Dielectric relaxation and conduction mechanism of complex perovskite Ca0.90Sr0.10Cu3Ti3.95Zn0.05O12 ceramic

In this work, Sr and Zn co-doped calcium copper titanate having nominal formula Ca_0.90Sr_0.10Cu₃Ti_3.95Zn_0.05O₁₂ has been synthesized and systematically studied for structure, dielectric and electrical properties. The phase purity of the prepared composition has been confirmed by X-ray diffraction (XRD) pattern and various structural parameters are presented here with Rietveld refinement data. The Scanning electron microscopy (SEM) image revealed the presence of homogeneous fine-grained microstructure investigated in the prepared ceramic. The impedance data well fitted with 2 R-CPE model confirmed the non-ideality of the system. Dielectric studies have shown the existence of two relaxation processes in low and high frequency domains. Low frequency dielectric response proposed as a combination of Maxwell-Wagner relaxation and intrinsic defect (V_o⁺⁺) while high frequency behavior has been interpreted in terms of polaronic relaxation caused by hopping process of an electron between Ti³⁺ and Ti⁴⁺ states. The frequency dependent behavior of conductivity has been well fitted to Dong’s model and interpreted in term of Overlapping Large Polaron Tunneling (OLPT) mechanism. The various parameters; relaxation angular frequency (ω₁) of Debye process, ionic hopping frequency (ω₂₎, dc conductivity (σ_o), cole- cole parameter (α) and frequency exponent (s) have been determined by Dong’s Model fitting.     

Novel Low-Overhead Operand Isolation Techniques for Low-Power Datapath Synthesis

Power consumption in datapath modules due to redundant switching is an important design concern for high-performance applications. Operand isolation schemes that reduce this redundant switching incur considerable overhead in terms of delay, power, and area. This paper presents novel operand isolation techniques based on supply gating that reduce overheads associated with isolating circuitry. The proposed schemes also target leakage minimization and additional operand isolation at the internal logic of datapath to further reduce power consumption. We integrate the proposed techniques and power/delay models to develop a synthesis flow for low-power datapath synthesis. Simulation results show that the proposed operand isolation techniques achieve at least 40% reduction in power consumption compared to original circuit with minimal area overhead (5%) and delay penalty (0.15%)     

Instability of plane compressible gas sheets

Summary The instability of a plane compressible gas sheet in a quiescent viscous liquid medium of infinite expanse has been studied. It is found that there exist two unstable modes of disturbances, sinuous and varicose. For temporal instability, sinuous disturbance is stable if the gas Weber number, defined as the ratio of aerodynamic to capillary forces, is less than unity, varicose mode controls the instability process except for large Weber numbers when both modes become equally important, and gas compressibility effect always enhances instability development and induces an additional range of unstable wave numbers. For spatial-temporal evolution of disturbances, it is found that convective instability does not exist at all and the instability of plane gas sheets is always absolute in nature, which is strikingly opposite to the instability of plane liquid sheets. The absolutely unstable disturbance is found always temporally growing, although it may be spatially growing or decaying depending on flow conditions. Gas compressibility always enhances and liquid viscosity damps out both the temporal and the spatial part of absolute instability growth rate. Although the Weber number always promotes the temporal growth rate of absolute instability, it has a dual effect of enhancing and inhibiting the spatial growth rate.     

Motion planning in uncertain environments with vision-like sensors

In this work we present a methodology for intelligent path planning in an uncertain environment using vision-like sensors, i.e., sensors that allow the sensing of the environment non-locally. Examples would include a mobile robot exploring an unknown terrain or a micro-UAV navigating in a cluttered urban environment. We show that the problem of path planning in an uncertain environment, under certain assumptions, can be posed as the adaptive optimal control of an uncertain Markov decision process, characterized by a known, control-dependent system, and an unknown, control-independent environment. The strategy for path planning then reduces to computing the control policy based on the current estimate of the environment, also known as the “certainty-equivalence” principle in the adaptive control literature. Our methodology allows the inclusion of vision-like sensors into the problem formulation, which, as empirical evidence suggests, accelerates the convergence of the planning algorithms. Further we show that the path planning and estimation problems, as formulated in this paper, possess special structure which can be exploited to significantly reduce the computational burden of the associated algorithms. We apply this methodology to the problem of path planning of a mobile rover in a completely unknown terrain.     

Sol–gel derived polycrystalline Cr1.8Ti0.2O3 thick films for alcohols sensing application

The powder sample of Cr_1.8Ti_0.2O₃ (CTO) was obtained by a sol–gel method. The thick films were developed on identical ceramic tubes of 4 mm length comprising of two Au-electrodes and printing an eight-layer film prepared by mixing CTO with glass powder and -terpinol as an organic vehicle. X-ray powder diffraction (XRD) patterns showed the formation of a single phase. The scanning electron microscope (SEM) images of the ceramic sensor treated at 850 °C revealed that the grain size was larger than 400 nm for the individual isolated grains on the surface, and the agglomerated dense spheroidal platelets had the size of 1–4 μm in diameter. The AC impedance measurement in ambient air showed that the resistance decreased nearly by two orders of magnitude with an increase in temperature in the range of 400–600 °C for both the powder sample and the thick film, and the activation energy E_a derived from the measurement was found to be 0.35 and 0.36 eV for the powder and the film, respectively. The films were exposed to various concentrations of alcohols (0.4–1.2 ppm of methanol and 1.0–5.0 ppm of ethanol), followed by determination of sensor response, sensitivity and reversibility and reproducibility. The origin of the gas response was attributed to the surface reaction of R-OH (R = methyl and ethyl group) with O⁻_(ads) to form adsorbed R-CHO, which was desorbed as a gas at 400 °C after the sensor departing from the gas.     

Device-Aware Yield-Centric Dual-Vt Design Under Parameter Variations in Nanoscale Technologies

Dual-V_t design technique has proven to be extremely effective in reducing subthreshold leakage in both active and standby mode of operation of a circuit in submicrometer technologies. However, aggressive scaling of technology results in different leakage components (subthreshold, gate and junction tunneling) to become significant portion of total power dissipation in CMOS circuits. High-V_t devices are expected to have high junction tunneling current (due to stronger halo doping) compared to low-V_t devices, which in the worst case can increase the total leakage in dual-V_t design. Moreover, process parameter variations (and in turn V_t variations) are expected to be significantly high in sub-50-nm technology regime, which can severely affect the yield. In this paper, we propose a device aware simultaneous sizing and dual-V_t design methodology that considers each component of leakage and the impact of process variation (on both delay and leakage power) to minimize the total leakage while ensuring a target yield. Our results show that conventional dual-V_t design can overestimate leakage savings by 36% while incurring 17% average yield loss in 50-nm predictive technology. The proposed scheme results in 10%-20% extra leakage power savings compared to conventional dual-V_t design, while ensuring target yield. This paper also shows that nonscalability of the present way of realizing high-V_t devices results in negligible power savings beyond 25-nm technology. Hence, different dual-V_t process options, such as metal gate work function engineering, are required to realize high-performance and low-leakage dual-V_t designs in future technologies.     

Determination of the polymer‐solvent contact angle by the capillary raising curve,applied to the field of supports for homogeneous catalysts

A comprehension of the phenomenon that controls the diffusion of an organic solvent to the pores of a polymeric matrix is fundamental for optimizing the operating conditions to distribute a homogeneous catalyst, which has to be supported on it. The traditional sessile drop method is impossible to use when a high polymer‐solvent affinity exists. In this case, a different determination technique, similar to the Wilhelmy static mode method and based on the direct observation of the capillary raising curve of the solvent on the polymeric surface, has been set together with an experimental apparatus specifically built to perform measurements at a desired temperature and atmosphere. Such a technique has been demonstrated to be easy and promising for differentiating the behavior of different polyolefins [polypropylene (PP), high density polyethylene (HDPE), heterophasic copolymers (COPO)] at equal solvent and different temperatures. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Alumina supported MoO3: an efficient and recyclable catalyst for selective oxidation of tertiary nitrogen compounds to N-oxides using anhydrous TBHP as oxidant under mild reaction conditions

Alumina-supported MoO₃ was found to be an efficient heterogeneous and recyclable catalyst for the oxidation of tertiary nitrogen compounds to N-oxides in excellent yields using anhydrous t-BuOOH as oxidant under mild reaction conditions.     

Computing with subthreshold leakage: device/circuit/architecture co-design for ultralow-power subthreshold operation

This paper presents a novel design methodology for ultralow-power design using subthreshold leakage as the operating current (suitable for medium frequency of operation: tens to hundreds of millihertz). Standard design techniques suitable for super-threshold design can be used in the subthreshold region. However, in this study, it has been shown that a complete co-design at all levels of hierarchy (device, circuit, and architecture) is necessary to reduce the overall power consumption while achieving acceptable performance (hundreds of millihertz) in the subthreshold regime of operation. Simulation results of co-design on a five-tap finite-impulse-response filter shows /spl sim/2.5/spl times/ improvement in throughput at iso-power compared to a conventional design.     

Ionic liquid promoted an improved synthesis of 3,4-dihydropyrimidinones using [bmim]BF4 immobilized Cu (II) acetylacetonate as recyclable catalytic system

An improved method for the synthesis of 3,4-dihydropyrimidinones by one pot cyclocondensation of aldehyde, β-dicarbonyl compound and urea with significant enhancement in reaction rates using room temperature ionic liquid [bmim] BF₄ immobilized Cu(acac)₂ as recyclable catalytic system is described.