Cost analysis of a two unit priority standby system with imperfect switch and arbitrary distributions

This paper deals with cost analysis of a single server two-unit (one priority and the other ordinary) cold standby system with two modes—normal and total failure. A switch is used to operate the standby unit (ordinary) and it works successfully with known probability p( = 1 ? q). Priority unit gets preference both for operation and repair. Failure and repair time distributions are arbitrary. System fails when switch or both the units fail totally. The system is observed at suitable regenerative epochs in order to obtain reliability characteristics of interest to system designers and operations managers. Explicit results for the exponential time distributions have been obtained in particular cases.     

Determination of fibre-matrix interfacial properties in ceramic-matrix composites by a fibre push-out technique

A simple concentric cylinder model is developed for the fibre push-out test in order to interpret the experimentally observed indenter load-displacement curves in ceramic-matrix composites. The fibre-matrix interface is assumed to be partially bonded and partially frictionally coupled. It is shown that a slope change in the loading curve corresponds to bonding at the fibre-matrix interface. In contrast an insignificant change in the slope is predicted for composites in which the fibre-matrix interface is frictionally coupled. This model also provides a framework for determining the interfacial debond energy and the interfacial shear strength in ceramic composites using the fibre push-out tests. The predictions of this model are compared with the push-out test results performed on zircon-SiC composites uniaxially reinforced with either uncoated or BN-coated SiC monofilaments, which suggested that the fibre-matrix interfaces in both of these composites are frictionally coupled.     

Evaluation of Mangosteen juice blend on biomarkers of inflammation in obese subjects: a pilot, dose finding study

Background  

The ability to reduce inflammation in overweight and obese individuals may be valuable in preventing the progression to metabolic syndrome with associated risks for heart disease and diabetes. The purpose of this study was to evaluate the effect of multiple dosages of a proprietary Mangosteen Juice blend on indicators of inflammation and antioxidant levels in obese patients with elevated C-reactive protein (CRP) levels.     

Mobility and distribution of cadmium, nickel and zinc in contaminated soil profiles from Bangladesh

We investigated the mobility and distribution of cadmium (Cd), nickel (Ni) and zinc (Zn) in four contaminated soil profiles from Bangladesh. The sources of contamination of these profiles were tannery wastes, city sewage and the wastes of pharmaceutical and paper mill factories at different locations in Bangladesh. The samples were collected from the A-, B- and C-horizons of each profile: two sub-samples from the A-horizon at depths of 0–5 cm (A1) and >5 cm (A2), and one sample each from the B- and C-horizons. Soil samples were analysed for total metal content by dissolution in aqua regia followed by sequential extraction of the fractions based on their varying solubility. There were six operationally defined groups of extraction sequences: water soluble (F1), exchangeable (F2), carbonate (F3), oxide (F4), organic (F5) and residual (F6). The total concentration of Cd, Ni and Zn in the A-horizon (0–5 cm) ranged from 0.10 to 0.62, from 31 to 54 and from 85 to 838 mg kg⁻¹, respectively. In the B- and C-horizons, the concentrations of these metals decreased many fold, particularly in the city sewage profile where the decrease for Cd and Zn was approximately fourfold. The distribution of metals among the chemical fractions depended on their total concentrations. In the A1-horizon, Cd had the highest mobility factor [MF = (F1+F2+F3)/(F1+F2+F3+F4+F5+F6) × 100] at 41–43% and Ni had the lowest at 3–13%, while Zn, showed intermediate values at 8–25%. The MF decreased with depth in all soil profiles. Among the fractions, the residual fraction contained the lowest levels of Cd but the highest levels of Ni and Zn. This state affected their relative mobility and distribution in soil profiles. Of the soil profiles, the mobility of all metals was higher in the city sewage soil than in any of the other three soils investigated, suggesting that the former may create a health risk by contaminating agricultural products and ground water as it also contained higher amounts of Cd and Zn.     

Integrated Front-End Radar Receivers at Ka-Band

This paper describes the Integrated Finline Front-end Radar Receivers at Ka-Band. The Front-receivers developed for Radar applications include combining of finline components on a single MIC substrate with various planar transmission lines. The integrated systems so developed have better noise figure and control over phase and gain imbalances as compared to discrete component systems. Two types of Integrated Front-ends Radar receivers are described here. The developed systems are highly compact and reliable.     

In situ micro/nano-hydrogel synthesis from acrylamide derivates with lecithin organogel system

Acrylamide based hydrogel particles with variable charge were synthesized in different sizes using a biocompatible surfactant. We use microemulsion polymerization to synthesize the hydrogel particles in lecithin organogel systems. The phospholipid, lecithin, is a soybean extract that exhibits a rich phase behavior depending on various factors such as amount of water, co-solvent, additives and their concentrations. By UV irradiation of water-in-oil microemulsions of lecithin, containing different monomers, phospholipid coated hydrogels were synthesized in situ. The hydrogel particle size varies from a few hundred nanometers to tens of micrometer. The response time of these micron sized hydrogel particles, as measured by swelling experiments, is very fast (∼10⁰ s) in comparison with their corresponding bulk hydrogels (∼10¹ h). The positively charged cationic hydrogel microparticles were embedded/dispersed into another hydrogel matrix to render responsive behavior to a non-responsive matrix. Besides TEM and SEM studies, fluorescein dye absorption studies were also performed in order to visualize the hydrogel microparticles. Additionally, anionic hydrogel micro/nano-particles were also synthesized in the lecithin system.     

Synthesis,structure and calculated NLO properties of [(n-Bu)2Sn-μ-O-μ-OH-Sn(n-Bu)2(CH3CO2)]2 and its putative derivatives

Title compound[(n-Bu)₂Sn-μ-O-μ-OH-Sn(n-Bu)₂(CH₃CO₂)]₂ was obtained accidentally by the reaction of n-Bu₂SnCl₂ with the metalloligand K₂[Ni(CDC)₂] in ethanol - water mixture while synthesizing a heterobimetallic complex [n-Bu₂Sn Ni(CDC)₂]. This has been characterized by micro analysis, UV–Vis, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy and the single crystal X-ray. The complex forms an interesting supramolecular architecture via (acetate)O?HO hydrogen bonding interactions which generates hydrophobic “pseudo-cage”. The electronic absorption bands of the title complex were assigned with the help of the time dependent density functional theory (TD-DFT) calculations. Density functional theory (DFT) calculations have been performed at the optimized molecular geometry of some of its putative derivatives e. g. trans p-amino cinnamic acid derivative 2; trans p-amino cinnamic acid and trans p-nitro cinnamic acid derivative 3; trans p-amino cinnamic acid and trans p-(N,N dimethylamino) cinnamic acid derivative 4. The first static hyperpolarizability (β) of the title compound and its derivatives were calculated with double numerical differentiation of total energies. The derivatives 3 and 4 showed three times and five times enhancement in the non-linear optical (NLO) responses than the standard p-nitroaniline (pNA).     

Microwave‐assisted facile and convenient synthesis of fatty acid amide (erucamide): Chemical‐catalyzed rapid method

The present investigation explores a process for the production of erucamide, utilizing microwave irradiation as the heating element for the reaction between erucic acid and gaseous ammonia liberated by urea in the presence of catalyst (di‐ammonium hydrogen ortho‐phosphate) at atmospheric pressure and high temperature. In this process, the time of reaction is very short (25 min) and the yield is also good (92%).     

Biogenic synthesis and thermo‐magnetic study of highly porous carbon nanotubes

Nanomaterials synthesis using natural sources is the technology to up come with advanced materials through extracts of plant, microorganisms, poultry waste etc. In this study, the authors report the synthesis of porous carbon nanotubes using high‐temperature decomposition technique facilitated by cobalt salt using chicken fats, a poultry waste as a precursor. Since chicken fats contain fatty acids which can decompose into short hydrocarbon chains and cobalt can act as the catalyst. The formation of carbon nanotubes was confirmed by Raman spectra, peaks at 1580 and 1350.46 cm⁻¹ confirmed the graphite mode G‐band and structural imperfections defect mode D‐band, respectively. Transmission electron microscopy showed the formation of tube‐like structures. Nitrogen adsorption–desorption studies showed the high‐surface area of 418.1 m² g⁻¹ with an estimated pore diameter of 8.1 nm. Thermogravimetry analysis–derivative thermogravimetric analysis–differential thermal analysis showed the instant weight loss at 517°C attributed to the rapid combustion of nanotubes. A vibrating‐sample magnetometer showed the paramagnetic nature of the so‐formed carbon nanotubes formed.Inspec keywords: transmission electron microscopy, infrared spectra, nanomagnetics, pyrolysis, decomposition, adsorption, desorption, carbon nanotubes, differential thermal analysis, thermal analysis, nanofabrication, Raman spectra, X‐ray diffraction, scanning electron microscopy, paramagnetic materialsOther keywords: biogenic synthesis, highly porous carbon nanotubes, microorganisms, high‐temperature decomposition technique, cobalt salt, chicken fats, fatty acids, short hydrocarbon chains, Raman spectra, graphite mode G‐band, structural imperfections defect mode D‐band, transmission electron microscopy, paramagnetic nature, thermo‐magnetic properties, poultry waste, nitrogen adsorption‐desorption studies, thermogravimetry analysis, differential thermal analysis, carbon nanotubes, temperature 517.0 degC, C     

Physicochemical,thermal and pasting properties of starch separated from γ-irradiated and stored potatoes

The morphological, thermal and pasting properties of starch separated from potatoes of three varieties (Kufri Chandramukhi, Kufri Jyoti and Kufri Chipsona-2), treated either with CIPC (isopropyl N-(3 chlorophenyl) carbamate) or γ-irradiation (Co⁶⁰, 0.1 and 0.5 kGy) and subsequently stored at 8, 12 and 16 °C for 90 days, were studied. Scanning electron microscopy (SEM) showed the presence of oval and irregular shaped starch granules with a diameter range of 15–16 μm. Mean granule size of starch separated from potatoes stored at 12 °C ranged from 18–25 μm and irradiation treatment resulted in an increase in the proportion of small size granules. The irradiation of potatoes with 0.5 kGy resulted in starch with significantly lower peak-, trough- and breakdown-viscosity as compared to starch from potatoes treated with either CIPC or 0.1 kGy irradiation. The irradiation of potatoes with 0.5 kGy caused a significant increase in setback and pasting temperature. Pasting temperature of starch was observed to vary with the storage temperature. Starch separated from potatoes stored at higher temperature showed lower pasting temperature and vice versa. The starch from potatoes stored at 8 °C showed higher peak-, trough- and breakdown-viscosity and lower setback. Peak viscosity increased and swelling volume decreased with increase in storage temperature. FTIR spectra showed that the starch from irradiated potatoes displayed a significant decrease in the intensity of the C–H stretch region between 2800 and 3000 cm⁻¹, which was observed to be irradiation dose-dependent, and higher with 0.5 than 0.1 kGy. However, a slight broadening of O–H stretch (3000–3600 cm⁻¹) in starches from irradiated potatoes was observed. The spectral changes caused by γ-irradiation were apparent in the O–H stretch (3000–3600 cm⁻¹), C–H stretch (2800–3000 cm⁻¹) and bending mode of water (1600–1800 cm⁻¹).