Doped oxides of cerium as inorganic colorants

The colour of inorganic colorants is based on metal ions such as cadmium, lead, chromium or cobalt, the majority of which are unfortunately potentially toxic. Thus, there is in a need to introduce alternative metal or metal oxides, which would be environmentally friendly and economically viable as a replacement for potentially toxic inorganic colorants. Rare earth-based colorants offer an additional opportunity for the development of optically pure colours. In this study, a replacement for potentially toxic colorants has been sought through the use of a rare earth metal ion, cerium. Appropriate doping of cerium oxides with molybdenum and iron gives an orange–red colorant. The conditions ideal for optimal colour have been standardised and the resultant colorant characterised through powder X-ray diffraction techniques, particle size measurement, etc. The colorants exhibit good hiding power and tinting strength.     

Remote sensing of phytoplankton functional types

The principal goal in early missions of satellite-borne visible spectral radiometry (ocean colour) was to create synoptic fields of phytoplankton biomass indexed as concentration of chlorophyll-a. In the context of climate change, a major application of the results has been in the modelling of primary production and the ocean carbon cycle. It is now recognised that a partition of the marine autotrophic pool into a suite of phytoplankton functional types, each type having a characteristic role in the biogeochemical cycle of the ocean, would increase our understanding of the role of phytoplankton in the global carbon cycle. At the same time, new methods have been emerging that use visible spectral radiometry to map some of the phytoplankton functional types. Here, we assess the state of the art, and suggest paths for future work.     

Supplementation of squalene attenuates experimentally induced myocardial infarction in rats

We have investigated the preventive effects of squalene against isoprenaline-induced myocardial infarction in male albino rats. Supplementation with squalene significantly prevented the isoprenaline-induced adverse changes in the levels of protein and glycoprotein components in plasma and heart tissue of experimental groups of rats. It exerted an antioxidant effect by inhibiting the isoprenaline-induced lipid peroxidation and by maintaining the level of non-enzymatic free radical-scavenger, reduced glutathione at near normalcy. Histopathological observations also confirmed the possible cardioprotective action of squalene by maintaining the normal architecture of the heart tissue. The results of the present investigation demonstrate that supplementation with squalene offers cardioprotection in experimental rats by its antioxidant and membrane- stabilizing properties.     

Strategies for stereocontrol at C1 or C2 in syntheses of α-glucosaminides

The C1 and C2 stereocenters of α-glucosaminides can be prepared by establishing the stereocenters in either order. For the former, a C2-azido glucosyl donor is prepared first, and the restraining effect of a 4,6-O-benzylidene ring is used to induce α-coupling. For the latter, the C1 linkage is prepared first by use of an n-pentenyl-manno-1,2-orthoester donor which ensures (a) clean α-coupling and (b) a convenient C2-ester. The C2-ester is replaced with a triflate leaving group, and nucleophilic displacement is effected by use of a hypervalent silicon azide.     

Heavy metal concentrations in fish,shellfish and fish products from internal markets of India vis-a-vis international standards

Heavy metals are an important group of chemical contaminants and food is the major vehicle for entry into the system. Fish constitute a major source of heavy metals in food. Concentration of heavy metals in commercially important species of fish, shellfish and fish products from fish markets in and around the Cochin area was evaluated using an atomic absorption spectrometer. The concentration ranges of Cd, Pb, Hg, Cr, As, Zn, Cu, Co, Mn, Ni, and Se in the samples were <0.07–1, <0.07–1.32, <0.05–2.31, <0.05 to 3.65, <0.1–4.14, 0.6 to 165, 0.15 to 24, <0.02 to 0.85, <0.08 to 9.2, <0.032–1.38 and; <0.03–1.35 mg/kg, respectively. The present study showed that different metals were present in the samples at different levels but within the maximum residual levels prescribed by the EU and USFDA and the fish and shellfish from these areas, in general, are safe for human consumption.     

The genes for butanol and acetone formation in Clostridium acetobutylicum ATCC 824 reside on a large plasmid whose loss leads to degeneration of the strain

Degeneration is the process whereby Clostridium acetobutylicum ATCC 824 loses the capacity to produce acetone and butanol after repeated vegetative transfers or in continuous culture. Two degenerate mutants (M5 and DG1) of C. acetobutylicum ATCC 824 do not contain the four genes (ctfA, ctfB, adc, and aad) for acetone and butanol formation. Strain ATCC 824 contains a 210-kb plasmid (pSOL1) which is absent in M5 and DG1. pSOL1 carries the four acetone and butanol formation genes. A restriction map of pSOL1 was constructed by using ApaI, SmaI, SstII, and NarI digestions. M5 and DG1 could be complemented for acetone and butanol formation by expressing the corresponding genes (ctfA, ctfB, and adc for acetone; aad for butanol) on the plasmid. Degeneration of this strain thus appears to be the result of pSOL1 loss.     

Grain Growth of Microtubes During Sintering in Semiconducting Ba3Ce3−xBixTi5Nb5O30 (x=0.5, 1.0, 2.0, and 3.0) Ceramics

Well grown microtubes of Ba₃Ce_{3− x} Bi _x Ti₅Nb₅O₃₀ ( x =0.5, 1.0, 2.0, and 3.0) have been observed in the sintered ceramics. The microtubes have octagonal shapes at the cylindrical ends, hollow cores with diameters of 2–3 μm, lengths over a few tens of micrometers and wall thickness of 0.5–1.0 μm. In morphology, the tubes are very straight and are apparently welded to each other on the sides. The tubular growth as well as increase of wall thickness is observed to be more with greater Bi content, but when Ce is fully substituted by Bi, the tubes have grown into solid rods without hollowness. The growth spirals at the ends of tubes as seen by scanning electron microscope indicate that growth takes place in the longitudinal direction of the tubes. Observation of growth spirals on grains of a sintered ceramic is unusual. In fact, such features are usually seen in liquid phase growth and, therefore, we propose here grain growth in partially fluid conditions. The phase identification by X-ray diffraction shows that the compound has a tetragonal tungsten bronze type structure. The resistivity measurements above room temperature indicate that these compounds are semiconductors and both resistivity and activation energy increase with Bi content.     

Scalar Variational Analysis of Fundamental Mode in Single-Mode Elliptical Core Fiber Using Super-Gaussian Approximation

We present detailed propagation characteristics of single-mode elliptical core fiber using scalar variational method with novel super-Gaussian approximation. Results obtained through this method for different aspect ratios matched excellently with those reported using other methods.