掺杂TBPe的单一发光层白色OLEDs研究

以聚合物poly（N-vinylcarbazole）（PVK）为主体材料,分别掺入蓝光染料2,5,8,11-tetra-tertbutylperylene（TBPe）和橙黄光染料5,6,11,12-tetraphenyl-naphthacene（Rubrebe）,制成单层白色有机电致发光器件（WOLED）。通过多组实验结果的对比,最终确定了最佳染料掺杂浓度和器件结构,得到最佳色举标为（0．33,0．38）,已位于该坐标的白色等能区之内,且随着外加电压由8V增加到16V,色坐标保持不变。器件的亮度为553cd／m^2,外量子效率为0．16％。     

InGaN/GaN多量子阱蓝光LED的p-GaN盖层的MOCVD生长研究

利用金属有机物化学气相淀积（MOCVD）生长了InGaN／GaN多量子阱（MQW）蓝光发光二极管（LED）,研究了不同Cp2Mg流量下生长的p-GaN盖层对器件电学特性的影响。结果表明,随着Cp2Mg流量的提高,漏电流升高,并且到达一临界点会迅速恶化;正向压降则先降低,后升高。进而研究相同生长条件下生长的p-GaN薄膜的电学特性、表面形貌及晶体质量,结果表明,生长p-GaN盖层时,Cp2Mg流量过低,盖层的空穴浓度低,电学特性不好;Cp2Mg流量过高,则会产生大量的缺陷,盖层晶体质量与表面形貌变差,使得空穴浓度降低,电学特性变差。因此,生长p-GaN盖层时,为使器件的正向压降与反向漏电流均达到要求,Cp2Mg流量应精确控制。     

矿井巷道挡水墙设计及施工技术

矿井水害有多种,解决水害的方法也不同,在分析矿井水害的来源及安全承受水压的基础上,依据《煤矿井下车场及硐室设计规范》《煤矿防治水设计规范》,采用挡水墙来解决矿井水害.挡水墙的主要作用是堵截过水通道,防止邻近矿井或本矿井的大突水点向本矿井突水,作为解决矿井水害的一种方法,有施工工艺简单、不受场地限制、便于施工的优点,普遍...     

纳米炭黑水泥砂浆的导电性与电热特性研究

研究了纳米炭黑水泥砂浆的导电性和电热特性.研究表明,当炭黑掺量＜2.5%时,随着炭黑掺量的增加,电阻率下降明显;炭黑掺量为2.5%时,炭黑水泥砂浆电阻率可达到102Ω·cm;而炭黑掺量＞2.5%时,电阻率下降趋缓.在炭黑掺量为5%左右电阻率基本不变,电阻率在30～40Ω·cm之间.与石墨粉相比,纳米炭黑做导电相只需较小掺量,就可制备满足电热功能应用的导电混凝土.当炭黑掺量＞1%时,龄期对电阻率影响小,其电阻比较稳定.炭黑水泥砂浆板电功率稳定、电热功能重复性好.     

石墨烯增强铝基复合材料导电性能的研究

采用粉末冶金法,制备了石墨烯增强铝基复合材料,研究了石墨烯含量及烧结温度对复合材料组织及力学性能、导电性能的影响.结果表明,当石墨烯添加量为0.3％(质量分数)、在580 ℃烧结1h时,所得复合材料晶粒较细小,分布较均匀,致密度最大,为90.14％,电导率最高,为25.54 MS/m,硬度最大,为HB23.35.     

P(AM-g-NBR)改性共混型吸水膨胀丁腈橡胶制备与性能研究

以两亲性接枝聚合物丙烯酰胺接枝丁腈橡胶P(AM-g-NBR)为增溶剂,将丁腈橡胶(NBR)与自制的吸水树脂(SAR-PA)共混制备出了吸水膨胀丁腈橡胶WSR-NB。考察了P(AM-g-NBR)及SAR-PA对吸水橡胶性能的影响。实验结果表明,P(AM-g-NBR)的加入可明显改善吸水橡胶的力学性能及吸水性能;随吸水树脂用量增大,吸水橡胶的拉伸强度降低,吸水率增大。     

一种新型磷化工艺研究

对一种新型不含亚硝酸盐的磷化工艺进行了研究,获得了该工艺合适的处理方法和操作条件,由于其性能的优异,值得推广使用。     

费托合成浆态床速度分布和浓度分布的模拟及其影响规律

提出了浆态床速度分布的一维流体力学模型和合成气液相浓度分布的二维扩散模型,用于描述浆态床液相返混对费托合成反应的影响。模型计算结果与示范工厂数据符合良好。计算表明,液相返混状态对合成气转化率有显著影响。利用模型考察了空塔气速对合成气转化率和空时产率的影响规律,随气速增加,合成气转化率单调下降,空时产率先增大后缓慢降低;塔径放大后,中心液速和液相循环流率都增大,浆料返混加剧,费托合成反应转化率降低。     

Highly Porous Zirconia Ceramic Foams with Low Thermal Conductivity from Particle‐Stabilized Foams

Zirconia ceramic foams with ultra‐high porosity of 96%–98% have been fabricated using sodium dodecyl sulfate (SDS) as the particle stabilizer of zirconia particles for the first time. The wet foams stabilized by zirconia particles are ultra‐stable due to partially hydrophobic zirconia particles modified by SDS. Zirconia foams exhibit close cells with thin cell wall and small grain size. Increasing SDS concentration favors the foamability of the suspension, and further increases the porosity of ceramic foams. Zirconia ceramic foams with porosity of 98.1% have compressive strength of 0.26 ± 0.05 MPa. Decreasing solid loading leads to the porosity of ceramic foams. The compressive strength could be improved significantly by increasing the sintering temperature. Zirconia ceramic foams with porosity of 97.9% has low thermal conductivity of 0.027 ± 0.004 W·(m·K)^?1, which could be used as thermal insulation and refractory material.     

Facile fabrication of ultra-low density,high-surface-area,broadband antireflective carbon aerogels as ultra-black materials

Carbon aerogels with various densities, even as low as 20 mg/cm³, were fabricated by pyrolysis of organic aerogels formed by aqueous condensation of resorcinol and formaldehyde. It was found that carbon aerogels with the density below 70 mg/cm³ exhibited the total reflectance values of typically less than 0.24 % across wavelengths in the range of 400–2000 nm. The change of antireflective properties between the lowest-density carbon aerogel monolith and its powder coating was discussed. Furthermore, we studied the effect of the density on the structure and antireflective property of carbon aerogels. As a result, the low-density carbon aerogels showed broadband low-reflectivity and high absorption to incident light.