High-yield production of graphene by liquid-phase exfoliation of graphite

Fully exploiting the properties of graphene will require a method for the mass production of this remarkable material. Two main routes are possible: large-scale growth or large-scale exfoliation. Here, we demonstrate graphene dispersions with concentrations up to approximately 0.01 mg ml(-1), produced by dispersion and exfoliation of graphite in organic solvents such as N-methyl-pyrrolidone. This is possible because the energy required to exfoliate graphene is balanced by the solvent-graphene interaction for solvents whose surface energies match that of graphene. We confirm the presence of individual graphene sheets by Raman spectroscopy, transmission electron microscopy and electron diffraction. Our method results in a monolayer yield of approximately 1 wt%, which could potentially be improved to 7-12 wt% with further processing. The absence of defects or oxides is confirmed by X-ray photoelectron, infrared and Raman spectroscopies. We are able to produce semi-transparent conducting films and conducting composites. Solution processing of graphene opens up a range of potential large-area applications, from device and sensor fabrication to liquid-phase chemistry.     

Influence of PTFE content in PEEK-PTFE blends on mechanical properties and tribo-performance in various wear modes

Few papers are available on the optimum composition of PEEK-PTFE blends for the best possible combination of mechanical and tribological properties in the adhesive wear mode. Nothing is reported in this context on low amplitude oscillating/fretting wear mode. Moreover, the influence of increasing amounts of PTFE in the blend on abrasive wear behaviour along with a correlation with strength properties is not reported. Hence, in this work, five injection-moulded blends of PEEK with PTFE (in the range of 0-30 wt.%) were evaluated on a pin-on-disc configuration on an SRV Optimol Tester for their tribo-behaviour in the low amplitude oscillating wear mode. The data in the abrasive wear mode were generated by abrading a pin loaded against an abrasive paper fitted on the rotating disc. Data on neat PTFE were also included for comparison. It was observed that inclusion of PTFE affected the adhesive wear and low amplitude oscillating wear (LAOW) in a beneficial way. With an increase in PTFE contents, coefficient of friction in both the wear modes (adhesive and low amplitude oscillating) decreased but the trends in wear performance differed. In the adhesive wear mode, the specific wear rate showed minima for 7.5% PTFE inclusion followed by a slow increase for further PTFE addition. In the case of LAOW mode, on the other hand, the wear rate continuously decreased for the selected compositions. The 30% PTFE blend showed excellent combination of μ, wear rate and limiting pressure-velocity (PV) values. Unfilled PEEK proved to be fairly good wear-resistant material but exhibited high μ, a stick-slip tendency and a low PV limit value. Abrasive wear performance of the blends on the other hand, deteriorated with increasing amount of PTFE. Fairly good correlation was observed between the wear rate and product of H and S (H-hardness and S-ultimate tensile strength) rather than Ratner-Lancaster plot (product of S and e, where e is elongation to break).Thus, with increase in PTFE contents, though adhesive and LAOW performance increased substantially, it was at the cost of deterioration in all mechanical properties (except impact strength) and abrasive wear performance.     

Designing Energy Efficient Strategies Using Markov Decision Process for Crowd-Sensing Applications

Mobile Networks and Applications - In mobile crowd-sensing, smartphone users take part in sensing and then share the data to the server (cloud) and get an incentive. These data can be utilized for...     

Dry and minimum quantity lubrication drilling of cast magnesium alloy (AM60)

Dry and minimum quantity lubrication (MQL) drilling of cast magnesium alloy AM60 used in the manufacturing of lightweight automotive components have been studied. The maximum and average torque and thrust forces measured during drilling using distilled water (H₂O-MQL) and a fatty acid-based MQL fluid (FA-MQL), both supplied at the rate of 10 ml/h, were compared with those generated during flooded (mineral oil) drilling. Tool life during dry drilling was inadequately short, due to excessive magnesium transfer and adhesion to the (HSS steel) drill causing drill failure in less than 80 holes. The use of MQL reduced magnesium adhesion and built-up edge formation, resulting in an increase in tool life as well as reductions in both average torque and thrust forces—prompting a performance similar to that of flooded drilling. The maximum temperature generated in the workpiece during MQL drilling was lower than that observed in dry drilling, and comparable to flooded condition. The mechanical properties of the material adjacent to drilled holes, as evaluated through plastic strain and hardness measurements near the holes, revealed a notable softening in the case of dry drilling, but not for MQL drilling. MQL drilling provided a stable drilling performance, which was evident from the uniform torque and force patterns throughout the drilling cycles and also resulted in desirable machining characteristics, including a smooth hole surface and short chip segments.     

Design Analysis of Heterojunction Solar Cells with Aligned AZO Nanorods Embedded in p-type Si wafer

Higher price-per-watt of silicon (Si) solar cells is still the main bottleneck in their widespread use for power generation due to their expensive manufacturing process. The n-type zinc oxide (n-ZnO) and p-type Si (p-Si) based single heterojunction solar cell is one of the several methods being tried to replace conventional Si single homojunction solar cell technology. In this work, we have explored the possibility of producing photovoltaic materials by employing RF sputtering and hydrothermal technologies. Conductivity of ZnO nanorods has been increased by aluminium (Al) doping. The advantages of using Al doped ZnO (AZO) nanorods (NRs) have been investigated. The integrated reflectance (IR) has been found to be only ~2.86%. Hence, the short circuit current density (Jsc) has been increased by minimizing the reflection loss of solar cells. AZO NR array have been developed over several large area (3″ × 3″) textured p-Si wafers to confirm the repeatability. The maximum efficiency of AZO NRs/Si solar cell of 0.8 cm2 area has been found to be 6.25% for textured p-type Si wafer which is much higher than reported hitherto for this type of solar cell. A simple, low temperature, low cost procedure is thus being proposed, which has the potential of attaining lower cost of production of heterojunction silicon solar cells.     

Realistic simulations of the July 1, 2011 severe wind event over the Buffalo Ridge Wind Farm

Severe winds from thunderstorm outflows pose a challenge to wind turbine arrays. They can cause significant power ramps and disruption in energy production. They can also cause extreme structural damage to turbines as was seen in the severe storm event over the Buffalo Ridge Wind Farm on July 1, 2011. At this southwestern Minnesota site, blades from multiple turbines broke away and a tower buckled in the intense winds. In this study, we attempt to characterize meteorological conditions over the Buffalo Ridge Wind Farm area during this event. The observational network included NEXRAD radars, automated surface observation stations and a wind profiler. Storm reports from the Storm Prediction Center and damage surveys provided additional insight to the in situ measurements. Even with these datasets, assessing wind speeds around turbine rotors is difficult. Thus, Weather Research and Forecasting model simulations of the event are carried out that consider current and anticipated future operational model setups. This work addresses model spatial resolution versus parameterization complexity. Parameterizations of the planetary boundary layer and microphysics processes are evaluated based on their impact on storm dynamics and the low‐level wind field. Results are also compared with the Wind Integration National Dataset, which utilizes data assimilation and an extensive continental domain. Enhanced horizontal resolution with simplistic parameterization helps increase resolved wind speeds and ramp intensity. Enhanced sophistication of microphysics parameterizations also helps increase resolved wind speeds, improve storm timing and structure and resolve higher values of turbulent kinetic energy in the lowest 1 km of the atmosphere. Copyright © 2017 John Wiley & Sons, Ltd.     

Automatic Classification of Cardiac Arrhythmias Based on Hybrid Features and Decision Tree Algorithm

Machine Intelligence Research - Accurate classification of cardiac arrhythmias is a crucial task because of the non-stationary nature of electrocardiogram (ECG) signals. In a life-threatening...     

Compatibilization of polyetherimide/liquid crystalline polymer blend using modified multiwalled carbon nanotubes and polyphosphazene as compatibilizers

In this study, compatibilizing ability of silicone carbide modified multiwalled carbon nanotube (MWCNT) and polyphosphazene for the incompatible polyetherimide/liquid crystalline polymer (LCP) blend was investigated in detail. From rheological study, it was evident that the viscosities of binary and ternary blends were lower than those of the neat polymers, which signifying the great ability of LCP as a processing aid. Field emission scanning electron microscopic analysis revealed that the addition of polyphosphazene and modified MWCNT, together, reduced the average domain size of LCP and improved the filler‐matrix adhesion. Measurement of surface energy from contact angle measurement also point towards the improved interfacial interaction, in presence of compatibilizers. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Fabrication of two sites hydrophobicity on cotton surface – a fluoropolymerization approach

Cotton fabric on both surfaces was coated with polymerization of fluoromonomer followed by adsorption of fluorosurfactant by a new technique admicellar polymerization to obtain durable hydrophobicity. Water repellence properties were determined in terms of simple drop test contact angles. The coating on cotton fabric exhibited the right water contact angle of 137.23° and left contact angle 138.35° (an average value of 137.79°). However, the durability of the coatings was decreased after simple home laundering with a decrease in water contact angle value. The surface morphology was evaluated by scanning electron microscopy before and after polymerization. Beside this chemical composition on the cotton, the surface was evaluated by EDS analysis to determine the number of fluorine moieties deposited on the cotton surface by this technique.     

Fabrication of fluoropolymer-modified hydrophobic functionalization of cotton fabric by admicellar polymerization

Herein, a hydrophobic polyfluoroacrylate adhered cotton fabric having a smart affair with water under oil, is developed using a simple surfactant-assisted polymerization technique commonly known as admicellar polymerization of low surface energy trifluoroethyl acrylate monomer. The hydrophobicity of the treated substrates was determined by the contact angle. The results show that the cotton fabric became hydrophobic. The surface investigation conducted by scanning electron microscopy (SEM) provided distinctive features of the untreated and treated fabric samples. The elementary analysis was also carried out on the substrate through energy dispersive X-ray to confirm the presence of hydrophobic groups. In addition to this, the hydrophobic cotton fabric shows excellent durability against home laundering and simple adhesive peel testing.