Effectiveness test of alginate‐derived polymeric surfactants

A series of alginate‐derived polymeric surfactants (APSs) with a linear alkyl group (C8, C12, C16) was synthesized by oxidation followed by reductive amination of 2,3‐dialdehydic alginate. The products were characterized by measuring IR spectra, NMR spectra, surface tension and critical micelle concentration (cmc). They were also tested for the solubilization of azobenzene and adsorption of heavy metal. In the case of 40% CHO‐C8 APSs, the lowest interfacial tension value (31.5 m Nm^?1) was obtained at the cmc value of 1.35 g dm^?3. The dissolving capacity of 40% CHO‐C8 APS towards azobenzene was 27 times greater than that of alginate. The overall cobalt (Co²⁺) removal efficiency by adsorption using APSs was high compared with that of sodium alginate at pH 3, 5 and 7. Equilibrium aspects of cobalt adsorption onto 10% CHO‐APSs were studied, and the results show that APSs had high equilibrium capacities for cobalt uptake, 115.5 mgg^?1. © 2002 Society of Chemical Industry     

Cure kinetics of high performance epoxy resin systems

Summary Isothermal cure kinetics ofEPON HPT 1071/DDS system have been performed by means of differential scanning calorimetry. The maximum cure rate and the extent of conversion at various DDS concentrations were studied as a function of cure temperature. Maximum cure rate increases with increasing cure temperature and DDS concentration. At various DDS concentrations, the maximum cure rate occured between 19–22% conversion. In order to evaluate the kinetic parameters, numerical calculations by means of a Newton-Raphson technique and experimental results obtained from the peak of reaction rate curve were undertaken.     

基于CUDA的并行粒子群优化算法研究及实现

应用图形处理器(GPU)来加速粒子群优化(PSO)算法并行计算时,为突出其加速性能,经常有文献以恶化CPU端PSO算法性能为代价。为了科学比较GPU-PSO算法和CPU-PSO算法的性能,提出用"有效加速比"作为算法的性能指标。文中给出的评价方法不需要CPU和GPU端粒子数相同,将GPU并行算法与最优CPU串行算法的性能作比较,以加速收敛到目标精度为准则,在统一计算设备架构(CUDA)下对多个基准测试函数进行了数值仿真实验。结果表明,在GPU上大幅增加粒子数能够加速PSO算法收敛到目标精度,与CPU-PSO相比,获得了10倍以上的"有效加速比"。     

Polymer gel electrolytes prepared from P(EG‐co‐PG) and their nanocomposites using organically modified montmorillonite

Polymer gel electrolytes were prepared by thermal crosslinking reaction of a series of acrylic end‐capped poly(ethylene glycol) and poly(propylene glycol) [P(EG‐co‐PG)] having various geometries and molecular weights. Acrylic end‐capped prepolymers were prepared by the esterification of low molecular weight (M_n: 1900–5000) P(EG‐co‐PG) with acrylic acid. The linear increase in the ionic conductivity of polymer gel electrolyte films was observed with increasing temperature. The increase in the conductivity was also monitored by increasing the molecular weight of precursor polymer. Nanocomposite electrolytes were prepared by the addition of 5 wt % of organically modified layered silicate (montmorillonite) into the gel polymer electrolytes. The enhancement of the ionic conductivity as well as mechanical properties was observed in the nanocomposite systems. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 894–899, 2004     

Synergistic Catalysis of Carbon Dioxide Hydrogenation into Methanol by Yttria-Doped Ceria/γ-Alumina-Supported Copper Oxide Catalysts: Effect of Support and Dopant

Methanol synthesis from carbon dioxide hydrogenation was studied over ceria/-alumina- and yttria-doped ceria (YDC)/-alumina-supported copper oxide catalysts to seek insight into the catalysis at metal–support interfaces. It was found that, in comparison with Cu/-Al₂O₃, the Cu/CeO₂/-Al₂O₃ and Cu/YDC/-Al₂O₃ catalysts exhibited substantial enhancement in activity and selectivity toward methanol formation. The extent of enhancement was augmented by increased ceria loading on -alumina and with increased yttria doping into ceria. The enhancement is inferred to result from the synergistic effect between copper oxide and surface oxygen vacancies of ceria.     

Selective CO oxidation in the presence of hydrogen over supported Pt catalysts promoted with transition metals

Selective CO oxidation in the presence of excess hydrogen was studied over supported Pt catalysts promoted with various transition metal compounds such as Cr, Mn, Fe, Co, Ni, Cu, Zn, and Zr. CO chemisorption, XRD, TPR, and TPO were conducted to characterize active catalysts. Among them, Pt-Ni/γ-Al₂O₃ showed high CO conversions over wide reaction temperatures. For supported Pt-Ni catalysts, Alumina was superior to TiO₂ and ZrO₂ as a support. The catalytic activity at low temperatures increased with increasing the molar ratio of Ni/Pt. This accompanied the TPR peak shift to lower temperatures. The optimum molar ratio between Ni and Pt was determined to be 5. This Pt-Ni/γ A1₂O₃ showed no decrease in CO conversion and CO₂ selectivity for the selective CO oxidation in the presence of 2 vol% H₂O and 20 vol% CO₂. The bimetallic phase of Pt-Ni seems to give rise to stable activity with high CO₂ selectivity in selective oxidation of CO in H₂-rich stream.     

Web交互模型的形式化验证研究

Web交互模型的形式化验证是对Web事件属性进行校验的十分可信的方法。通过一系列的系统模型建立、系统行为分析以及对于模型中关心属性的相关验证,能够让交互模型在设计阶段就能使形式化模型暴露出其所存在的缺陷,而不至于让缺陷保留到编码阶段或者更后面才能被真正地暴露出来,这样使系统模型的生存能力更加强大,同时避免了因后期缺陷暴露而出现的大代价修复。通过对Web系统的交互应用服务的过程模型化的体系进行研究,通过模型本身具有的属性进行相关正确性的校验,主要通过使用数学推理实现系统逻辑上的服务交互进程,从而进行过程的推演,并对系统服务的正确性进行过程的形式化验证,从而使系统服务模块的属性正确性可以通过逻辑上的演进来发现服务问题的存在,而不再是系统通过编码实现后才发现。对Web交互模型的形式化验证是基于IMWSC模型语义形成的IMWSC模型的验证机制。     

具有不同代理群的多代理多签名方案

目前在大多数多代理多签名(multi-proxy multi-signature,MPMS)方案中,所有的原始签名人指定同一个代理群生成代理签名。然而在很多实际应用中,每个原始签名人经常需要在自己所在的组织中选择代理群,从而导致各个原始签名人需要选择不同的代理群,代表自己生成代理签名。现有的多代理多签名方案中还没有考虑这方面的需求。提出一个可以指定不同代理群的MPMS方案。在该方案中,可以指定一个多人的验证群合作验证最终签名的合法性。为证明方案的安全性,对现有的安全模型进行改进,在计算Diffie-Hellman假设的基础上,验证所提方案是安全的。与已有方案相比,本方案更加安全和有效。     

Effects of melt‐extension and annealing on row‐nucleated lamellar crystalline structure of HDPE films

The row‐nucleated lamellar crystalline structure of high‐density polyethylene (HDPE) films was prepared by applying elongation stress to HDPE melt during T‐die cast film extrusion and subsequently annealing the extruded films. This unusual crystalline structure was analyzed in terms of lamellar crystalline orientation, long‐period lamellar spacing, crystallite size, and degree of crystallinity. The contribution of melt‐extension represented by draw‐down‐ratio (DDR) to the overall orientation was found to be most noticeable than other processing variables. Meanwhile, the long‐period lamellar spacing, the crystallite size, and the degree of crystallinity were influenced predominantly by the annealing temperature. Finally, the processing (melt extension and annealing temperature) – structure (lamellar crystalline structure) – property (hard elasticity) relationship of HDPE films was investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3326–3333, 2007     

Chemical Stability of the Fiber Coating Matrix Interface in Silicon-Based Ceramic Matrix Composites

Carbon and boron nitride are used as fiber coatings in silicon-based composites. In order to assess the long-term stability of these materials, reactions of carbon/Si₃N₄ and BN/SiC were studied at high temperatures with Knudsen effusion, coupon tests, and by microstructural examination. In the carbon/Si₃N₄ system, carbon reacted with Si₃N₄ to form gaseous N₂ and SiC. The formation of SiC limited further reaction by physically separating the carbon and Si₃N₄. Consequently, the development of high p (N₂) at the interface, predicted from thermochemical calculations, did not occur, thus limiting the potential deleterious effects of the reaction on the composite. Strong indications of a reaction between BN and SiC were shown by TEM and SIMS analysis of the BN/SiC interface. In long-term exposures, this reaction can lead to a depletion of a BN coating and/or an unfavorable change of the interfacial properties, limiting the beneficial effects of the coating.