Realization of high mobility p-type co-doped ZnO: AlN film with a high density of nitrogen-radicals

High mobility p-type ZnO:AlN thin films have been efficiently realized by utilizing pre-activated nitrogen (N) plasma sources with an inductively coupled dual target co-sputtering system. High density of N-plasma-radicals was generated with an additional RF power applied through a ring-shaped quartz-tube located inside the chamber during co-sputtering process. The AlN codoped ZnO film shows excellent p-type behavior with a high mobility and a hole concentration of 154 cm^2°V^− 1s^− 1 and about 3 × 10^18°cm^− 3 at 600 °C, respectively. Electrical properties of p-n homo-junction devices based on p-type ZnO film are also discussed.     

Wafer-scale fabrication of polymer-based microdevices via injection molding and photolithographic micropatterning protocols

Because of their broad applications in biomedical analysis, integrated, polymer-based microdevices incorporating micropatterned metallic and insulating layers are significant in contemporary research. In this study, micropatterns for temperature sensing and microelectrode sets for electroanalysis have been implemented on an injection-molded thin polymer membrane by employing conventional semiconductor processing techniques (i.e., standard photolithographic methods). Cyclic olefin copolymer (COC) is chosen as the polymer substrate because of its high chemical and thermal stability. A COC 5-in. wafer (1-mm thickness) is manufactured using an injection molding method, in which polymer membranes (approximately 130 microm thick and 3 mm x 6 mm in area) are implemented simultaneously in order to reduce local thermal mass around micropatterned heaters and temperature sensors. The highly polished surface (approximately 4 nm within 40 microm x 40 microm area) of the fabricated COC wafer as well as its good resistance to typical process chemicals makes it possible to use the standard photolithographic and etching protocols on the COC wafer. Gold micropatterns with a minimum 5-microm line width are fabricated for making microheaters, temperature sensors, and microelectrodes. An insulating layer of aluminum oxide (Al2O3) is prepared at a COC-endurable low temperature (approximately 120 degrees C) by using atomic layer deposition and micropatterning for the electrode contacts. The fabricated microdevice for heating and temperature sensing shows improved performance of thermal isolation, and microelectrodes display good electrochemical performances for electrochemical sensors. Thus, this novel 5-in. wafer-level microfabrication method is a simple and cost-effective protocol to prepare polymer substrate and demonstrates good potential for application to highly integrated and miniaturized biomedical devices.     

Residual strength prediction for aircraft panels with Multiple Site Damage,using the “EPFEAM” for stable crack growth analysis

In this paper, a new analytical method for solving stable crack propagation problems in a ductile panel with a row of cracks, is presented. The main purpose of the present study is to estimate the maximum load carrying capacity of such panels accurately. The so called Elastic Plastic Finite Element Alternating Method (Pyo et al. (1994) was extended to account for the propagating cracks. The crack propagation algorithm utilizes the analytic crack solution to release the stresses ahead the crack tip. The T _inf ^sup* integral is employed as the crack extension criterion. This integral parameter accounts for the near tip stress-strain singularity and its critical values for crack propagation can be extracted from the P-a curve of single cracked specimen case. The present method can be applied to the problems of the fuselage skin of aging airplanes, in which a row of cracks develop (MSD; Multiple Site Damage) from rivet holes. The load carrying capacity of such damaged structure reduces by a considerable amount. In order to predict the behavior near the critical load, one must account for plastic deformation, if the material is ductile. Furthermore, the maximum load carried by the structure is often reached after some amount of crack propagation. In this paper, a series of analyses have been conducted and their results compare with the available experimental data.     

An elastic-plastic finite element alternating method for analyzing wide-spread fatigue damage in aircraft structures

In this paper, a new analytical technique to study the effect of wide-spread fatigue damage in ductile panels is presented. The main purpose of the study is to develop an efficient methodology to predict the maximum load carrying capacity of panels with cracks. The problem arises especially in the fuselage skin of aging airplanes, in which cracks initiate from a row of rivet holes. This problem is known as Multi Site Damage (MSD) in aging aircraft. It is very important to estimate the load carrying capacity. Usually, the approach based on elastic fracture mechanics may overestimate the load capacity. It is very important for the aircraft structure with MSD to estimate the load carrying capacity of such damaged structures. Approaches based on elastic fracture mechanics often lead to a considerable error. In this paper, the Elastic Finite Element Alternating Method (EFEAM) has been extended to the case of elastic-plastic fracture of panels with MSD cracks. In EFEAM, analytical solutions to crack problems in an infinite plate are employed. In this study, we adopted an analytical solution for a row of cracks in an infinite panel. Furthermore, the plastic deformation is accounted for, by using the initial stress algorithm. The T _inf ^sup* integral is employed for the fracture criterion. The methodology developed in the present study can be called as Elastic-Plastic Finite Element Alternating Method (EPFEAM) for MSD problems. A series of studies on the maximum load capacity of panels with a row of cracks has been conducted.The support of this work by the Federal Aviation Administration through a grant to the Center of Excellence for Computational Modeling of Aircraft Structures, at the Georgia Institute of Technology, is sincerely appreciated.     

Enhanced Controllability of Fries Rearrangements Using High‐Resolution 3D‐Printed Metal Microreactor with Circular Channel

High‐resolution 3D‐printed stainless steel metal microreactors (3D‐PMRs) with different cross‐sectional geometry are fabricated to control ultrafast intramolecular rearrangement reactions in a comparative manner. The 3D‐PMR with circular channel demonstrates the improved controllability in rapid Fries‐type rearrangement reactions, because of the superior mixing efficiency to rectangular cross‐section channels (250 µm × 125 µm) which is confirmed based on the computational flow dynamics simulation. Even in case of very rapid intramolecular rearrangement of sterically small acetyl group occurring in 333 µs of reaction time, the desired intermolecular reaction can outpace to the undesired intramolecular rearrangement using 3D‐PMR to result in high conversion and yield.     

Ultrasensitive Strain Sensor Based on Separation of Overlapped Carbon Nanotubes

Although there have been remarkable improvements in stretchable strain sensors, the development of strain sensors with scalable fabrication techniques and which both high sensitivity and stretchability simultaneously is still challenging. In this work, a stretchable strain sensor based on overlapped carbon nanotube (CNT) bundles coupled with a silicone elastomer is presented. The strain sensor with overlapped CNTs is prepared by synthesizing line‐patterned vertically aligned CNT bundles and rolling and transferring them to the silicone elastomer. With the sliding and disconnection of the overlapped CNTs, the strain sensor performs excellently with a broad sensing range (≥145% strain), ultrahigh sensitivity (gauge factor of 42 300 at a strain of 125–145%), high repeatability, and durability. The performance of the sensor is also tunable by controlling the overlapped area of CNT bundles. Detailed mechanisms of the sensor and its applications in human motion detection are also further investigated. With the novel structure and mechanism, the sensor can detect a wide range of strains with high sensitivity, demonstrating the potential for numerous applications including wearable healthcare devices.     

TiO2-grafted multi-walled carbon nanotubes for dye-sensitized solar cells

Dye-Sensitized Solar Cells (DSSCs) comprised of TiO2 porous films with multi-walled carbon nanotubes (MWNT) were prepared at low temperature (150 degrees C). MWNT were incorporated to facilitate the fast electron transport resulting from metallic properties of carbon nanotubes. In order to enhance the effect of MWNT incorporation, TiO2-grafted MWNT (TiO2-MWNT) was synthesized which can increase the electron transport rate further due to proximity of TiO2 to MWNT The presence of TiO2 nanoparticles on the surface of MWNT was confirmed by electron microscopy and energy dispersive X-ray spectroscopy. As in the DSSCs prepared through high temperature sintering of photoanodes, the maximum content of MWNT incorporated into TiO2 was limited to 0.01 wt% relative to TiO2. TiO2 photoanodes including TiO2-grafted MWNT (TiO2-MWNT/P25) enhanced the cell efficiencies by ca. 28% and 14%, relative to TiO2 photoanodes without and with MWNT respectively, reaching the efficiency of 5.0%. Electrochemical impedance spectroscopy (EIS) was utilized to examine the effect of incorporation of TiO2 nanoparticles grafted to MWNT on the cell performance.     

Novel SrCo1 − 2x(Fe,Nb)xO3 − δ (x = 0.05, 0.10) oxides targeting CO2 capture and O2 enrichment: Structural stability and oxygen sorption properties

The novel Fe/Nb co-doped SrCo_1 ? 2x(Fe,Nb)_xO_3 ? δ (x = 0.05, 0.10) perovskite oxides were synthesized by the solid-state method. Structural and chemical stability of the SrCo_1 ? 2x(Fe,Nb)_xO_3 ? δ (x = 0.05, 0.10) oxides were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TG) and X-ray diffraction (XRD). The results demonstrated that the structural and chemical stability of the Fe/Nb co-doped SrCo_1 ? 2x(Fe,Nb)_xO_3 ? δ (x = 0.05, 0.10) is improved significantly. The oxygen sorption properties of the SrCo_1 ? 2x(Fe,Nb)_xO_3 ? δ (x = 0.05, 0.10) oxides were investigated between 300–900 °C in air, and the high oxygen sorption capacity of 11.5 and 10.3 mL O₂ (STP)/g oxide, respectively, are obtained.     

Significant improvement of the oxygen permeation flux of tubular Ba0.5Sr0.5Co0.8Fe0.2O3 − δ membranes covered by a thin La0.6Sr0.4Ti0.3Fe0.7O3 − δ layer

We present a new method to improve the oxygen flux properties and stability of Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ tube membrane using a thin layer of La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ as protective coatings. The first relevant result is that the La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ protective layer had an extraordinary positive effect on improving the oxygen permeation flux of the tubular Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ membranes. La_0.6Sr_0.4Ti_0.3Fe_0.7O_3 − δ-coated Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3 − δ tubular membrane showed the highest oxygen permeability with the flux reaching ~ 3 ml cm⁻² min⁻¹ (oxygen purity > 99%) at 950 °C in static atmospheric pressure through a 1.0 mm thick membrane.