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991.
Haotian Wang Jian Sun Hong Ding Ganlin Shan Zhuang Chang 《Journal of Failure Analysis and Prevention》2017,17(6):1182-1190
Performance degradation modeling plays an important role in prognostics and health management of mechanical system. Influenced by the complex structure of the hydraulic pump and the limited experiment standards, it is hard to establish an appropriate performance degradation model. To fulfill current requirements, a method for establishing the performance degradation model based on accelerated experiment is proposed. In order to describe the general trend of the degradation, the double-stress exponential model is firstly established as the theoretical degradation model. On this basement, combined with the characteristics of the experiment, the accelerating coefficient is settled; meanwhile, the procedures for assuring the model parameters are presented. Furthermore, based on the accelerated experiment of the hydraulic pump under various stresses, the performance degradation model is finally established. Result of the experimental analysis indicates that the proposed method is applicable and the presented model is effective to measure the performance degradation of pump. 相似文献
992.
Phase Separation Derived Core/Shell Structured Cu11V6O26/V2O5 Microspheres: First Synthesis and Excellent Lithium‐Ion Anode Performance with Outstanding Capacity Self‐Restoration 下载免费PDF全文
Jian Pei Gang Chen Qiang Zhang Changfeng Bie Jingxue Sun 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(17)
Novel amorphous vanadium oxide coated copper vanadium oxide (Cu11V6O26/V2O5) microspheres with 3D hierarchical architecture have been successfully prepared via a microwave‐assisted solution method and subsequent annealing induced phase separation process. Pure Cu11V6O26 microspheres without V2O5 coating are also obtained by an H2O2 solution dissolving treatment. When evaluated as an anode material for lithium‐ion batteries (LIBs), the as‐synthesized hybrid exhibits large reversible capacity, excellent rate capability, and outstanding capacity self‐recovery. Under the condition of high current density of 1 A g?1, the 3D hierarchical Cu11V6O26/V2O5 hybrid maintains a reversible capacity of ≈1110 mA h g?1. Combined electrochemical analysis and high‐resolution transmission electron microscopy observation during cycling reveals that the amorphous V2O5 coating plays an important role on enhancing the electrochemical performances and capacity self‐recovery, which provides an active amorphous protective layer and abundant grain interfaces for efficient inserting and extracting of Li‐ion. As a result, this new copper vanadium oxide hybrid is proposed as a promising anode material for LIBs. 相似文献
993.
Sensitive Detection of Carcinoembryonic Antigen Using Stability‐Limited Few‐Layer Black Phosphorus as an Electron Donor and a Reservoir 下载免费PDF全文
Jian Peng Youqun Lai Yuanyuan Chen Jun Xu Liping Sun Jian Weng 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(15)
The instability of few‐layer black phosphorus (FL‐BP) hampers its further applications. Here, it can be demonstrated that the instability of FL‐BP can also be the advantage for application in biosensor. First, gold nanoparticle/FL‐BP (BP‐Au) hybrid is facilely synthesized by mixing Au precursor with FL‐BP. BP‐Au shows outstanding catalytic activity (K = 1120 s?1 g?1) and low activation energy (17.53 kJ mol?1) for reducing 4‐nitrophenol, which is attributed to the electron‐reservoir and electron‐donor properties of FL‐BP, and synergistic interaction of Au nanoparticles and FL‐BP. Oxidation of FL‐BP after catalytic reaction is further confirmed by transmission electron microscope, X‐ray photoelectron spectroscopy, and zeta potentials. Second, the catalytic activity of BP‐Au can be reversibly switched from “inactive” to “active” upon treatment with antibody and antigen in solution, thus providing a versatile platform for label‐free colorimetric detection of biomarkers. The sensor shows a wide detection range (1 pg mL?1 to –10 µg mL?1), high sensitivity (0.20 pg mL?1), and selectivity for detecting carcinoembryonic antigen (CEA). Finally, the biosensor has been used to detect CEA in colon and breast cancer clinical samples with satisfactory results. Therefore, the instability of BP can also be the advantage for application in detecting cancer biomarker in clinic. 相似文献
994.
Near‐Infrared Photodetectors Based on MoTe2/Graphene Heterostructure with High Responsivity and Flexibility 下载免费PDF全文
Wenzhi Yu Shaojuan Li Yupeng Zhang Weiliang Ma Tian Sun Jian Yuan Kai Fu Qiaoliang Bao 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(24)
2D transition metal dichalcogenides (TMDCs) have attracted considerable attention due to their impressively high performance in optoelectronic devices. However, efficient infrared (IR) photodetection has been significantly hampered because the absorption wavelength range of most TMDCs lies in the visible spectrum. In this regard, semiconducting 2D MoTe2 can be an alternative choice owing to its smaller band gap ≈1 eV from bulk to monolayer and high carrier mobility. Here, a MoTe2/graphene heterostructure photodetector is demonstrated for efficient near‐infrared (NIR) light detection. The devices achieve a high responsivity of ≈970.82 A W?1 (at 1064 nm) and broadband photodetection (visible‐1064 nm). Because of the effective photogating effect induced by electrons trapped in the localized states of MoTe2, the devices demonstrate an extremely high photoconductive gain of 4.69 × 108 and detectivity of 1.55 × 1011 cm Hz1/2 W?1. Moreover, flexible devices based on the MoTe2/graphene heterostructure on flexible substrate also retains a good photodetection ability after thousands of times bending test (1.2% tensile strain), with a high responsivity of ≈60 A W?1 at 1064 nm at V DS = 1 V, which provides a promising platform for highly efficient, flexible, and low cost broadband NIR photodetectors. 相似文献
995.
Surface Energy and Surface Stability of Ag Nanocrystals at Elevated Temperatures and Their Dominance in Sublimation‐Induced Shape Evolution 下载免费PDF全文
Long‐Bing He Lei Zhang Xiao‐Dong Tan Lu‐Ping Tang Tao Xu Yi‐Long Zhou Zhan‐Yong Ren Yun Wang Chun‐Yu Teng Li‐Tao Sun Jian‐Feng Nie 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(27)
The surface energy and surface stability of Ag nanocrystals (NCs) are under debate because the measurable values of the surface energy are very inconsistent, and the indices of the observed thermally stable surfaces are apparently in conflict. To clarify this issue, a transmission electron microscope is used to investigate these problems in situ with elaborately designed carbon‐shell‐capsulated Ag NCs. It is demonstrated that the {111} surfaces are still thermally stable at elevated temperatures, and the victory of the formation of {110} surfaces over {111} surfaces on the Ag NCs during sublimation is due to the special crystal geometry. It is found that the Ag NCs behave as quasiliquids during sublimation, and the cubic NCs represent a featured shape evolution, which is codetermined by both the wetting equilibrium at the Ag–C interface and the relaxation of the system surface energy. Small Ag NCs (≈10 nm) no longer maintain the wetting equilibrium observed in larger Ag NCs, and the crystal orientations of ultrafine Ag NCs (≈6 nm) can rotate to achieve further shape relaxation. Using sublimation kinetics, the mean surface energy of Ag NCs at 1073 K is calculated to be 1.1–1.3 J m?2. 相似文献
996.
Drug Delivery: One‐Step Microfluidic Synthesis of Nanocomplex with Tunable Rigidity and Acid‐Switchable Surface Charge for Overcoming Drug Resistance (Small 9/2017) 下载免费PDF全文
997.
Solar Cells: Multidimensional Anodized Titanium Foam Photoelectrode for Efficient Utilization of Photons in Mesoscopic Solar Cells (Small 34/2017) 下载免费PDF全文
998.
Multicolor Photo‐Crosslinkable AIEgens toward Compact Nanodots for Subcellular Imaging and STED Nanoscopy 下载免费PDF全文
Xiaofeng Fang Xuanze Chen Rongqin Li Zhihe Liu Haobin Chen Zezhou Sun Bo Ju Yifei Liu Sean Xiao‐An Zhang Dan Ding Yujie Sun Changfeng Wu 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(41)
Aggregation induced emission (AIE) has attracted considerable interest for the development of fluorescence probes. However, controlling the bioconjugation and cellular labeling of AIE dots is a challenging problem. Here, this study reports a general approach for preparing small and bioconjugated AIE dots for specific labeling of cellular targets. The strategy is based on the synthesis of oxetane‐substituted AIEgens to generate compact and ultrastable AIE dots via photo‐crosslinking. A small amount of polymer enriched with oxetane groups is cocondensed with most of the AIEgens to functionalize the nanodot surface for subsequent streptavidin bioconjugation. Due to their small sizes, good stability, and surface functionalization, the cell‐surface markers and subcellular structures are specifically labeled by the AIE dot bioconjugates. Remarkably, stimulated emission depletion imaging with AIE dots is achieved for the first time, and the spatial resolution is significantly enhanced to ≈95 nm. This study provides a general approach for small functional molecules for preparing small sized and ultrastable nanodots. 相似文献
999.
Large‐Scale Fabrication of Core–Shell Structured C/SnO2 Hollow Spheres as Anode Materials with Improved Lithium Storage Performance 下载免费PDF全文
Yong Cheng Qian Li Chunli Wang Lianshan Sun Zheng Yi Limin Wang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(47)
Due to the high theoretical capacity as high as 1494 mAh g?1, SnO2 is considered as a potential anode material for high‐capacity lithium–ion batteries (LIBs). Therefore, the simple but effective method focused on fabrication of SnO2 is imperative. To meet this, a facile and efficient strategy to fabricate core–shell structured C/SnO2 hollow spheres by a solvothermal method is reported. Herein, the solid and hollow structure as well as the carbon content can be controlled. Very importantly, high‐yield C/SnO2 spheres can be produced by this method, which suggest potential business applications in LIBs field. Owing to the dual buffer effect of the carbon layer and hollow structures, the core–shell structured C/SnO2 hollow spheres deliver a high reversible discharge capacity of 1007 mAh g?1 at a current density of 100 mA g?1 after 300 cycles and a superior discharge capacity of 915 mAh g?1 at 500 mA g?1 after 500 cycles. Even at a high current density of 1 and 2 A g?1, the core–shell structured C/SnO2 hollow spheres electrode still exhibits excellent discharge capacity in the long life cycles. Consideration of the superior performance and high yield, the core–shell structured C/SnO2 hollow spheres are of great interest for the next‐generation LIBs. 相似文献
1000.
Mesoporous NiS2 Nanospheres Anode with Pseudocapacitance for High‐Rate and Long‐Life Sodium‐Ion Battery 下载免费PDF全文
Ruimin Sun Sijie Liu Qiulong Wei Jinzhi Sheng Shaohua Zhu Qinyou An Liqiang Mai 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(39)
It is of great importance to exploit electrode materials for sodium‐ion batteries (SIBs) with low cost, long life, and high‐rate capability. However, achieving quick charge and high power density is still a major challenge for most SIBs electrodes because of the sluggish sodiation kinetics. Herein, uniform and mesoporous NiS2 nanospheres are synthesized via a facile one‐step polyvinylpyrrolidone assisted method. By controlling the voltage window, the mesoporous NiS2 nanospheres present excellent electrochemical performance in SIBs. It delivers a high reversible specific capacity of 692 mA h g?1. The NiS2 anode also exhibits excellent high‐rate capability (253 mA h g?1 at 5 A g?1) and long‐term cycling performance (319 mA h g?1 capacity remained even after 1000 cycles at 0.5 A g?1). A dominant pseudocapacitance contribution is identified and verified by kinetics analysis. In addition, the amorphization and conversion reactions during the electrochemical process of the mesoporous NiS2 nanospheres is also investigated by in situ X‐ray diffraction. The impressive electrochemical performance reveals that the NiS2 offers great potential toward the development of next generation large scale energy storage. 相似文献