Effect of XRD relative intensities of the Li (002) on surface,optical and electrochemical impedance spectroscopy analyses of the deposited LiCoO<Subscript>2</Subscript> thin film

In this paper, the effect of RF power on LiCoO₂ thin films was investigated using X-ray diffractometer (XRD), atomic force microscopy, UV–Vis spectrophotometer, and potentiostat. The microstructural, surface, optical and electrochemical impedance measurements were performed to LiCoO₂ thin films, are used to for the fully solid-state battery cathode material. According to obtained results, the relative intensities of the Li (002) crystal phase in XRD patterns of deposited LiCoO₂ thin films were increased by increasing applied RF power, for the first time. The intensity of the LiCoO₂ (104) plane is nearly invariant. The relative intensities of the LiCoO₂ (113) plane were decreased by increasing RF power. The peak locations of the Li (002) and LiCoO₂ (104) were not changed. It was found that Li (002) relative intensities affect the all investigated parameters for the LiCoO₂ thin films. Especially, transmittance value increased about 20%. The band gap of the deposited film was changed 100–300 meV drastically. Deposited samples are shown high transparency in the visible region. Randles circuit was used for the equivalent circuit model. Nyquist plots, fitting parameters values and value of the circuit elements were estimated by ZSim software.     

Exploring Blockchain and Smart Contract Technology for Reliable and Secure Land Registration and Record Management

The most significant issue in the government registry department is the duplicate registry of land in the current scenario. These kinds of problems are increasing day by day by day, which necessitates the advancement of the existing registry process system. It is a manual process that a typical stamp-based or newly not secure online process (only a few places). Use of a manual process, there are many issues in the duplicate registry of a particular land. The final registry, where the landlord has a stamp paper copy and sale deed or a specific number of the property. One receipt copy at the land registry department for their record. Blockchain has emerged as a new technology to resolve or handle the above-said issue of the current system, a distributed ledger that is a timestamp and immutable. Being immutable, forgeries related to the particular land during the registry are not allowed. This concept provides trust and consensus among all entities in the network or system. In this paper, we propose a framework for automated maintains a record of registry papers. This framework will also resolve the most effort to loan clearance operations and provide transparency in government e-governance. The system handled by the blockchain network, instead of existing typical manual processor online registry record maintain the process, it includes: An authentication scheme at multiple levels to make the blockchain-based framework secure, a quick verification for all the stack holders (bank, registry department, buyer, and seller), and apply Smart Contract to automate check the loan process as government norms and facilitate buyer and seller selling and purchase. The obtained consequences are examined against the latest approaches to indicate the supremacy of the proposed framework and provide transparent, accountable, incoherent data with the different government departments.

     

Passenger Flow Prediction Based on Newly Adopted Algorithms

Passenger flow forecasting is an essential part of transportation systems. Neural networks in the transportation field have been applied to passenger demand prediction. In this paper, we developed two hybrid methods, known as parlimentary optimization algorithm-artificial neural network (POA-ANN), and intelligent water drops algorithm-ANN (IWD algorithm-ANN). In addition, we applied the proposed algorithms to illustrate the effect of precise prediction for passenger queues. We mainly focus on predicting passenger demand by comparing the genetic algorithm-ANN (GA-ANN) with POA-ANN and IWD-ANN. The results of prediction methods suggest that both POA-ANN and IWD-ANN provide a better forecasting performance, which is obtained via mean square error (MSE), than GA-ANN in the field of passenger flow prediction. This study illustrates that the newly adopted algorithms exhibit good performance for passenger prediction.     

PNIPAAm-grafted thermoresponsive microcarriers: Surface-initiated ATRP synthesis and characterization

In this study, we developed novel thermoresponsive microcarriers as a powerful tool for cell culture and tissue engineering applications. For this purpose, two types of commercially available spherical microparticles (approximately 100 μm in diameter), dextran-based Sephadex® and vinyl acetate-based VA-OH (Biosynth®), were used and themoresponsive poly(N-isopropylacrylamide) (PNIPAAm) was grafted to the beads' surfaces by surface-initiated atom transfer radical polymerization (SI-ATRP). Initially, hydroxyl groups of microbeads were reacted with 2-bromopropionyl bromide to form ATRP macroinitiator. Then, NIPAAm was successfully polymerized from the initiator attached microbeads by ATRP with CuBr/2,2′-dipyridyl, catalyst complex. Furthermore, grafted and ungrafted microbeads were characterized by attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, scanning electron microscope (SEM), atomic force microscopy (AFM) and electron spectroscopy for chemical analysis (ESCA). The results of characterization studies confirmed that PNIPAAm was successfully grafted onto both dextran and vinyl acetate-based beads by means of ATRP reaction and thus, grafted microbeads gained thermoresponsive characteristics which will be evaluated for cell harvesting in further studies.     

Leaching kinetics of colemanite in ammonium hydrogen sulphate solutions

The aim of the study was to investigate the dissolution kinetics of colemanite in ammonium hydrogen sulphate solutions in a mechanical agitation system and to declare an alternative reactant to produce boric acid. Reaction temperature, concentration of ammonium hydrogen sulphate, stirring speed, solid/liquid ratio and particle size were selected as parameters on the dissolution rate of colemanite. The experimental results were successfully correlated by linear regression using Statistica Package Program. Dissolution curves were evaluated in order to test shrinking core models for solid–fluid systems. It was observed that increase in the reaction temperature and decrease in the solid/liquid ratio causes an increase the dissolution rate of colemanite. The dissolution extent is highly increased with increase the stirring speed rate between 100 and 500 rpm and the dissolution extent is slowly increased with increase the stirring speed between 500 and 700 rpm in experimental conditions. The activation energy was found to be 32.66 kJ/mol. The leaching of colemanite was controlled by diffusion through the ash or product layer. The rate expression associated with the dissolution rate of colemanite depending on the parameters chosen may be summarized as follows: 1 ? 3(1 ? X)^2/3 + 2(1 ? X) = 8.99 × C^1.08 × W^1.39 × D^?1.27 × (S/L)^?0.54 × e^(?32.66/RT)t.     

Performance, carcass, gastrointestinal tract and meat quality traits, and selected blood parameters of broilers fed diets supplemented with humic substances

BACKGROUND: The effects of humic substances (HS) on quality traits (colour, water‐holding capacity, and pH) of breast and thigh meats and on blood minerals (calcium and phosphorus) and on metabolites (glucose, total protein, triglyceride and cholesterols) as well as on the performance, carcass, and gastrointestinal tract (gut) traits of broilers were studied. In total, 480 male chicks (ROSS 308) were allocated to four treatments, each with five replicates containing 24 birds. While control birds were fed a diet (mash form) with no additives (0 HS), other treatment birds were fed with diets containing HS at 0.5 (0.5 HS), 1.0 (1 HS) or 1.5 (1.5 HS) g kg^?1 from 1 to 42 days of age. RESULTS: The body and carcass weights and feed efficiency increased (P < 0.05) by 1.5 HS, and blood cholesterol decreased (P < 0.05) by 1 HS and 1.5 HS compared to 0 HS. The 0.5 HS decreased (P < 0.10) low‐density lipoprotein compared to 0 HS. The 0.5 HS resulted in thigh meat and breast meat that were lighter and darker than those found in the other groups and 1.5 HS respectively (P < 0.01). CONCLUSION: Feeding with a diet containing HS caused a measurable variation in the meat quality and blood cholesterol as well as the performance, carcass, and gut traits of broilers. Copyright © 2011 Society of Chemical Industry     

Atom Probe Tomography of Zinc Oxide Nanowires

Wide-bandgap zinc oxide (ZnO) semiconductors and nanowires have become important materials for electronic and photonic device applications. In this work, we report the growth of well-aligned single-crystal ZnO nanowire arrays on sapphire substrates by chemical vapor deposition and the development of atom probe tomography, an emerging nanoscale characterization method capable of providing deeper insight into the three-dimensional distribution of atoms and impurities within its structure. Using a metal-catalyst-free approach, the influence of the growth parameters on the orientation and density of the nanowires were studied. The resulting ZnO nanowires were determined to be single crystalline, with diameter on the order of 50 nm to 150 nm and length that could be controlled between 0.5 μm to 20 μm. Their density was on the order of high 10⁸ cm⁻² to low 10⁹ cm⁻². In addition to routine characterizations using scanning and transmission electron microscopy, x-ray diffraction, photoluminescence, and Raman spectroscopy, we developed the atom probe tomography technique for ZnO nanowires, comparing the voltage pulse and laser pulse modes. In-depth analysis of the data was carried out to determine the accurate chemical composition of the nanowires and reveal the incorporation of nitrogen impurities. The current–voltage characteristics of individual nanowires were measured to determine their electrical properties.     

Modelling of the hysteresis effect of target voltage in reactive magnetron sputtering process by using neural networks

Reactive sputtering process is very non-linear and usually exhibits hysteresis behaviour with respect to the reactive gas flow. Most of the problems encountered in the preparation of non-stoichiometric compound films by reactive sputtering are due to the hysteresis effect. Therefore, a considerable amount of effort has been devoted to find means for its elimination or ensuring a stable sputtering in the transition mode. This paper presents a new approach based on Artificial Neural Networks (ANNs) for modelling of the hysteresis effect of target voltage at different target power levels and reactive gas flow rates in reactive sputtering. Based on this model, it is possible to predict the target voltage in reactive magnetron sputtering processes, when the target power level, reactive gas flow rate and its direction are used as inputs to the artificial neural network (ANN). The proposed ANN is trained in different structures with the use of learning algorithms to obtain better performance and faster error convergence. Broyden–Fletcher–Goldfarb Shanno (BFGS) algorithm gives the best result among other learning algorithms used in the analysis. The training and test data required to develop the ANN model are obtained from the experimental studies. Both the training and the test results are in very good agreement with the experimental results obtained in this work.     

Efficacy of different surface treatments and universal adhesives on the microtensile bond strength of bulk-fill composite repair

Abstract

The purpose of this in vitro study was to evaluate the influence of different surface treatments and aging on the microtensile bond strength (μTBS) of bulk-fill composite resins. Bulk-fill composites (Filtek One; 3M ESPE) randomly received five different surface treatments: (1) no treatment, control, (2) 37% phosphoric acid etching (PA), (3) 9% hydrofluoric acid etching (HF), (4) air-borne particle abrasion with 50-μm alumina particles (Al₂O₃), (5) tribochemical silica coating (CoJet). Following, the specimens were divided into three subgroups according to universal adhesive applied: Clearfil Universal Bond (CU; Kuraray), Prime&Bond Universal (PBU; Dentsply Sirona), or Single Bond Universal (SBU; 3M ESPE). A nanofill composite (Filtek Ultimate; 3M ESPE) was employed as a repair. Bonded specimens were stored in water for 24?h at 37?°C or thermal aged, then subjected to the μTBS test. Additionally, specimens were analyzed with a contact profilometer and were evaluated with scanning electron microscopy. Control and PA treatments were showed the lowest µTBS (p?<?0.05), and there was no significant difference between these two groups (p?>?0.05). Al₂O₃ and CoJet treatments generally exhibited a similar influence on µTBS values. In addition, a correlation was found between surface roughness and bond strength (r?=?0.831). CoJet resulted in significantly higher repair µTBS values when compared to the other surface treatments. In addition, the use of silane-containing universal adhesive was increased the cohesive failure rate and maintained the repair µTBS values after thermocycling.     

A case study and troubleshooting experience of safety power channel of instrumentation and control system of the BAEC TRIGA Research Reactor

Microsystem Technologies - Bangladesh Atomic Energy Commission TRIGA Research Reactor (BTRR) is a MK II type nuclear research reactor with a maximum thermal output power of 3&nbsp;MW. Nuclear...