Determination of the Optimum NiS Fire Assay Parameters for Pt,Pd, and Rh in Automotive Exhaust Catalytic Converters

This work investigates the performance of the nickel sulfide fire assay (NiS-FA) for the pyrometallurgical analysis of platinum group elements (PGEs) from mixtures of automotive exhaust catalytic converters (e.g., gasoline, diesel, and diesel particular filter) by assessing the effects of various flux materials and reaction parameters on platinum, palladium, and rhodium recovery. Inductively coupled plasma mass spectrometry and atomic absorption spectroscopy (AAS) are used for the analysis of the NiS-FA beads. We found that the optimum recovery (at least 99.0%) was achieved with reaction of 11.5 g of flux (0.53 w/w ratio, sodium tetraborate:sodium carbonate), 1 g nickel, and 0.84 g sulfur (1.2 w/w ratio, Ni:S) per gram of sample for 90 min at 975°C. Reference standards (NIST SRM 2557) were used to compare efficiencies and identify the optimum conditions. The results are consistent with certified values and PGEs could be recovered within the 95% confidence level. The precision (<4.0% RSD) of all measurements, expressed as percentage relative standard deviation (SD), ranged up to 3.0%.     

Thermodynamic analysis of an existing coal-fired power plant for district heating/cooling application

In a conventional coal-fired power plant, which is only designed for electricity generation, 2/3 of fuel energy is wasted through stack gases and cooling water of condensers. This waste energy could be recovered by trigeneration; modifying the plants in order to meet district heating/cooling demand of their locations. In this paper, thermodynamical analysis of trigeneration conversion of a public coal-fired power plant, which is designed only for electricity generation, has been carried out. Waste heat potentials and other heat extraction capabilities have been evaluated. Best effective steam extraction point for district heating/cooling system; have been identified by conducting energetic and exergetic performance analyses. Analyses results revealed that the low-pressure turbine inlet stage is the most convenient point for steam extraction for the plant analyzed.     

Numerical Determination of Thermal-Diffusivity Coefficients of Some Nematic Liquid Crystals <Emphasis Type="Italic">in Situ</Emphasis>

In this study, a new experimental study has been implemented to determine the thermal-diffusivity parameters of industrial nematic liquid crystals, 4-pentyl-4′-cyanobiphenyl (5CB) and 4′-octyl-4-cyanobiphenyl (8CB), both numerically by using the finite difference method (FDM) for forward solutions and experimentally by measuring the temperature variation with time and position. The most important parts of this experimental study are the heating system and the liquid crystal cell, which were constructed in-house to determine the temperatures of the materials in situ. Four different positions for local measurements have been studied, and the optimum graph of this variation has been determined. The experimental and theoretical results of this study are consistent with previous measurements performed by means of a conventional thermal technique.     

Floc settling characteristics of turbid water coagulated with moringa oleifera seeds

The results of studies into the particle aggregations and settling rates of flocs from turbid water (kaolin suspension) with turbidities varying from 50 to 550 NTU coagulated with Moringa oleifera seeds are presented. The results of the laboratory based study showed that the maximum value of the “apparent aggregation rate”, K _app,increased with increase in initial turbidity. K _app was found to be 0.000778 for low turbidity (50 NTU) and 0.00654 for high turbidity (550 NTU). The velocity gradient for rapid mix at the maximum K _app was found to be constant at 443/sec for all turbidities. Settling rate of floc coagulated with Moringa oleifera seed was dependent on the initial turbidity of the water sample. For water with initial turbidity of 50 NTU, 30% to 70% turbidity was removed between 60 and 210 minutes, while for high turbidity of 400 to 550 NTU, 80% to 95% turbidity removal occurred between 60 and 150 minutes.     

Bench Scale Studies for Pretreatment of Sanitary Landfill Leachate with Moringa Oleifera Seeds Extract

A laboratory study using a bench scale model of two unit operations involved processes of coagulation (using Moringa oleifera seeds as a natural coagulant) and flocculation-sedimentation have been adopted to treat the leachate from Air Hitam Sanitary Landfill at Puchong in Malaysia. The results of this study has shown, that M. oleifera has a potential for the removal of heavy metals from the leachate, and may be used as a pre-treatment stage for biological treatment to eliminate a portion of the toxic heavy metals, which limit the activity of micro-organisms in the leachate.     

Investigation of Arsenic and Cadmium Contents in Rice Samples in Turkey by Electrothermal Atomic Absorption Spectrometry

Electrothermal atomic absorption spectrometry was the method used for the direct determination of arsenic and cadmium traces in rice samples. The optimum experimental conditions were investigated in the presence of a Pd/Mg(NO₃)₂ modifier. For arsenic and cadmium, the detection limits were 6.1 and 0.7 μg?kg^?1, whereas the characteristic concentrations were 1.33 and 0.067 μg?L^?1, respectively. For the validation of the method, the concentrations of As and Cd in IRMM-804 rice flour and GBW-08503 wheat flour certified reference materials were determined after microwave-assisted digestion of the samples. The results were found within the uncertainty limits of the certified values. The different 25 rice samples sold in Turkey were digested using a microwave system and then analyzed. The average (range) As and Cd concentrations of all samples were 0.0985 (0.0204–0.1708) and 0.0314 (0.0084–0.0775) mg?kg^?1, respectively. The arsenic and cadmium results were at acceptable levels. The average As and Cd amounts taken from rice are below the provisional tolerable weekly intake levels accepted by the World Health Organization. The distribution of analyte concentrations in some selected rice packages was investigated. The concentrations of both analytes were changed in a wide range even in the same packages.     

A beam search-based algorithm and evaluation of scheduling approaches for flexible manufacturing systems

This paper presents a new algorithm for the flexible manufacturing system (FMS) scheduling problem. The proposed algorithm is a heuristic based on filtered beam search. It considers finite buffer capacity, routing and sequence flexibilities and generates machine and automated guided vehicle (AGV) schedules for a given scheduling period. A new deadlock resolution mechanism is also developed as an integral part of the proposed algorithm. The performance of the algorithm is compared with several machine and AGV dispatching rules using mean flow time, mean tardiness and makespan criteria. It is also used to examine the effects of scheduling factors (i.e., machine and AGV load levels, routing and sequence flexibilities, etc.) on the system performance. The results indicate that the proposed scheduling algorithm yields considerable improvements in system performance over dispatching rules under a wide variety of experimental conditions.     

Regional Evacuation Modeling System (REMS): A decision support system for emergency area evacuations

In this paper we present a decision support system being developed at the University of Florida. The system is a PC-based software package that is capable of testing different emergency scenarios due to hurricanes, chemical accidents or nuclear accidents. The underlying models are optimization models based on a regional transportation network. One of the most significant aspects of the software is its ability to handle time dimension of the problem explicitly. It is this aspect of REMS that makes incorporation at any time of road blockages due to the presence of extremely hazardous substances or inundation of roads due to accidents or flooding possible in evacuation scenarios tested. The software has the ability to animate the evacuation process in time and display the flow of traffic on the links of the transportation network in a time-lapsed manner with color codes. Additionally REMS is also capable to animate the progress of the plume exposure pathway of an extremely hazardous substances as it evolves in time onto the evacuation network and to display the dynamic vehicle flow in time simultaneously.     

Decomposition of process damping ratios and verification of process damping model for chatter vibration

In the previous study, by the same authors, titled “A new process damping model (PDM) for chatter vibration (Measurement, 44 (8) (2011) 1342–1348)”, a new approach has been presented for obtaining process damping ratios (PDRs). This PDM has been constituted on the basis of the shear angle (φ)$(\phi )$ oscillations of the cutting tool and the alteration of the penetration forces when they penetrate into the wavy surface. Variation and quantity of PDR are predicted by reverse running analytical calculation procedure of traditional Stability Lobe Diagrams (SLDs). In this study, firstly, how the PDM in previous study results with different materials such as AISI-1050 and Al-7075 are examined. Then, two problems are solved: how much of the total PDR of cutting system is caused by the tool penetration and how much is caused by (φ)$(\phi )$ oscillation? Finally, verification of PDR values and PDM are performed by energy equations.     

Development of empirical models for performance evaluation of UASB reactors treating poultry manure wastewater under different operational conditions

A nonlinear modeling study was carried out to evaluate the performance of UASB reactors treating poultry manure wastewater under different organic and hydraulic loading conditions. Two identical pilot scale up-flow anaerobic sludge blanket (UASB) reactors (15.7 L) were run at mesophilic conditions (30-35 degrees C) in a temperature-controlled environment with three hydraulic retention times (theta) of 15.7, 12 and 8.0 days. Imposed volumetric organic loading rates (L(V)) ranged from 0.65 to 4.257 kg COD/(m(3) day). The pH of the feed varied between 6.68 and 7.82. The hydraulic loading rates (L(H)) were controlled between 0.105 and 0.21 m(3)/(m(2)day). The daily biogas production rates ranged between 4.2 and 29.4 L/day. High volumetric COD removal rates (R(V)) ranging from 0.546 to 3.779 kg COD(removed)/(m(3)day) were achieved. On the basis of experimental results, two empirical models having a satisfactory correlation coefficient of about 0.9954 and 0.9416 were developed to predict daily biogas production (Q(g)) and effluent COD concentration (S(e)), respectively. Findings of this modeling study showed that optimal COD removals ranging from 86.3% to 90.6% were predicted with HRTs of 7.9, 9.5, 11.2, 12.6, 13.7 and 14.3 days, and L(V) of 1.27, 1.58, 1.78, 1.99, 2.20 and 2.45 kg COD/(m(3)day) for the corresponding influent substrate concentrations (S(i)) of 10,000, 15,000, 20,000, 25,000, 30,000 and 35,000 mg/L, respectively.