Influence of Cl-, Br-, NO 3 - and SO 4 2- ions on the corrosion behaviour of 6061 Al alloy

The effects of anions like Cl^-, Br^-, NO ₃ ^- and SO ₄ ^2- on the anodic dissolution of the monolithic Al 6061 alloy have been investigated at neutral pH through immersion testing and electrochemical techniques like potentiodynamic polarization and a.c. impedance spectroscopy. Scanning electron microscopy was employed to characterize the corroded surface and to observe the extent of pitting in different media. From the evaluated corrosion parameters it was found that the dissolution of the matrix was extensively reduced in presence of aqueous solutions containing Br^-, NO ₃ ^- and SO ₄ ^2- ions while Cl^- ions aggravated corrosion by penetrating into the barrier oxide film on the surface of the material. Pronounced effect of pitting was observed in presence of Cl^- and the level of pitting in NO ₃ ^- and Br^- were mild. In presence of SO ₄ ^2- ions passivity was extended over a wide potential range and breakdown of passivity occurs when the material was polarized beyond pitting potential. The departure of capacitive behaviour towards resistive behaviour was clearly observed through impedance measurements when investigations were conducted in Cl^- media and in presence of the other electrolytes. Corrosion rates were, however, controlled during prolonged exposure in the electrolytic media, specially in case of chloride media, due to the predominance of film repair kinetics.     

Benchmarking nanotechnology for high-performance and low-power logic transistor applications

Recently there has been tremendous progress made in the research of novel nanotechnology for future nanoelectronic applications. In particular, several emerging nanoelectronic devices such as carbon-nanotube field-effect transistors (FETs), Si nanowire FETs, and planar III-V compound semiconductor (e.g., InSb, InAs) FETs, all hold promise as potential device candidates to be integrated onto the silicon platform for enhancing circuit functionality and also for extending Moore's Law. For high-performance and low-power logic transistor applications, it is important that these research devices are frequently benchmarked against the existing Si logic transistor data in order to gauge the progress of research. In this paper, we use four key device metrics to compare these emerging nanoelectronic devices to the state-of-the-art planar and nonplanar Si logic transistors. These four metrics include: 1) CV/I or intrinsic gate delay versus physical gate length L/sub g/; 2) energy-delay product versus L/sub g/; 3) subthreshold slope versus L/sub g/; and 4) CV/I versus on-to-off-state current ratio I/sub ON//I/sub OFF/. The results of this benchmarking exercise indicate that while these novel nanoelectronic devices show promise and opportunities for future logic applications, there still remain shortcomings in the device characteristics and electrostatics that need to be overcome. We believe that benchmarking is a key element in accelerating the progress of nanotechnology research for logic transistor applications.     

Studies on the Reduction of Coefficient of Variation: A Case Study

In a spinning mill, yarn is the final product. Linear density expressed in terms of count is one of the important characteristics of yarn. Because variability of textile strands increases as the linear density increases, the variability in the count is often measured in terms of coefficient of variation (CV)%. The yarn with a high CV% of count leads to a higher end breakage rate during the spinning and subsequent weaving/knitting operations, and consequently, results in lesser productivity and poorer appearance quality of the woven/knitted fabric. When this woven/knitted fabric is dyed, uneven shades are generated. Because the production of yarn involves processing of raw cotton in multimachines at multistages, possible sources that lead to a high CV% of count are many. Enrick's (1960) analysis procedure, which is based on the modification of the range method for analysis of variance, is used conventionally for detecting the stages where excessive “between-machine” differences are present. When the CV% of count is inflated due to the generation of systematic variation in any machine or introduction of high variability by any machine, this inflation remains undetected when using Enrick's procedure. The case study presented here demonstrates that a step-by-step analysis of linear densities of different stage-outputs starting from yarn to card sliver, using appropriate nested design models along with Duncan's multiple range test, is very useful in detecting all possible sources of a high CV% of count of yarn.     

Synthesis and Optical Studies of Superconducting MgB2 Thin Films

Synthesis and optical transmission of MgB₂ thin films on optically transparent glass are reported. In the 400–1000 nm regime as deposited films show high metallic reflectivity and very little transmission. After deposition, the films were annealed ex situ and rendered superconducting with T _c of 38 K, approaching that of the bulk material. The reaction conditions where quite soft ∼10 min at 550°C. The optical absorption coefficient, α and photon energy, E followed a Tauc-type behavior, = _T (E - E_g )(\alpha E)^{1/2} = \beta _T (E - E_{\rm g} ). The band gap (E _g) was observed to peak at 2.5 eV; but, the slope parameter β _T behaved monotonically with reaction temperature. Our results indicate that an intermediate semiconducting phase is produced before the formation of the superconducting phase; also optical measurements provide valuable information in monitoring the synthesis of MgB₂ from its metallic constituents. In addition these films have interesting optical properties that may be integrated into optoelectronics.     

Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts

Polyurethane (PU) recycling is a topic of growing interest due to the increasing amount of polyurethane waste. The main purpose of polyurethane chemical recycling is to recover the starting polyol. In this study, a method of polyurethane thermochemical recycling, glycerolysis by means of crude glycerin, is proposed. This work presents a comparative study of commercial catalysts used in order to accelerate the decomposition process, namely triethylamine (TEA), potassium acetate (KAc), 1,4‐diazabicyclo[2.2.2]octane (DABCO), sodium hydroxide (NaOH), dibutyltin dilaurate (DbDl), and stannous octoate (StOc).The effect of used catalyst on the chemical structure and rheological properties was studied. The type of catalyst does not have significant influence on the chemical structure, but causes different course of reaction: split‐ and single‐phase in applied conditions. Glycerolysates were measured by Brookfield Rheometer. It was found that repolyols can be described by the Herschel–Bulkely mathematical model in the best accuracy. The investigation showed that the rheological behavior of glycerolysates depended on the catalyst used in glycerolysis process. POLYM. ENG. SCI., 57:891–900, 2017. © 2016 Society of Plastics Engineers     

Development of Multi Micro Manipulation System Using IPMC Micro Grippers

This paper presents a new design of multi micro manipulation system using ionic polymer metal composite (IPMC) micro grippers for robotic micro assembly where IPMC is used as a light weight actuator for developing the micro grippers. It has the potential of large displacement, low mass force generation and misalignment compensation ability during micro manipulation. These capabilities are utilized for handling of miniature parts like pegs. The analysis of IPMC micro gripper and manipulator are carried out for developing a multi micro manipulation system that can handle pegs in micro assembly operation for shifting one to another hole position in a large work space (100 mm × 100 mm). By developing a prototype, it is demonstrated that IPMC based micro grippers are capable of handling the peg-in-hole assembly tasks in a multi micro manipulation system.     

Predictive Thermal Inactivation Model for Effects and Interactions of Temperature, NaCl, Sodium Pyrophosphate, and Sodium Lactate on Listeria monocytogenes in Ground Beef

The effects and interactions of heating temperature (60 °C to 73.9 °C), salt (0.0 % to 4.5 %?w/v), sodium pyrophosphate (0.0 % to 0.5 %?w/v), and sodium lactate (0.0 % to 4.5 %?w/v) on the heat resistance of a five-strain mixture of Listeria monocytogenes in 75 % lean ground beef were examined. Meat samples in sterile filtered stomacher bags were heated in a temperature controlled waterbath to determine thermal death times. The recovery medium was tryptic soy agar supplemented with 0.6 % yeast extract and 1 % sodium pyruvate. Weibull survival functions were employed to model the primary survival curves. Then, survival curve-specific estimated parameter values obtained from the Weibull model were used for determining a secondary model. The results indicate that temperature and salt have a large impact on the inactivation kinetics of L. monocytogenes, while sodium lactate (NaL) has an impact in the presence of salt. The model presented in this paper for predicting inactivation of L. monocytogenes can be used as an aid in designing lethality treatments meant to control the presence of this pathogen in ready-to-eat products.     

Design and Characterization of a W-Band Folded-Waveguide Slow-Wave Structure

A single-section slow-wave structure for a W-band folded-waveguide traveling-wave tube with operating bandwidth of around 4% was designed for delivering the output power of 50 W at the operating voltage of 13.5 kV and operating beam current of 80 mA. The design was carried out using analytical formulations and 3D electromagnetic simulations. The beam-wave interaction analysis was carried out using large signal Lagrangian analysis and particle-in-cell simulation. The folded-waveguide slow-wave structure along with input-output couplers and RF windows were fabricated. Cold test measurements were carried out for dispersion characteristics of the slow-wave structure and voltage standing-wave ratio and insertion loss characteristics of the RF window. The measured cold circuit parameters show close agreement with the analysis.     

Semiconductor quantum dots as nanoelectronic circuit components

In this paper, a systematic investigation of frequency response of CdS and CdS:Cu quantum dot devices, following microwave-assisted synthesis, is presented. Phase of the output relative to the input as a function of frequency is also recorded to have some insight into the observed low-pass filter characteristics of the as-fabricated devices. The as-fabricated quantum dot devices are found to have all the characteristics of a classical low-pass filter with optimization of gain, phase shift and cut-off frequency in the band-gap range of ‘2.5–2.6’ eV. The as-fabricated devices are tested for demodulation and satisfactory operation is obtained. This suggests for employing such nanoscale devices in the field of communications.