantify the service provision in the context of the dynamic behavior of a complex distributed system. In this paper, we present an approach to define and evaluate the dependability of complex IoT systems. Our approach is an adaptation of the ISO/IEC 25040, an international standard for the evaluation process for system and software quality, which is part of the systems and software quality requirements and evaluation (SQuaRE) series. Our approach was designed and evaluated with action research in an industrial study at Robert Bosch GmbH. Based on the framework of the SQuaRE series, we integrated different elements of site reliability engineering (SRE) and combined them with distributed tracing as a promising measurement method. Our approach introduces the IoT transaction concept to reduce modeling and observation efforts while increasing operationalization to measure performance against dependability targets. Our adaption was effectively applied, consumer-centricity along different system stakeholders were enhanced, and negative consequences of organizational silos were reduced. This has improved the dependability evaluation of service provision to enable fast feedback cycles for service performance control and improvement.

     

Distributed primal–dual interior-point methods for solving tree-structured coupled convex problems using message-passing

In this paper, we propose a distributed algorithm for solving coupled problems with chordal sparsity or an inherent tree structure which relies on primal–dual interior-point methods. We achieve this by distributing the computations at each iteration, using message-passing. In comparison to existing distributed algorithms for solving such problems, this algorithm requires far fewer iterations to converge to a solution with high accuracy. Furthermore, it is possible to compute an upper-bound for the number of required iterations which, unlike existing methods, only depends on the coupling structure in the problem. We illustrate the performance of our proposed method using a set of numerical examples.     

A Scenario-Based Management of Water Resources and Supply Systems Using a Combined System Dynamics and Compromise Programming Approach

Water Resources Management - Long-term sustainability in water supply systems is a major challenge due to water resources depletion, climate change and population growth. This paper presents a...     

Forbidden region virtual fixtures from streaming point clouds

Forbidden region virtual fixtures protect objects from unwanted contact with a robot. In this paper, we propose a method for creating forbidden region haptic virtual fixtures for teleoperation from streaming point clouds obtained by an RGB-D camera. Upon violating the protected area, the operator receives force feedback that opposes motion inside the forbidden region. Three architectures for creating virtual fixtures are presented and their advantages and disadvantages are described. The proposed methods have the ability to implement constraints and can handle dynamic environments in real-time. The effectiveness of the methods is demonstrated in experiments with a surgical robot.     

Experimental and numerical analysis of aerodynamic effects of repair patches on damaged airfoils

This investigation assesses the change of aerodynamic characteristics of triangular and star-shaped damaged airfoils with repair patches. Both experimental and numerical methods to determine aerodynamic coefficients are used in this study. The test model is a NACA 64₁-412 airfoil full span, which is considered by using five schematics: Clean model, damaged model, upper repaired model, lower repaired model, and fully repaired model. Repair patches are chosen based on the Aircraft battle damage repair (ABDR) manuals. Various effects of repair schemes on triangular and star-shaped damages are quantitatively and qualitatively illustrated. A novel visualization method by paint and oil is used in wind tunnel tests to study the effects of repair patches on the damaged airfoil.