Adsorption‐concentration polarization model for ultrafiltration in mixed matrix membrane

Adsorption has been found to be significant in ultrafiltration by mixed matrix membrane. Removal of very low molecular weight solutes compared to the molecular weight cut off of the membrane is facilitated by adsorption. The modeling of the adsorption coupled with concentration polarization is presented based on the mathematical approach developed by Gekas et al. (Gekas et al. Chem Eng Sci. 1993;48:2753–2765), from the first principles. However, extensive modifications were included in theoretical development including those suggested by Ruiz‐Bevia et al. (Ruiz‐Bevia et al. Chem Eng Sci. 1997;52:2343–2352). The developed model captured the rejection dynamics with the help of retention factor. The model equations were solved under the framework of boundary layer analysis, using the integral approach. Effects of the adsorption isotherm and the different parameters affecting the system performance were also investigated. Further, experimental validation of the model results with two different mixed matrix ultrafiltration studies was also elucidated. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2354–2364, 2014     

Characterizing nutrient dynamics with relation to changes in partial pressure of CO2 in a tropical sewage‐fed aquaculture pond situated in a Ramsar wetland

The changes in nutrient dynamics (nitrate, ammonium, silicate, phosphate and iron concentration) vis‐à‐vis partial pressure of CO₂ in water [pCO₂(water)] from tropical sewage‐fed aquaculture ponds (East Kolkota Wetlands, India) were analysed by means of a microcosm. A significant relationship between these nutrient’s removal from the system and reduction in pCO₂(water) was observed (with few exceptions). These water bodies acted as significant sources of CO₂ in pre‐monsoon and monsoon seasons despite having substantial quantity of chlorophyll‐a to make it a net autotrophic system. The study revealed that if conditions favourable for optimum photosynthesis can be maintained in these ponds, the CO₂ source character of these ponds can be reversed. In the post‐monsoon season, when the pH of the water column was high, the system acted as sink for CO₂ which suggests the use of lime to prevent these systems from becoming hypereutrophic and carbon source at the same time.     

New control allocation algorithms in fixed point framework for overactuated systems with actuator saturation

In this paper, two control allocation algorithms have been proposed for overactuated systems. The algorithms are developed by formulating constrained control allocation problem into an equivalent fixed point framework. The first algorithm follows sequential solving method while the other one involves a zero finding technique by the Newton method. In order to consider limiting constraints, the saturation function has been taken into account that leads to a nonsmooth zero finding problem and the proposed method guarantees superlinear convergence. The second algorithm is easy to implement and faster than the algorithm developed based on the sequential solving technique. To demonstrate the effectiveness of the proposed algorithms, a detail simulation study has been carried out, in which one example considers both the actuator rate and amplitude constraints.     

Response of OceanSat II scatterometer winds in the Bay of Bengal circulation

Surface wind is one of the major forcing factors in any ocean circulation model. The response of satellite-derived OceanSat II scatterometer (OSCAT) winds during spring (February and March) 2010 in the Bay of Bengal (BOB) surface circulation is described in this study. Wind stress is calculated from wind speed derived from OSCAT by the bulk-aerodynamic formula. The Regional Ocean Modeling System is used in this study because it is a free-surface, terrain-following, primitive-equations ocean model widely used by the scientific community for a diverse range of applications. The model is used after a climatological simulation with Comprehensive Ocean–Atmosphere Data Set (COADS) forcing when the model simulation reached the annual cycle. The paper also carried out a comparative study of National Centers for Environmental Prediction (NCEP) forcing over the same time period. The comparison of model-simulated surface temperature to National Oceanic and Atmospheric Administration (NOAA) sea surface temperature (SST) indicates that meso-scale features in the BOB are resolved due to the finer resolution of this model. Comparisons of water mass characteristics to the available ARGO floats show good agreement in different locations within the BOB. This study confirms the usefulness of OSCAT winds in simulating the meso-scale feature in the BOB.     

Synthesis of Nanofiber‐like Mesoporous γ‐Al2O3 toward Its Adsorption Efficiency for Congo Red

Nanofiber‐like mesoporous γ‐Al₂O₃ was synthesized using freshly prepared boehmite sol in the presence of triblock copolymer, P123 following evaporation‐induced self‐assembly (EISA) process followed by calcinations at 400°C–1000°C. The samples were characterized by thermogravimetry (TG), differential thermal analysis (DTA), X‐ray diffraction (XRD), N₂ adsorption–desorption, and transmission electron microscopy (TEM). The adsorption efficiency of the samples with Congo red (CR) was studied by UV – vis spectroscopy. XRD results showed boehmite phase in the as‐prepared sample while γ‐Al₂O₃ phase obtained at 400°C was stable up to 900°C, a little transformation of θ‐Al₂O₃ resulted at 1000°C. The Brunauer‐Emmett‐Teller surface area of the 400°C‐treated sample was found to be 175.5 m²g ^{? 1}. The TEM micrograph showed nanofiber‐like morphology of γ‐Al₂O_3. The 400°C‐treated sample showed about 100% CR adsorption within 60 min.     

Modeling of Gel Layer-Controlled Fruit Juice Microfiltration in a Radial Cross Flow Cell

An analysis of gel layer-controlled microfiltration in a radial cross flow cell is presented in this study. Clarification of a real fruit juice, i.e., cactus pear juice is considered. An expression of Sherwood number is derived using an integral method under the framework of boundary layer theory. The effects of viscosity and temperature are incorporated in the Sherwood number relationship through the Sieder–Tate type correction factor and Stokes–Einstein equation, respectively. The transient flux behavior is modeled successfully both for the total recycle mode and batch concentration mode of operation. The model parameters are evaluated from the total recycle mode and are used in the predictive calculation of the batch concentration mode. In batch concentration mode of filtration, the model predicted results match excellently with the experimental data.     

Robust stability and performance analysis for uncertain linear systems—The distance measure approach

This paper presents readily applicable distance measures, robust stability margins and associated robust stability and robust performance theorems for three commonly used uncertainty structures (additive, input/output multiplicative, output/input inverse multiplicative). Besides providing robust stability results for a larger uncertainty class than previously reported (???_∞ instead of ???_∞), this paper also states robust performance theorems for the above uncertainty structures. In contrast to previous methods for robust performance analysis, they only require the computation of two infinity norms for every uncertain plant considered. The theorems in this paper enable practising engineers to choose the most suitable uncertainty structure for a family of uncertain plants, as illustrated through a physically motivated numerical example. Copyright © 2011 John Wiley & Sons, Ltd.     

Comprehensive interpretation of gel electrophoresis data

From temperature analysis of polyacrylamide gel electrophoresis data for rigid-rod DNA analytes, it is proposed that an entropic force term is responsible for the discrepancy between Ogston-Morris-Rodbard-Chrambach model predictions and experimental results. This entropic force originates from reduction of the orientational freedom of anisotropic analytes in small pores of polyacrylamide gels. Time-dependent fluorescence anisotropy decay measurements confirm that, even in the absence of an external field, orientation of anisotropic analytes is restricted in polyacrylamide gels. A new comprehensive model is proposed that takes this effect into consideration. Predictions based on this model are found to compare favorably with experimental data for linear and three-arm asymmetrically branched rigid-rod DNA analytes covering a broad range of molecular aspect ratios and sizes. A new length scale is also proposed for describing the effect of analyte topology on electrophoretic mobility. This length scale reduces to the analyte radius of gyration in the limiting cases of spherically symmetric and linear rigid-rod species. Based on these results, a general approach is proposed for interpreting gel electrophoresis data of charged analytes possessing simple and complex topologies.     

Influence of different carbon nanotubes on the electrical and mechanical properties of melt mixed poly(ether sulfone)-multi walled carbon nanotube composites

Commercial Udel® poly(ether sulfone) (PSU) was filled with three different commercially available multiwalled carbon nanotubes (MWCNTs) by small scale melt mixing. The MWCNTs were as grown NC 7000 and two of its derivatives prepared by ball milling treatment. One of them was unmodified (NC 3150); the other was amino modified (NC 3152). The main difference beside the reactivity was the reduced aspect ratio of NC 3150 and NC 3152 caused by ball milling process. All PSU/MWCNT composites with similar filler content were prepared under fixed processing conditions and comparative analysis of their electrical and mechanical properties were performed and were correlated with their microstructure, characterized by optical microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). A non-uniform MWCNT dispersion was observed in all composites. The MWCNTs were present in form of agglomerates in the size of 10–60 μm whereas the deagglomerated part was homogeneously distributed in the PSU matrix. The differences in the agglomeration states correlate with the variations of properties between different PSU/MWCNT composites. The lowest electrical percolation threshold of 0.25–0.5 wt.% was observed for the shortened non-functionalized MWCNT composites and the highest for amine-modified MWCNT composites (ca. 1.5 wt.%). The tensile behavior of the three composites was only slightly altered with CNT loading as compared to the pure PSU. However, the elongation at break showed a reduction with MWCNT loading and the reduction was least for composite with best MWCNT dispersion.