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941.
Hengfei Gu Fei Zhang Shinjae Hwang Anders B. Laursen Xin Liu So Yeon Park Mengjin Yang Rosemary C. Bramante Hussein Hijazi Leila Kasaei Leonard C. Feldman Yao-Wen Yeh Philip E. Batson Bryon W. Larson Mengjun Li Yifei Li Keenan Wyatt James L. Young Krishani Teeluck Kai Zhu Eric Garfunkel G. Charles Dismukes 《Advanced functional materials》2023,33(25):2301196
The rapidly increasing solar conversion efficiency (PCE) of hybrid organic–inorganic perovskite (HOIP) thin-film semiconductors has triggered interest in their use for direct solar-driven water splitting to produce hydrogen. However, application of these low-cost, electronic-structure-tunable HOIP tandem photoabsorbers has been hindered by the instability of the photovoltaic-catalyst-electrolyte (PV+E) interfaces. Here, photolytic water splitting is demonstrated using an integrated configuration consisting of an HOIP/n+silicon single junction photoabsorber and a platinum (Pt) thin film catalyst. An extended electrochemical (EC) lifetime in alkaline media is achieved using titanium nitride on both sides of the Si support to eliminate formation of insulating silicon oxide, and as an effective diffusion barrier to allow high-temperature annealing of the catalyst/TiO2-protected-n+silicon interface necessary to retard electrolytic corrosion. Halide composition is examined in the (FA1-xCsx)PbI3 system with a bandgap suitable for tandem operation. A fill factor of 72.5% is achieved using a Spiro-OMeTAD-hole-transport-layer (HTL)-based HOIP/n+Si solar cell, and a high photocurrent density of −15.9 mA cm−2 (at 0 V vs reversible hydrogen electrode) is attained for the HOIP/n+Si/Pt photocathode in 1 m NaOH under simulated 1-sun illumination. While this thin-film design creates stable interfaces, the intrinsic photo- and electro-degradation of the HOIP photoabsorber remains the main obstacle for future HOIP/Si tandem PEC devices. 相似文献
942.
David B. Ahn Won-Yeong Kim Kwon-Hyung Lee Seong-Sun Lee Seung-Hyeok Kim Sodam Park Young-Kuk Hong Sang-Young Lee 《Advanced functional materials》2023,33(18):2211597
Conventional power sources encounter difficulties in achieving structural unitization with complex-shaped electronic devices because of their fixed form factors. Here, it is realized that an on-demand conformal Zn-ion battery (ZIB) on non-developable surfaces uses direct ink writing (DIW)-based nonplanar 3D printing. First, ZIB component (manganese oxide-based cathode, Zn powder-based anode, and UV-curable gel composite electrolyte) inks are designed to regulate their colloidal interactions to fulfill the rheological requirements of nonplanar 3D printing, and establish bi-percolating ion/electron conduction pathways, thereby enabling geometrical synchronization with non-developable surfaces, and ensuring reliable electrochemical performance. The ZIB component inks are conformally printed on arbitrary curvilinear substrates to produce embodied ZIBs that can be seamlessly integrated with complicated 3D objects (including human ears). The conformal ZIB exhibits a high fill factor (i.e., areal coverage of cells on underlying substrates, ≈100%) that ensures high volumetric energy density (50.5 mWh cmcell−3), which exceeds those of previously-reported shape-adaptable power sources. 相似文献
943.
Andy Shar Phillip Glass Sung Hyun Park Daeha Joung 《Advanced functional materials》2023,33(5):2211079
3D printing of conductive elastomers is a promising route to personalized health monitoring applications due to its flexibility and biocompatibility. Here, a one-part, highly conductive, flexible, stretchable, 3D printable carbon nanotube (CNT)-silicone composite is developed and thoroughly characterized. The one-part nature of the inks: i) enables printing without prior mixing and cures under ambient conditions; ii) allows direct dispensing at ≈100 µm resolution printability on nonpolar and polar substrates; iii) forms both self-supporting and high-aspect-ratio structures, key aspects in additive biomanufacturing that eliminate the need for sacrificial layers; and iv) lends efficient, reproducible, and highly sensitive responses to various tensile and compressive stimuli. The high electrical and thermal conductivity of the CNT-silicone composite is further extended to facilitate use as a flexible and stretchable heating element, with applications in body temperature regulation, water distillation, and dual temperature sensing and Joule heating. Overall, the facile fabrication of this composite points to excellent synergy with direct ink writing and can be used to prepare patient-specific wearable electronics for motion detection and cardiac and respiratory monitoring devices and toward advanced personal health tracking and bionic skin applications. 相似文献
944.
Dohyung Kim Hyeonsu Bang Hyoung Won Baac Jongmin Lee Phuoc Loc Truong Bum Ho Jeong Tamilselvan Appadurai Kyu Kwan Park Donghyeok Heo Vu Binh Nam Hocheon Yoo Kyeounghak Kim Daeho Lee Jong Hwan Ko Hui Joon Park 《Advanced functional materials》2023,33(14):2213064
Reversible metal-filamentary mechanism has been widely investigated to design an analog resistive switching memory (RSM) for neuromorphic hardware-implementation. However, uncontrollable filament-formation, inducing its reliability issues, has been a fundamental challenge. Here, an analog RSM with 3D ion transport channels that can provide unprecedentedly high reliability and robustness is demonstrated. This architecture is realized by a laser-assisted photo-thermochemical process, compatible with the back-end-of-line process and even applicable to a flexible format. These superior characteristics also lead to the proposal of a practical adaptive learning rule for hardware neural networks that can significantly simplify the voltage pulse application methodology even with high computing accuracy. A neural network, which can perform the biological tissue classification task using the ultrasound signals, is designed, and the simulation results confirm that this practical adaptive learning rule is efficient enough to classify these weak and complicated signals with high accuracy (97%). Furthermore, the proposed RSM can work as a diffusive-memristor at the opposite voltage polarity, exhibiting extremely stable threshold switching characteristics. In this mode, several crucial operations in biological nervous systems, such as Ca2+ dynamics and nonlinear integrate-and-fire functions of neurons, are successfully emulated. This reconfigurability is also exceedingly beneficial for decreasing the complexity of systems—requiring both drift- and diffusive-memristors. 相似文献
945.
Tingdong Zhang Wenfeng Pan Suiting Ning Ning Qi Zhiquan Chen Xianli Su Xinfeng Tang 《Advanced functional materials》2023,33(10):2213761
Synergetic optimization of electrical and thermal transport properties is achieved for SnTe-based nano-crystalline materials. Gd doping is able to suppress the Sn vacancy, which is confirmed by positron annihilation measurements and corresponding theoretical calculations. Hence, the optimal hole carrier concentration is obtained, leading to the improvement of electrical transport performance and simultaneous decrease of electronic thermal conductivity. In addition, the incremental density of states effective mass m* in SnTe is realized by the promotion of the band convergence via Gd doping, which is further confirmed by the band structure calculation. Hence, the enhancement of the Seebeck coefficient is also achieved, leading to a high power factor of 2922 µW m−1 K−2 for Sn0.96Gd0.04Te at 900 K. Meanwhile, substantial suppression of the lattice thermal conductivity is observed in Gd-doped SnTe, which is originated from enhanced phonon scattering by multiple processes including mass and strain fluctuations due to the Gd doping, scattering of grain boundaries, nano-pores, and secondary phases induced by Gd doping. With the decreased phonon mean free path and reduced average phonon group velocity, a rather low lattice thermal conductivity is achieved. As a result, the synergetic optimization of the electric and thermal transport properties contributes to a rather high ZT value of ≈1.5 at 900 K, leading to the superior thermoelectric performance of SnTe-based nanoscale polycrystalline materials. 相似文献
946.
Chun-Hao Chen Fan Hu Zhen-Huang Su Yan-Jun Yu Kai-Li Wang Yi-Ran Shi Jing Chen Yu Xia Xing-Yu Gao Zhao-Kui Wang Liang-Sheng Liao 《Advanced functional materials》2023,33(15):2213661
The substrates of conventional flexible perovskite solar cells (FPSCs) are thermoplastic polymer material polyethylene naphthalate (PEN), which will deform during high temperature annealing process. In addition, lead iodide (PbI2) permanently formed and the substrate undergoes reversible deformation from 20 °C to 200 °C and back to 20 °C. Therefore, to balance the substrate supporting capacity and the crystalline quality of narrow band gap α-phase formamidinium lead iodide (α-FAPbI3), an annealing process of 120 °C for 30 minutes is determined. Additionally, there will also be a large number of gaps and lattice strain at the perovskite grain boundaries during the annealing process as the FAPbI3 phase transition is accompanied by much lattice shrinkage. As a result, 1,6-hexanediammonium diiodide (HADI) is chosen to passivate the defects and release the stress of perovskite film. Therefore, a recorded 1.4% extended stretch rate of the flexible film is attained. Finally, the champion PCE of 21.14% under AM 1.5G and 31.52% under 1062 lux is achieved after HADI treatment, accompanied by a better long-term and mechanical stability. This study provides annealing process optimization and stress relief strategies for the further development of narrow band gap FPSCs. 相似文献
947.
Erming Su Hao Li Jiabin Zhang Zijie Xu Baodong Chen Leo N.Y. Cao Zhong Lin Wang 《Advanced functional materials》2023,33(17):2214934
The anti-glare panels along highways can block the dazzling lights of opposing vehicles at night, playing an important role in the highway safety. Inspired by the highway anti-glare panels, wind energy harvesting triboelectric nanogenerator (AG-TENG) arrays to properly capture energy from highway moving vehicles is developed. A single AG-TENG installation module can achieve a high power density of 0.2 Wm−2 at a wind speed of 3 m s−1. This wind speed is too low to drive conventional wind energy harvesting equipment. The performance of the AG-TENG shows no degradation after 80 h of continuous operation (1 440 000 times). Thus, with the rational consideration and features, the system can generate enough power to drive internet of things (IoT) devices and environmental sensors, as well as offer wireless alarming and radio frequency identification vehicle monitoring. This study provides a promising strategy to properly harvest wind energy on highways using existing infrastructures under the condition of even no natural wind, showing broad application prospects in distributed environmental monitoring, intelligent highways, and the IoT. 相似文献
948.
Zhong Qiu Shenghui Shen Ping Liu Chen Li Yu Zhong Han Su Xueer Xu Yongqi Zhang Feng Cao Abolhassan Noori Mir F. Mousavi Minghua Chen Xinping He Xinhui Xia Yang Xia Wenkui Zhang Jiangping Tu 《Advanced functional materials》2023,33(16):2214987
Construction of high efficiency and stable Li metal anodes is extremely vital to the breakthrough of Li metal batteries. In this study, for the first time, groundbreaking in situ plasma interphase engineering is reported to construct high-quality lithium halides-dominated solid electrolyte interphase layer on Li metal to stabilize & protect the anode. Typically, SF6 plasma-induced sulfured and fluorinated interphase (SFI) is composed of LiF and Li2S, interwoven with each other to form a consecutive solid electrolyte interphase. Simultaneously, brand-new vertical Co fibers (diameter: ≈5 µm) scaffold is designed via a facile magnetic-field-assisted hydrothermal method to collaborate with plasma-enhanced Li metal anodes (SFI@Li/Co). The Co fibers scaffold accommodates active Li with mechanical integrity and decreases local current density with good lithiophilicity and low geometric tortuosity, supported by DFT calculations and COMSOL Multiphysics simulation. Consequently, the assembled symmetric cells with SFI@Li/Co anodes exhibit superior stability over 525 h with a small voltage hysteresis (125 mV at 5 mA cm−2) and improved Coulombic efficiency (99.7%), much better than the counterparts. Enhanced electrochemical performance is also demonstrated in full cells with commercial cathodes and SFI@Li/Co anode. The research offers a new route to develop advanced alkali metal anodes for energy storage. 相似文献
949.
Yikun Su Weirui Yu Liming Liao Xinbo Xiong Huanwen Chen Lingzhi Hu Tongjia Lei Jinlai Zhao Dong Chen Wenjie Mai 《Advanced functional materials》2023,33(42):2303976
Photo-electrochemical (PEC) water splitting is a promising method for converting solar energy into clean energy, but the mechanism of improving PEC efficiency through the interfacial contact and defect strategy remains highly controversial. Herein, reduced graphene oxide (rGO) and oxygen vacancies are introduced into α-Fe2O3 nanorod (NR) arrays using a simple spin-coating method and acid treatment. The resultant oxygen vacancy–α-Fe2O3/rGO-integrated system exhibits a higher photocurrent, four times than the pristine α-Fe2O3. It is well evidenced that the electronic interface interaction between α-Fe2O3 and rGO is boosted with the oxygen vacancies, facilitating electron transfer from α-Fe2O3 to rGO. Moreover, the oxygen vacancies not only create interband states in α-Fe2O3 that can trap photogenerated holes and thus facilitate charge separation but significantly also strengthen the adsorption of oxidative intermediates and reduce the energy barrier of rate-determining step during oxygen evolution reaction (OER). This study demonstrates an rGO–oxygen vacancy synergistic interfacial contact and defect modification approach to design semiconducting photocatalysts for high-efficiency solar energy capture and conversion. The generated principle is expected to be extendable to another material system. 相似文献
950.
Yixing Li Linlin Yang Yijun Liao Rongzhi Zhao Lianze Ji Rui Su Dake Xu Fuhui Wang 《Advanced functional materials》2023,33(35):2302712
Antibacterial elements and non-contact heating abilities have been proven effective for antibacterial and antibiofilm activities, but it remains a challenge to integrate both within one material. Herein, assisted by the high-entropy effect, FeNiTiCrMnCux high-entropy alloy nanoparticles (HEA-NPs) with excellent photothermal heating properties for boosting antibacterial and antibiofilm performances are synthesized. Benefitting from the synergetic effect of copper ions released and thermal damage by the HEA-NPs, more reactive oxygen species (ROS) are generated, leading to the rupture of the cell membranes and the eradication of the biofilms. As a result, the antibiofilm efficiency (400 µg mL−1) of the mostly optimized FeNiTiCrMnCu1.0 HEA-NPs in the marine nutrient medium, which is the worst-case scenario for the antimicrobial material, can be improved from 81% to 97.4% under 30 min solar irradiation (1 sun). The present study demonstrates a new strategy for effectively treating marine microorganisms that cause biofouling and microbial corrosion using HEA-NPs with photothermal heating characteristics as an antibacterial auxiliary. 相似文献